Efficient phosphate and hydrogen recovery from sludge fermentation liquid by sacrificial iron anode in electro-fermentation system.

Electro-fermentation (EF) has been extensively studied for recovering hydrogen and phosphorus from waste activated sludge (WAS), while was limited for the further application due to the low hydrogen yield and phosphorus recovery efficiency. This study proposed an efficient strategy for hydrogen and vivianite recovery from the simulated sludge fermentation liquid by sacrificial iron anode in EF. The optimum hydrogen productivity and the utilization efficiency of short chain fatty acids (SCFAs) reached 45.2 mmol/g COD and 77.6% at 5 d in pH 8. Phosphate removal efficiency achieved at 90.8% at 2 d and the high crystallinity and weight percentage of vivianite (84.8%) was obtained. The functional microbes, i.e., anaerobic fermentative bacteria, electrochemical active bacteria, homo-acetogens and iron-reducing bacteria were highly enriched and the inherent interaction between the microbial consortia and environmental variables was thoroughly explored. This work may provide a theoretical basis for energy/resource recovery from WAS in the further implementation.

Removal of arsenic, phosphates and ammonia from well water using electrochemical/chemical methods and advanced oxidation: a pilot plant approach.

The purpose of this work was to develop a pilot plant purification system and apply it to groundwater used for human consumption, containing high concentrations of arsenic and increased levels of phosphates, ammonia, mercury and color. The groundwater used was obtained from the production well in the Vinkovci County (Eastern Croatia). Due to a complex composition of the treated water, the purification system involved a combined electrochemical treatment, using iron and aluminum electrode plates with simultaneous ozonation, followed by a post-treatment with UV, ozone and hydrogen peroxide. The removal of the contaminant with the waste sludge collected during the electrochemical treatment was also tested. The combined electrochemical and advanced oxidation treatment resulted in the complete removal of arsenic, phosphates, color, turbidity, suspended solids and ammonia, while the removal of other contaminants of interest was up to 96.7%. Comparable removal efficiencies were obtained by using waste sludge as a coagulant.

The Synergistic Effect of MoS2 and NiS on the Electrical Properties of Iron Anodes for Ni-Fe Batteries.

In this paper, a series of Fe3O4/MoS2/NiS composite electrodes were synthesized by a simple coprecipitation method. The influence of different ratio additives (MoS2 and NiS) on the performance of iron anodes for Ni-Fe batteries was systematically investigated. In this paper, the mixed alkaline solution of 6 mol/L NaOH and 0.6 mol/L LiOH was used as electrolyte, and sintered Ni(OH)2 was used as counterelectrode. The experimental results show that the MoS2 and NiS additives can effectively eliminate the passivation phenomena in iron electrodes, reduce the electrode polarization, and increase the reversibility capacity. As a result, the Fe3O4/MoS2/NiS composite electrodes exhibit a high specific capacity, good rate performance, and long cycling stability. Especially, the Fe3O4/MoS2 (5%)/NiS (5%) electrode with a suitable ratio of additives can provide excellent electrochemical performance, with high discharge capacities of 657.9 mAh g-1, 639.8 mAh g-1, and 442.1 mAh g-1 at 600 mA g-1, 1200 mA g-1, and 2400 mA g-1, respectively. This electrode also exhibits good cycling stability.

CaO2-based electro-Fenton-oxidation of 1,2-dichloroethane in groundwater.

It has been well recognized that the Fenton reaction requires a rigorous pH control and suffers from the fast self-degradation of H2O2. In an effort to resolve the technical demerits of the conventional Fenton reaction, particular concern on the use of CaO2-based Fenton reaction was paid in this study. To realize the practical use of CaO2 in the Fenton reaction for groundwater remediation, it could be of great importance to control its reaction rate in the subsurface. As such, this study laid great emphasis on the combined process of electrochemical oxidation and CaO2-based Fenton oxidation, using 1,2-dichloroethane (1,2-DCA) as a model compound. It was hypothesized that the reaction rate is also highly contingent on the formation of Fe(II) (stemmed from iron anode oxidation). Eighty percent of 1,2-DCA were degraded by the CaO2-based Fenton reaction. The final pH was neutral, inferring that the reaction could be a viable option for the subsurface environment. Moreover, the supply of electric current in an iron anode expedited 1,2-DCA degradation efficiency from 35 % to 62 % via electrically generated Fe(II), which donated electrons to H2O2, producing more hydroxyl radicals. An anode-cathode configuration from the single-well system enhanced the degradation of 1,2-DCA, with less amount of energy consumption than the double-well system. Based on results, CaO2-based electro-Fenton oxidation can remove well 1,2-DCA in groundwater and can be a strategic measure for groundwater remediation.

Modification of graphite felt doped with nitrogen and boron for enhanced removal of dimethyl phthalate in peroxi-coagulation system and mechanisms.

To enhance the generation of hydrogen peroxide (H2O2), a modified graphite felt cathode doped with nitrogen and boron was developed and used in peroxi-coagulation system to degrade dimethyl phthalate (DMP). After a simple modification method, the yield of H2O2 on cathode increased from 9.39 to 152.8 mg/L, with current efficiency increased from 1.61 to 70.3%. Complete degradation of DMP and 80% removal of TOC were achieved within 2 h at the optimal condition with pH of 5, cathodic potential of - 0.69 V (vs. SCE), oxygen aeration, and electrode gap of 1 cm. Possible mechanism with synergistic effect of electro-Fenton and electrocoagulation process in the peroxi-coagulation system was revealed via quenching experiments. The prospect of this system in the effluent of landfill leachate and domestic sewage was studied, achieving 50% and 61% of DMP removal in 2 h. This efficient system with simple modified cathode had promising prospects in practical applications.

Effect of low-intensity electric current field and iron anode on biological nitrate removal in wastewater with low COD to nitrogen ratio from coal pyrolysis.

Mixotrophic nitrate removal in wastewater from coal pyrolysis was achieved in microbial electrolysis cell with iron anode (iron-MEC). The effect of voltage, iron anode and conductivity were investigated. The effluent TN concentration was 8.35 ± 1.94 mg/L in iron-MEC when the conductivity of the wastewater was adjusted to 3.97 ± 0.08 mS/cm, which was lower than that in no-treated reactor. The increase of current density, which was resulted from the elevation of conductivity, promoted the iron corrosion and Fe2+ ion generation. Therefore, more Fe2+ ion was utilized by nitrate reducing ferrous oxidation bacteria (NRFOB) used to reduce nitrate. The microbial community analysis demonstrated that NRFOB, including Acidovorax and Bradyrhizobium, possessed a higher abundance in iron-MEC. The enrichment of Geobacter in iron-MEC might imply that the part of Fe(III) produced by ferrous oxidation was reduced by Geobacter, which established an iron cycle. Moreover, the production of N2O was decreased by the formation of Fe2+ ion.

Enhanced aerobic granulation by applying the low-intensity direct current electric field via reactive iron anode.

A novel granulation strategy by applying the low-intensity direct current (DC) electric field via reactive iron anode into the aerobic granular sludge (AGS) system was systematically investigated in this study. Three identical sequencing batch reactors (SBRs, namely R1, R2, and R3) were operated for 100 days. Comparatively, the R1 and R3 were continuously subjected to the 1.0 V DC electric field via a reactive Fe anode and an inert Ti-Ir/Rh anode, respectively, while the R2 without DC exposure. The results showed that the sludge granulation processes were accelerated in order as follows: R2