RESUMO
Thermo-mechanical fatigue (TMF) is one of the most detrimental failures of critical engine components and greatly limits their service life. In this study, the out-of-phase TMF (OP-TMF) behavior in Al-Si-Cu 319 cast alloys microalloyed with Mo was systematically investigated under various strain amplitudes ranging from 0.1-0.6% and temperature cycling at 60-300 °C and compared with the base 319 alloy free of Mo. Cyclic stress softening occurred in both experimental alloys when applying the TMF loading, resulting from the coarsening of θ'-Al2Cu precipitates. However, the softening rate of the Mo-containing alloy was lower than that of the base 319 alloy because of its lower θ'-Al2Cu precipitate coarsening rate per cycle. The Mo-containing alloy exhibited a longer TMF lifetime than the base alloy at the same strain amplitude. Microalloying 319 alloy with Mo enhanced the TMF resistance mainly by slowing the coarsening of θ'-Al2Cu precipitates and providing supplementary strengthening from thermally stable Mo-containing α-dispersoids distributed in the Al matrix. The energy-based model was successfully applied for predicting the TMF lifetime with a low life predictor factor, which agreed well with the experimentally measured fatigue cycles.
RESUMO
Mo2FeB2-based cermets have wide applications in fields of wear resistance, corrosion resistance and heat resistance due to their simple preparation process, low-cost raw materials, and prominent mechanical properties. Herein, Mo2FeB2-based cermets with xMo (x = 43.5, 45.5, 47.5, 49.5, wt.%) were prepared by means of the vacuum liquid phase sintering technique. Investigations on the microstructure and mechanical properties of Mo2FeB2-based cermets with Mo addition were performed. Experimental results show that, with Mo content increasing, the average particle size decreases gradually, revealing that the grain coarsening of Mo2FeB2-based cermets is controlled by interface reaction. In addition, Mo2FeB2 grains gradually transform from an elongated shape to a nearly equiaxed shape. The improvement of Mo2FeB2 hard phase on the morphology is mainly due to the inhibition of solution-precipitation reaction by increasing Mo. Furthermore, the relative density of cermets decreases due to the reduced Fe content. When Mo content is 47.5 wt.%, a relatively small grain size of Mo2FeB2 is obtained (about 2.03 µm). Moreover, with the increase in Mo content, hardness and transverse rupture strength (TRS) of Mo2FeB2-based cermets increase firstly and then decrease. Whereas, with increasing Mo content, the fracture toughness deteriorates gradually. When Mo content is 47.5 wt.%, the comprehensive mechanical properties of cermets are the best. The optimal raw material ratio for the preparation of Mo2FeB2-based cermets in this study is determined to be 47.5 wt.% Mo-6.0 wt.% B-Fe.
RESUMO
In the present study, Mo was added to Cu-15Ni-8Sn alloy as the fourth element to solve the limitation of service performance of the alloy by composition design. The phase composition, microstructure transformation and mechanical properties of Cu-15Ni-8Sn-xMo (x = 0.3, 0.9, 1.5 wt.%) alloy were systematically studied by simulation calculation and experimental characterization. The results show that the addition of Mo can improve the as-cast structure of Cu-15Ni-8Sn alloy and reduce segregation and Cu-Mo phase precipitates on the surface with the increase in Mo contents. During solution treatment, Mo can partially dissolve into the matrix, which may be the key to improving the properties of the alloy. Furthermore, the discontinuous precipitation of Sn can be effectively inhibited by adding the appropriate amount of Mo to Cu-15Ni-8Sn alloy, and the hardness of alloy does not decrease greatly after a long-time aging treatment. When Mo content is 0.9 wt.%, the alloy reaches the peak hardness of 384 HV at 4 h of aging. These results provide new ideas for composition optimization of Cu-15Ni-8Sn alloy.