Highly Active Immobilized Catalyst for Ethylene Polymerization: Neutral Single Site Y(III) Complex Bearing Bulky Silylallyl Ligand.

Exploring the surface organometallic chemistry on silica of highly electrophilic yttrium complexes is a relatively uncommon endeavor, particularly when focusing on tris-alkyl complexes characterized by Y-C σ-alkyl bonds. A drawback with this class of complexes once grafted on silica, is the frequent occurrence of alkyl transfer by ring opening of siloxane groups, resulting in a mixture of species. Herein, we employed a more stable homoleptic yttrium allyl complex bearing bulky η3-1,3-bis(trimethylsilyl)allyl ligand to limit this transfer reaction. This strategy has been validated by comparing the reactivity between [Y{ η3-1,3-C3H3(SiMe3)2}3] and [Y(o-CH2PhNMe2)3] with SiO2-700, where the undesired alkyl transfer reaction occurred for [Y(o-CH2PhNMe2)3] leading to a bipodal [(≡SiO)2Y(o-CH2PhNMe2)] as major surface species, 2, while [Y{ η 3-1,3-C3H3(SiMe3)2}3] resulted selectively in a monopodal species, [(≡SiO)Y{η3-1,3-C3H3(SiMe3)2}2], 1. The materials obtained were characterized by DRIFT, solid state NMR, mass balance analysis and EXAFS. Catalyst 1 showed high activity compared to 2 in ethylene polymerization. The catalytic performance of this neutral catalyst 1 was extended to pre-industrial scale in the presence of hydrogen and 1-hexene. An unprecedented activity, up to 7400 gPE gcat -1 h-1 was obtained even with very low concentration of scavenger AliBu3 (TIBA/Y=1.2). The obtained HDPE exhibited desired spherical particle morphology with broad molar mass distribution.

Assessment of perfluorocarboxylic acids in fluorinated high-density polyethylene containers and estimation of potential non-cancer risks associated with anticipated use scenarios.

High density polyethylene (HDPE) containers are fluorinated to impart barrier properties that prevent permeation of liquid products filled in the container. The process of fluorination may result in the unintentional formation of certain per- and polyfluoroalkyl substances (PFAS), specifically perfluoroalkyl carboxylic acids (PFCAs), as impurities. This study measured the amounts of PFCAs that may be present in the fluorinated HDPE containers, which could migrate into products stored in these containers. Migration studies were also conducted using water and mineral spirits to estimate the amount of PFCAs that might be found in the products stored in these containers. The migration results were used to conservatively model potential PFCA exposures from use of six product types: indoor-sprayed products, floor products, hand-applied products, manually-sprayed pesticides, hose-end sprayed products, and agricultural (industrial) pesticides. The potential that such uses could result in a non-cancer hazard was assessed by comparing the modeled exposures to both applicable human non-cancer toxicity values and environmental screening levels. Environmental releases were also compared to aquatic and terrestrial predicted no-effect concentrations (PNECs). The results of these analyses indicated no unreasonable non-cancer risk to humans, aquatic species, and terrestrial species from PFCAs in products stored in fluorinated HDPE containers.

Isolation and characterization of bio-prospecting gut strains Bacillus safensis CGK192 and Bacillus australimaris CGK221 for plastic (HDPE) degradation.

The present work reports the application of novel gut strains Bacillus safensis CGK192 (Accession No. OM658336) and Bacillus australimaris CGK221 (Accession No. OM658338) in the biological degradation of synthetic polymer i.e., high-density polyethylene (HDPE). The biodegradation assay based on polymer weight loss was conducted under laboratory conditions for a period of 90 days along with regular evaluation of bacterial biomass in terms of total protein content and viable cells (CFU/cm2). Notably, both strains achieved significant weight reduction for HDPE films without any physical or chemical pretreatment in comparison to control. Hydrophobicity and biosurfactant characterization were also done in order to assess strains ability to form bacterial biofilm over the polymer surface. The post-degradation characterization of HDPE was also performed to confirm degradation using analytical techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Field emission scanning electronic microscopy (FE-SEM) coupled with energy dispersive X-ray (EDX), and Gas chromatography-mass spectrometry (GC-MS). Interestingly strain CGK221 was found to be more efficient in forming biofilm over polymer surface as indicated by lower half-life (i.e., 0.00032 day-1) and higher carbonyl index in comparison to strain CGK192. The findings reflect the ability of our strains to develop biofilm and introduce an oxygenic functional group into the polymer surface, thereby making it more susceptible to degradation.

Type-specific inflammatory responses of vascular cells activated by interaction with virgin and aged microplastics.

Microplastics (MPs) are recognized as a major environmental problem due to their ubiquitous presence in ecosystems and bioaccumulation in food chains. Not only humans are continuously exposed to these pollutants through ingestion and inhalation, but recent findings suggest they may trigger vascular inflammation and potentially worsen the clinical conditions of cardiovascular patients. Here we combine headspace analysis by needle trap microextraction-gas chromatography-mass spectrometry (HS-NTME-GC-MS) and biological assays to evaluate the effects of polystyrene, high- and low-density polyethylene MPs on phenotype, metabolic activity, and pro-inflammatory status of Vascular Smooth Muscle Cells (VSMCs) the most prominent cells in vascular walls. Virgin and artificially aged MPs (4 weeks at 40 °C and 750 W/m2 simulated solar irradiation) were comparatively tested at 1 mg/mL to simulate a realistic exposure scenario. Our results clearly show the activation of oxidative stress and inflammatory processes when VSMCs were cultured with aged polymers, with significant overexpression of IL-6 and TNF-α. In addition, volatile organic compounds (VOCs), including pentane, acrolein, propanal, and hexanal as the main components, were released by VSMCs into the headspace. Type-specific VOC response profiles were induced on vascular cells from different MPs.

Production of Aromatic Hydrocarbons from Co-Hydropyrolysis of Biomass Components and HDPE with Application of Modified HZSM-5 Catalyst.

Experiments were conducted in this study on the co-hydropyrolysis of three components of biomass (cellulose, hemicellulose, and lignin) and HDPE by using SR-Pd/Trap-HZ-5 as catalyst. To control the variable, we use the same experiment conditions in co-hydropyrolysis: Si/Al ratio of 50, Pd load 1 %, catalyst to reactant ratio of 1 : 10, 1 MPa, 400 °C, reaction time 1 h. Use XRD, TEM, BET, and NH3-TPD to confirm catalyst successful synthesis; use pine sawdust (PW) co-hydropyrolysis with HDPE to analyse catalytic activity; and use GC/MS to characterize the chemical composition of the bio-oil from the co-hydropyrolysis of biomass components and HDPE. The results show that cellulose has a significant synergistic effect with aromatic hydrocarbon production, whose selectivity was 93.3 %; hemicellulose has a synergistic effect; aromatic selectivity can reach 75.1 %; and a negative synergistic effect between lignin and HDPE was shown as the selectivity of aromatic hydrocarbons decreased from 62.1 % to 15.6 %.

Alleviation of microplastic toxicity in soybean by arbuscular mycorrhizal fungi: Regulating glyoxalase system and root nodule organic acid.

Microplastic accumulation in the soil-plant system can stress plants and affect products quality. Currently, studies on the effect of microplastics on plants are not consistent and underlying molecular mechanisms are yet unknown. Here for the first time, we performed a study to explore the molecular mechanism underlying the growth of soybean plants in soil contaminated with various types of microplastics (PS and HDPE) and arbuscular mycorrhizal fungi (AMF) (presence/absence). Our results revealed that a dose-dependent decline was observed in plant growth, chlorophyll content, and yield of soybean under MPs stress. The addition of MPs resulted in oxidative stress closely related to hydrogen peroxide generation (H2O2), methylglyoxal (MG) levels, lipid peroxidation (MDA), and lipoxygenase (LOX). In contrast, MPs addition enhanced mycorrhizal colonization and dependency relative to control while the rubisco and root activity declined. All the genes (GmHMA13 and GmHMA19) were downregulated in the presence of MPs except GmHMA18 in roots. AMF inoculation alleviated MPs-induced phytotoxic effects on colonization, rubisco activity, root activity and restored the growth of soybean. Under MPs exposure, AMF inoculation induced plant defense system via improved regulation of antioxidant enzymes, ascorbate, glutathione pool, and glyoxalase system. AMF upregulated the genes responsible for metals uptake in soybean under MPs stress. The antioxidant and glyoxalase systems coordinated regulation expressively inhibited the oxidative and carbonyl stress at both MPs types. Hence, AMF inoculation may be considered an effective approach for minimizing MPs toxicity and its adverse effects on growth of soybean grown on MPs-contaminated soils.

Catalyst Accessibility and Acidity in the Hydrocracking of HDPE: A Comparative Study of H-USY, H-ZSM-5, and MCM-41 Modified with Ga and Al.

Plastic pollution is a critical environmental issue due to the widespread use of plastic materials and their long degradation time. Hydrocracking (HDC) offers a promising solution to manage plastic waste by converting it into valuable products, namely chemicals or fuels. This work aims to investigates the effect of catalyst accessibility and acidity on the HDC reaction of high density polyethylene (HDPE). Therefore, a variety of materials with significant differences in both textural and acidic properties were tested as catalysts. These include H-USY and H-ZSM.5 zeolites with various Si/Al molar ratios (H-USY: Si/Al = 2.9, 15, 30 and 40; H-ZSM-5: Si/Al = 11.5, 40, 500) and mesostructured MCM-41 materials modified with Ga and Al, also with different Si/metal ratios (Si/Al = 16 and 30; Si/Ga = 63 and 82). Thermogravimetric analysis under hydrogen atmosphere was used as a preliminary screening tool to evaluate the potential of the various catalysts for this application in terms of energy requirements. In addition, batch autoclave reactor experiments (T = 300 °C, PH2 = 20 bar, t = 60 min) were conducted to obtain further information on conversion, product yields and product distribution for the most promising systems. The results show that the catalytic performance in HDPE hydrocracking is determined by a balance between the acidity of the catalyst and its structural accessibility. Accordingly, for catalyst series where the structural and textural properties do not vary with the Si/Al ratio, there is a clear correlation of the HDPE degradation temperature and of the HDPE conversion with the Si/metal ratio (which relates to the acidic properties). In contrast, for catalyst series where the structural and textural properties vary with the Si/Al ratio, no consistent trend is observed and the catalytic performance is determined by a balance between the acidic and textural properties. The product distribution was also found to be influenced by the physical and chemical properties of the catalyst. Catalysts with strong acidity and smaller pores were observed to favor the formation of lighter hydrocarbons. In addition to the textural and acidic properties of the catalyst, the role of coke formation should not be neglected to ensure a comprehensive analysis of the catalytic performance.

Waste Plastic to Roads - HDPE-modified Bitumen and PET Plastic Fibres for Road Maintenance in South Africa: A Review.

This review article provides a comprehensive analysis of the transformative potential of waste plastic in South Africa, with a specific focus on high-density polyethylene-modified bitumen and polyethylene terephthalate plastic fibres asphalt. The review encompasses a wide range of topics, including the environmental and socio-economic impacts of plastic waste, the current state of plastic waste management practices in South Africa, and the potential use of waste plastic in road construction. The aim is to critically evaluate the compatibility of recycled waste plastics as bitumen modifiers and fibre to enhance road performance. Additionally, it explores the challenges and opportunities associated with the incorporation of waste plastic in road construction, shedding light on the environmental, economic and technological aspects. The review also emphasizes the need for targeted interventions and collaborative efforts from the South African government and industry stakeholders to address plastic waste management challenges and promote sustainable infrastructure development. Overall, this review provides valuable insights into the transformative potential of waste plastic in South African road maintenance and offers a roadmap for future research and initiatives in this critical area of sustainable development.

Utilization of Bacillus cereus strain CGK5 associated with cow feces in the degradation of commercially available high-density polyethylene (HDPE).

The accumulation and mismanagement of high-density polyethylene (HDPE) waste in the environment is a complex problem in the present scenario. Biodegradation of this thermoplastic polymer is a promising environmentally sustainable method that offers a significant opportunity to address plastic waste management with minimal negative repercussion on the environment. In this framework, HDPE-degrading bacterium strain CGK5 was isolated from the fecal matter of cow. The biodegradation efficiency of strain was assessed, including percentage reduction in HDPE weight, cell surface hydrophobicity, extracellular biosurfactant production, viability of surface adhered cells, as well as biomass in terms of protein content. Through molecular techniques, strain CGK5 was identified as Bacillus cereus. Significant weight loss of 1.83% was observed in the HDPE film treated with strain CGK5 for 90 days. The FE-SEM analysis revealed the profused bacterial growth which ultimately caused the distortions in HDPE films. Furthermore, EDX study indicated a significant decrease in percentage carbon content at atomic level, whereas FTIR analysis confirmed chemical groups' transformation as well as an increment in the carbonyl index supposedly caused by bacterial biofilm biodegradation. Our findings shed light on the ability of our strain B. cereus CGK5 to colonize and use HDPE as a sole carbon source, demonstrating its applicability for future eco-friendly biodegradation processes.

Delmopinol hydrochloride inhibits Campylobacter jejuni on skinless poultry meat, stainless steel, and high-density polyethylene food contact surfaces.

Delmopinol hydrochloride (delmopinol) is a cationic surfactant that is effective for treating and preventing gingivitis and periodontitis. This study evaluated the effectiveness of delmopinol for reducing attachment of Campylobacter jejuni to chicken meat, stainless steel, and high-density polyethylene (HDPE). These test materials were spot-inoculated with a C. jejuni culture. After 10 min, samples were sprayed with 0.5% or 1.0% delmopinol, 0.01% sodium hypochlorite, or distilled water. After a 1, 10, or 20 min contact time, samples were rinsed, which were serially diluted onto Campy-Cefex Agar. For additional samples, solutions were applied before inoculation with C. jejuni. Cultures remained undisturbed for 1, 10, or 20 min. Samples were then rinsed and plated as above. When C. jejuni was inoculated before treatments, 1% delmopinol application led to mean log reductions of 1.26, 3.70, and 3.72 log cfu ml-1, greater than distilled water alone, for chicken, steel and HDPE, respectively. When C. jejuni was inoculated after spray treatments, 1% delmopinol reduced C. jejuni by 2.72, 3.20, and 3.99 mean log cfu ml-1 more than distilled water for chicken, steel and HDPE, respectively. Application of 1% delmopinol, resulted in a significantly (P < .05) greater log reduction than a 0.01% sodium hypochlorite or distilled water application.

Multi-Analytical Approach to Characterize the Degradation of Different Types of Microplastics: Identification and Quantification of Released Organic Compounds.

Microplastics and nanoplastics represent one of the major environmental issues nowadays due to their ubiquitous presence on Earth, and their high potential danger for living systems, ecosystems, and human life. The formation of both microplastics and nanoplastics strongly depends on both the type of pristine materials and the degradation processes related to biological and/or abiotic conditions. The aim of this study is to investigate the effect of two of the most relevant abiotic parameters, namely temperature and light, taken under direct control by using a Solar box, on five types of reference polymers: high density polyethylene (HDPE), low density polyethylene (LDPE), polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET). A multi-analytical approach was adopted to investigate in detail the first steps of plastics degradation. Samples of plastic materials at different degradation times were analyzed by means of 1H NMR spectroscopy and thermal desorption gas chromatography mass spectrometry (TD-GC-MS) technique. Several minor molecular species released during degradation were consistently identified by both techniques thus providing a comprehensive view of the various degradation products of these five types of microplastics.

Microbeads in personal care products sold in Pakistan: extraction, quantification, characterization, and buoyancy analysis.

Microbeads used in personal care products (PCPs) as an exfoliating agent or as a sorbent phase for delivering active ingredients are the most common sources of microplastics. The release of these plastic microbeads into aquatic environments has raised significant concerns due to their direct availability for ingestion by organisms upon entering the recipient waters. In this study, twelve personal care products (PCPs; 5 face washes and 7 scrubs) were analyzed for microbead content, size, polymer type, and buoyant behavior. Among the face washes, the highest microbead content (i.e., 11 ± 1.2 mg/g) was found in Neutrogena (NS), while the lowest was found in Nivea (NI) with 0.33 ± 0 mg/g. In case of scrubs, Cool and Cool (CL) contained a higher concentration of microbeads (i.e., 57.08±14.15 mg/g) and a lower concentration was found in Yong Chin (YC) (i.e., 10.5±1.5 mg/g). The sizes of microbeads ranged from 3.14 ± 0 to 747 ± 313 µm, and most of the isolated microbeads showed negative buoyant behavior in both freshwater and seawater. The FTIR spectra showed that the microbeads were mainly composed of ethyl-vinyl acetate (66.66%), high-density polyethylene (16.66%), polyethylene terephthalate (8.3%), and nitrile (8.3%). The presence of plastic microbeads in PCPs highlights the need to regulate their use as an exfoliating agent and to raise public awareness to prevent the discharge of these persistent and potentially harmful elements into the environment.

Shelf life prediction of dried garlic powder under accelerated storage conditions.

The shelf life of dried garlic powder packaged in high-density polyethylene (HDPE), low-density polyethylene (LDPE), and aluminum laminated pouch (ALP) under accelerated storage temperature (5° to 40 °C) and humidity (70-90% RH) conditions, was predicted using GAB mathematical model. The water activity value reduced significantly from 0.83 to 0.31 as the moisture content reduced. The temperature had a negative effect on color change and the lightness value and whiteness index of garlic powder significantly decreased from 62.21 to 56.06 and 50.67 to 44.91 respectively, when temperature increased from 70° to 90° C. The storage life of garlic powder was 24, 78 and 210 days in LDPE, HDPE, and ALP, respectively under domestic storage conditions (40 °C, 90% RH). Therefore, under industrial storage conditions (5 °C, 70% RH), garlic could be preserved for 1.32, 4.30 and 7.28 years in LDPE, HDPE and ALP, respectively.

Mechanistic Understanding of Efficient Polyethylene Hydrocracking over Two-Dimensional Platinum-Anchored Tungsten Trioxide.

Chemical upcycling of polyethylene (PE) can convert plastic waste into valuable resources. However, engineering a catalyst that allows PE decomposition at low temperatures with high activity remains a significant challenge. Herein, we anchored 0.2 wt.% platinum (Pt) on defective two-dimensional tungsten trioxide (2D WO3 ) nanosheets and achieved hydrocracking of high-density polyethylene (HDPE) waste at 200-250 °C with a liquid fuel (C5-18 ) formation rate up to 1456 gproducts ⋅ gmetal species -1 ⋅ h-1 . The reaction pathway over the bifunctional 2D Pt/WO3 is elucidated by quasi-operando transmission infrared spectroscopy, where (I) well-dispersed Pt immobilized on 2D WO3 nanosheets trigger the dissociation of hydrogen; (II) adsorption of PE and activation of C-C cleavage on WO3 are through the formation of C=O/C=C intermediates; (III) intermediates are converted to alkane products by the dissociated H. Our study directly illustrates the synergistic role of bifunctional Pt/WO3 catalyst in the hydrocracking of HDPE, paving the way for the development of high-performance catalysts with optimized chemical and morphological properties.

Micrococcus luteus strain CGK112 isolated from cow dung demonstrated efficient biofilm-forming ability and degradation potential toward high-density polyethylene (HDPE).

Biodegradation is the most promising environmentally sustainable method that offers a significant opportunity with minimal negative environmental consequences while searching for solutions to this global problem of plastic pollution that has now spread to almost everywhere in the entire world. In the present work, HDPE-degrading bacterial strain CGK112 was isolated from the fecal matter of a cow. The bacterial strain was identified as Micrococcus luteus CGK112 by 16S rRNA sequence coding analysis. Significant weight loss, i.e., 3.85% was recorded in the HDPE film treated with strain CGK112 for 90 days. The surface micromorphology was examined using FE-SEM, which revealed spectacular bacterial colonization as well as structural deformation. Furthermore, the EDX study indicated a significant decrease in the atomic percentage of carbon content, whereas FTIR analysis confirmed functional groups alternation as well as an increase in the carbonyl index which can be attributed to the metabolic activity of biofilm. Our findings provide insight into the capacity of our strain CGK112 to colonize and utilize HDPE as a single carbon source, thus promoting its degradation.

Diversion Detection in Small-Diameter HDPE Pipes Using Guided Waves and Deep Learning.

In this paper, we propose a novel technique for the inspection of high-density polyethylene (HDPE) pipes using ultrasonic sensors, signal processing, and deep neural networks (DNNs). Specifically, we propose a technique that detects whether there is a diversion on a pipe or not. The proposed model transmits ultrasound signals through a pipe using a custom-designed array of piezoelectric transmitters and receivers. We propose to use the Zadoff-Chu sequence to modulate the input signals, then utilize its correlation properties to estimate the pipe channel response. The processed signal is then fed to a DNN that extracts the features and decides whether there is a diversion or not. The proposed technique demonstrates an average classification accuracy of 90.3% (when one sensor is used) and 99.6% (when two sensors are used) on 34 inch pipes. The technique can be readily generalized for pipes of different diameters and materials.

Influence of sediment texture on HDPE microplastics recovery by density separation.

Microplastics (MPs) are an emerging environmental pollutant, threatening marine and terrestrial ecosystems. Because of their properties and their widely varying size (5mm-0.1 µm), it is still difficult to define a valid and efficient method for extracting MPs from solid matrices. Among the several methods proposed, density separation is the most practical and cost-effective one. Progress is still ongoing towards a deeper understanding of the advantages and limitations related to the application of density separation for MPs extraction, the recovery yields and the factors that may influence it. In this context, we introduce the following work, which provides an early-stage insight into how the sediment texture may influence the efficiency of this extraction method, and how parameters, such as sedimentation time and extraction cycles, can be modified to always achieve the best recovery. Our focus has been directed on evaluating the extraction efficiency of HDPE MPs by density separation using NaCl, from three types of sediment: sandy (SS), sandy loam (SLS) and sandy-clay loam (SCLS). We investigated the impact of sedimentation time (1, 6, 12, 24 h) and extraction cycles (3 cycles for each sedimentation time) on MPs recovery. Finally, we determined the minimum amount of MPs (MPs g/g sediment) below which it is not possible to quantify MPs with the method used. The results have shown that the recovery efficiency of MPs from sediment is structure dependent. The highest recoveries are reached after a settling time of 1 and 6 h. Furthermore, for samples with minimum clay content (SS), only one extraction cycle is needed, whereas two extraction cycles are required for SLS and SCLS. The outcomes about the detection limit (LOD) of the method, showed the existence of an interaction MPs-clay/sediment, which allowed us to understand how far this extraction method is suitable in field, thus defining the minimum grade of MPs pollution (MPs g/g sediment) below which this method is no longer capable to extract MPs from contaminated samples.

Simulated experimental investigation of microplastic weathering in marine environment.

Microplastics act as a potential vector for a wide range of contaminants, which have emerged as a major environmental hazard in the modern world. Considering the seriousness of the problem, a simulated laboratory and field experiment were conducted to study the weathering of pristine microplastics following long-term exposure to natural background radiation and the marine environment after being disposed of in the open environment. For the study, polyethylene-originating (HDPE and LDPE) microplastics were chosen. The study revealed that radiation exposure causes surface roughness and cracks, leading to an increased surface area, which can invite a wide spectrum of pollutants to sorb on their surface. Furthermore, we report that the radiation-induced morphological changes favor microbial colonization on the microplastic surface when exposed to the marine environment. The growth of biofilms on the surface of microplastics reduces their hydrophobicity, which may attract a wide variety of polar contaminants. The study led to an interesting finding: that the HDPE microplastic surface is more conducive for biofilm growth in comparison to the LDPE surface.

Temperature effects on ageing properties and diffusivity of a HDPE GM in landfill.

High-density polyethylene (HDPE) geomembranes (GMs) play a crucial role in preventing the leakage and migration of pollutants. GM service life and ageing properties are the main concerns for the choice of materials. However, it is not clear how the mechanical properties and anti-fouling performance of geomembranes change with ageing time. To solve this problem, a HDPE GM was selected for testing under exposed air condition. The tests included oxidation induction time (OIT), melt flow index (MFI), tensile properties and diffusivity under four temperature conditions for 1½ years. The test results showed that the GM has higher OIT degradation rates. Stage I - depletion of antioxidants occurred at only 10 years for the GM, which was approximately 1/4 that of the GM-GSE. The GM engineering properties index showed the same changes as those of the GM-GSE. However, MI rapidly decreased with the incubation time. The molecular weight degradation of the GM was approximately 57% and far greater than that of GM-GSE after 15 months, but the tensile properties of the two GMs showed little change. The diffusion coefficient Di of GM increases gradually with the increase of temperature in methane and trichloromethane. Under the same conditions, the diffusion coefficient Di of the GM in methane is significantly higher than that in trichloromethane, indicating that the GM has better barrier to trichloromethane.

Applications of an electronic nose in the prediction of oxidative stability of stored biodiesel derived from soybean and waste cooking oil.

Waste cooking oil (WCO) is a valuable feedstock for the synthesis of biodiesel but the product exhibits poor oxidative stability. Techniques available for assessing this parameter are generally expensive and time-consuming, hence the purpose of this study was to develop and validate a rapid and reliable predictive system based on signals from the sensors of a commercial hand-held e-nose instrument. Biodiesels were synthesized from soybean oil and six samples of WCO, and their physicochemical characteristics and oxidative stabilities determined before and after storage in different types of containers for 30 or 60 days at room temperature or 43 °C. Linear regression models were constructed based on principal component analysis of the signals generated by all 32 e-nose sensors and stochastic modeling of signal profiles from individual sensors. The regression model with principal components as predictors was unable to explain the oxidative stability of biodiesels, while the regression model with stochastic parameters (combining signals from 11 sensors) as predictors showed an excellent goodness of fit (R2 = 0.91) with a 45-sample training set and a good quality of prediction (R2 = 0.84) with a 18-sample validation set. The proposed e-nose system was shown to be accurate and efficient and could be used to advantage by producers/distributors of biodiesel in the assessment fuel quality.