Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 20 de 76
Filtrar
1.
Environ Res ; 241: 117581, 2024 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-37967705

RESUMO

Plastic consumption and its end-of-life management pose a significant environmental footprint and are energy intensive. Waste-to-resources and prevention strategies have been promoted widely in Europe as countermeasures; however, their effectiveness remains uncertain. This study aims to uncover the environmental footprint patterns of the plastics value chain in the European Union Member States (EU-27) through exploratory data analysis with dimension reduction and grouping. Nine variables are assessed, ranging from socioeconomic and demographic to environmental impacts. Three clusters are formed according to the similarity of a range of characteristics (nine), with environmental impacts being identified as the primary influencing variable in determining the clusters. Most countries belong to Cluster 0, consisting of 17 countries in 2014 and 18 countries in 2019. They represent clusters with a relatively low global warming potential (GWP), with an average value of 2.64 t CO2eq/cap in 2014 and 4.01 t CO2eq/cap in 2019. Among all the assessed countries, Denmark showed a significant change when assessed within the traits of EU-27, categorised from Cluster 1 (high GWP) in 2014 to Cluster 0 (low GWP) in 2019. The analysis of plastic packaging waste statistics in 2019 (data released in 2022) shows that, despite an increase in the recovery rate within the EU-27, the GWP has not reduced, suggesting a rebound effect. The GWP tends to increase in correlation with the higher plastic waste amount. In contrast, other environmental impacts, like eutrophication, abiotic and acidification potential, are identified to be mitigated effectively via recovery, suppressing the adverse effects of an increase in plastic waste generation. The five-year interval data analysis identified distinct clusters within a set of patterns, categorising them based on their similarities. The categorisation and managerial insights serve as a foundation for devising a focused mitigation strategy.


Assuntos
Gerenciamento de Resíduos , Gerenciamento de Resíduos/métodos , Europa (Continente) , Embalagem de Produtos , Meio Ambiente , Aquecimento Global , Plásticos , Reciclagem
2.
J Environ Manage ; 351: 119630, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38043308

RESUMO

In order to obtain extended storage life of food-grade materials and better barrier properties against environmental factors, a multilayer plastic packaging (MLP) is often used. The multilayer packaging plastics are labelled as "other" (SPI#7) category, and are manufactured with a combination of barrier plastics, rigid plastics and printing surface. Owing to their complex composition and difficulty in separating the layers of MLP, its mechanical recycling is challenging. In this study, MLP wastes (MLPWs) were collected from zero-waste garbage collection center of IIT Madras, India, and thoroughly characterized to determine their composition and plastic types. MLPWs were characterized using various physico-chemical methods such as thermogravimetric/differential scanning calorimetric analysis, Fourier transform infrared spectroscopy, bomb calorimetry, and proximate and ultimate analyses. The MLPWs were mainly made up of polyethylene (PE) and polyethylene terephthalate (PET). Further, the non-catalytic and zeolite-catalyzed fast pyrolysis of these MLPWs were studied using analytical pyrolysis coupled with gas chromatograph/mass spectrometer (Py-GC/MS). The non-catalytic fast pyrolysis of MLPWs primarily produced a mixture of aliphatic and alicyclic hydrocarbons, while zeolite catalyzed fast pyrolysis resulted in the formation of mono-aromatic hydrocarbons (MAHs). The activity of HZSM-5, zeolite Y (HY) and zeolite beta (Hß) catalysts were evaluated, and the salient products were quantified. The yields of MAHs like benzene, toluene, ethylbenzene and xylene using the zeolites followed the trend: HZSM-5 (14.9 wt%) > HY (8.1 wt%) > Hß (7.8 wt%), at 650 °C. The use of HZSM-5 resulted in highest yield of MAHs, viz. 16.1 wt%, at the optimum temperature of 550 °C and MLPW-to-catalyst ratio of 1:15 (w/w). The superior activity of HZSM-5 is due to its nominal acidity and larger pore size of 4.24 nm, as compared to HY and Hß. The MAHs yield from three other types of MLPWs varied in the range of 9-16 wt%. The present study demonstrates a promising pathway for the catalytic upcycling of highly heterogeneous MLPWs in the context of circular economy.


Assuntos
Hidrocarbonetos Aromáticos , Zeolitas , Zeolitas/química , Índia , Hidrocarbonetos/análise , Hidrocarbonetos Aromáticos/análise , Catálise , Tolueno , Temperatura Alta
3.
Molecules ; 28(4)2023 Feb 16.
Artigo em Inglês | MEDLINE | ID: mdl-36838860

RESUMO

A hydrophobic calix[4]arene derivative was investigated for its iodine (I2) capture efficiency from gaseous and liquid phase. The iodine uptake was followed by UV-vis spectroscopy. Additionally, the influence of the calix[4]arene derivative-polyolefin system on the leaching of iodine through packaging from a povidone-iodine-based (PVP-I) formulation was evaluated. In fact, iodine is a low-cost, multi-target, and broad-spectrum antiseptic. However, it is volatile, and the extended storage of I2-based formulations is challenging in plastic packaging. Here, we investigated the possibility of reducing the loss of I2 from an iodophor formulation by incorporating 4-tert-butylcalix [4]arene-tetraacetic acid tetraethyl ester (CX) and its iodine complex in high-density polyethylene (HDPE) or polypropylene (PP) via a swelling procedure. Surface and bulk changes were monitored by contact angle, thermogravimetric analysis (TGA), and UV-vis diffuse reflectance spectra. The barrier effect of the different polymeric systems (embedded with CX, iodine-CX complex, or I2) was evaluated by monitoring the I2 retention in a buffered PVP-I solution by UV-vis spectroscopy. Overall, experimental data showed the capability of the calix[4]arene derivative to complex iodine in solution and the solid state and a significant reduction in the iodine leaching by the PP-CX systems.


Assuntos
Calixarenos , Iodo , Povidona-Iodo , Análise Espectral , Calixarenos/química
4.
Waste Manag Res ; 41(6): 1134-1143, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-36642979

RESUMO

A reliable comparison of European Union (EU) Member States' reporting of statistics on plastic packaging waste generation, recycling and recovery is necessary if there is to be a fair transition to a circular economy across the EU. It is a priority for there to be an improvement in the quality and validity of these statistics to assess each Member State's performance in relation to EU targets. This article explores the quality of national reporting based on the two main approaches which are used to calculate packaging waste generation, namely 'placed on the market' and 'waste analysis'. The findings outline how Member States apply a variety of approaches leading to different packaging waste statistics which makes reported data difficult to compare. Often, it is not clear what approach is applied in different counties. Factors such as freeriding, non-compliance and de minimis have represented the primary weaknesses in evaluating and reporting packaging waste statistics as producers have financial incentives for under-reporting. This article highlights the need to inform circular economy strategies by addressing the challenge of comparing data on packaging and plastic packaging waste generation across the EU.


Assuntos
Plásticos , Gerenciamento de Resíduos , Europa (Continente) , Embalagem de Produtos , União Europeia , Reciclagem
5.
J Mater Cycles Waste Manag ; : 1-17, 2023 Apr 24.
Artigo em Inglês | MEDLINE | ID: mdl-37360950

RESUMO

The circularity of plastic packaging waste (PPW) material via recycling is critical to its circular economy towards sustainability and carbon neutrality of society. The multi-stakeholders and complex waste recycling loop of Rayong Province, Thailand, is herein analysed using an actor-network theory to identify key actors, roles, and responsibilities in the recycling scheme. The results depict the relative function of three-actor networks, namely policy, economy, and societal networks, which play different roles in PPW handling from its generation through various separations from municipal solid wastes to recycling. The policy network comprises mainly national authorities and committees responsible for targeting and policymaking for local implementation, while economic networks are formal and informal actors acting for PPW collection with a recycling contribution of 11.3-64.1%. A societal network supports this collaboration for knowledge, technology, or funds. Two waste recycling models are classified as community-based and municipality-based management, which functions differently by coverage areas, capabilities, and process efficiency. The economic reliability of each informal sorting activity is a crucial factor for sustainability, while empowering people in environmental awareness and sorting ability at the household level is also essential, as well as law enforcement that is effective in the long-term circularity of the PPW economy.

6.
Crit Rev Food Sci Nutr ; 62(4): 957-979, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-33081493

RESUMO

Plastic packaging materials (PPMs) protect food from contamination, maintain quality, and ease transportation and distribution. Additives included during the manufacturing and processing of PPMs improve flexibility, durability, barrier properties, and sometimes aid the processing itself. During processing, these additives, even the monomers used to produce the plastics, can produce side products or breakdown products as a result of degradation and various chemical reactions. These starting substances and reaction products include 2,2-bis(4-hydroxyphenyl)propane (bisphenol A), phthalates/phthalic acid esters, alkylphenols, and bis(2-ethylhexyl) adipate, which are considered endocrine-disrupting chemicals (EDCs) that may interfere with the human endocrine system and produce adverse reproductive, neurological, developmental, and immune effects. When in contact with food, EDCs can migrate into food if conditions are appropriate, thereby possibly jeopardizing food safety. Chemical risk assessment and regulatory control were developed to reduce human exposure to harmful migrated EDCs. This article gives an overview of the migration of EDCs from PPMs and control measures to reduce the risk of adverse impacts on human health.


Assuntos
Disruptores Endócrinos , Disruptores Endócrinos/toxicidade , Alimentos , Embalagem de Alimentos , Humanos , Plásticos/toxicidade , Medição de Risco
7.
Environ Sci Technol ; 56(12): 8416-8427, 2022 06 21.
Artigo em Inglês | MEDLINE | ID: mdl-35584204

RESUMO

Plastic packaging material is widely used to package high-temperature soup food in China, but this combination might lead to increased exposure to phthalates. The health effects and potential biological mechanisms have not been well studied. This study aimed to examine urinary phthalate metabolites and the expression of inflammatory cytokines in the blood before, during, and after a "plastic-packaged high-temperature soup food" dietary intervention in healthy adults. The results showed that compared with those in the preintervention period, urinary creatinine-adjusted levels of monomethyl phthalate (MMP), mono-n-butyl phthalate (MBP), mono-isobutyl phthalate (MIBP), and total phthalate metabolites in the intervention period were significantly higher, with increases of 71.6, 41.8, 38.8, and 29.8% for MMP, MBP, MIBP, and the total phthalate metabolites, respectively. After intervention, the mean levels of IL-1ß, IL-4, and TNF-α mRNA increased by 19.0, 21.5, and 25.0%, respectively, while IL-6 and IFN-γ mRNA decreased by 24.2 and 32.9%, respectively, when compared with the preintervention period. We also observed that several phthalates were associated with the mRNA or protein expression of IL-8, TNF-α, and IL-10. Therefore, consumption of plastic-packaged high-temperature soup food was linked to increased phthalate exposure and might result in significant changes in mRNA expression of several inflammatory cytokines.


Assuntos
Poluentes Ambientais , Ácidos Ftálicos , Adulto , Carga Corporal (Radioterapia) , Exposição Ambiental/análise , Poluentes Ambientais/metabolismo , Humanos , Plásticos , RNA Mensageiro , Temperatura , Fator de Necrose Tumoral alfa
8.
Food Control ; 136: 108845, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-35075333

RESUMO

Countries continue to debate the need for decontamination of cold-chain food packaging to reduce possible severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) fomite transmission among frontline workers. While laboratory-based studies demonstrate persistence of SARS-CoV-2 on surfaces, the likelihood of fomite-mediated transmission under real-life conditions is uncertain. Using a quantitative microbial risk assessment model of a frozen food packaging facility, we simulated 1) SARS-CoV-2 fomite-mediated infection risks following worker exposure to contaminated plastic packaging; and 2) reductions in these risks from masking, handwashing, and vaccination. In a frozen food facility without interventions, SARS-CoV-2 infection risk to a susceptible worker from contact with contaminated packaging was 1.5 × 10-3 per 1h-period (5th - 95th percentile: 9.2 × 10-6, 1.2 × 10-2). Standard food industry infection control interventions, handwashing and masking, reduced risk (99.4%) to 8.5 × 10-6 risk per 1h-period (5th - 95th percentile: 2.8 × 10-8, 6.6 × 10-5). Vaccination of the susceptible worker (two doses Pfizer/Moderna, vaccine effectiveness: 86-99%) with handwashing and masking reduced risk to 5.2 × 10-7 risk per 1h-period (5th - 95th percentile: 1.8 × 10-9, 5.4 × 10-6). Simulating increased transmissibility of current and future variants (Delta, Omicron), (2-, 10-fold viral shedding) among a fully vaccinated workforce, handwashing and masking continued to mitigate risk (1.4 × 10-6 - 8.8 × 10-6 risk per 1h-period). Additional decontamination of frozen food plastic packaging reduced infection risks to 1.2 × 10-8 risk per 1h-period (5th - 95th percentile: 1.9 × 10-11, 9.5 × 10-8). Given that standard infection control interventions reduced risks well below 1 × 10-4 (World Health Organization water quality risk thresholds), additional packaging decontamination suggest no marginal benefit in risk reduction. Consequences of this decontamination may include increased chemical exposures to workers, food quality and hazard risks to consumers, and unnecessary added costs to governments and the global food industry.

9.
Bull Environ Contam Toxicol ; 106(2): 237-240, 2021 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-33515068

RESUMO

Plastic pollution control has been on top of the political agenda in China. In January 2020, China announced a phased ban on the production and usage of various types of single-use plastics as a solution to environmental pollution problems. However, the outbreak of COVID-19 seems to be a new obstacle to the ban on single-use plastic products. To basically satisfied the daily necessities and contain the spread of SARS-CoV-2 under the background of the regular epidemic prevention and control in China, online ordering, contactless delivery and wearing mask have become an important and feasible way of daily life. However, the unrestrained use of disposable plastic bags, lunch boxes and masks within the nationwide quarantine leads to hundreds of millions of plastics wastes every day. The potential environmental pollution caused by the use of disposable plastic products during the pandemic should arouse social concern. The Chinese government should manage environmental protection in parallel with anti-pandemic endeavors as the situation of the pandemic evolves.


Assuntos
COVID-19 , Pandemias , China/epidemiologia , Humanos , Plásticos , SARS-CoV-2
10.
Molecules ; 25(9)2020 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-32366050

RESUMO

Most container-content interaction studies are carried out through migration tests on end products or simulants involving generally toxic solvents. This study was conducted with the aim of identifying potential leachables from materials used in cosmetic plastic packaging by using two approaches based on solvent-free extraction, i.e., solid-phase microextraction sampling and pyrolyzer/thermal desorption coupled with gas chromatography mass spectrometry. Volatile and semi-volatile intentionally and non-intentionally added substances were detected in seven packaging samples made of polypropylene, polyethylene, and styrene-acrylonitrile copolymer. Thirty-five compounds related to the polymers industry or packaging industry were identified, among them phthalates, alkanes, styrene, and cyanide derivates including degradation products, impurities, additives, plasticizers, and monomers. All except eight belong to the Cramer class I. These thermodesorption techniques are complementary to those used for migration tests.


Assuntos
Cosméticos/análise , Cromatografia Gasosa-Espectrometria de Massas , Plásticos/química , Pirólise , Cosméticos/química , Química Verde , Estrutura Molecular , Microextração em Fase Sólida
11.
Food Microbiol ; 57: 172-7, 2016 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-27052716

RESUMO

In this study, the efficacy of using UV-C light to inactivate sliced cheese inoculated with Escherichia coli O157:H7, Salmonella Typhimurium, and Listeria monocytogenes and, packaged with 0.07 mm films of polyethylene terephthalate (PET), polyvinylchloride (PVC), polypropylene (PP), and polyethylene (PE) was investigated. The results show that compared with PET and PVC, PP and PE films showed significantly reduced levels of the three pathogens compared to inoculated but non-treated controls. Therefore, PP and PE films of different thicknesses (0.07 mm, 0.10 mm, and 0.13 mm) were then evaluated for pathogen reduction of inoculated sliced cheese samples. Compared with 0.10 and 0.13 mm, 0.07 mm thick PP and PE films did not show statistically significant reductions compared to non-packaged treated samples. Moreover, there were no statistically significant differences between the efficacy of PP and PE films. These results suggest that adjusted PP or PE film packaging in conjunction with UV-C radiation can be applied to control foodborne pathogens in the dairy industry.


Assuntos
Queijo/microbiologia , Queijo/efeitos da radiação , Escherichia coli O157/efeitos da radiação , Irradiação de Alimentos/métodos , Listeria monocytogenes/efeitos da radiação , Plásticos/química , Salmonella typhimurium/efeitos da radiação , Escherichia coli O157/crescimento & desenvolvimento , Contaminação de Alimentos/prevenção & controle , Embalagem de Alimentos/instrumentação , Listeria monocytogenes/crescimento & desenvolvimento , Plásticos/efeitos da radiação , Salmonella typhimurium/crescimento & desenvolvimento , Raios Ultravioleta
12.
Polymers (Basel) ; 16(8)2024 Apr 11.
Artigo em Inglês | MEDLINE | ID: mdl-38674986

RESUMO

The recycling of plastic packaging wastes helps to alleviate the problems of white pollution and resource shortage. It is very necessary to develop high-value conversion technologies for plastic packaging wastes. To our knowledge, carbon materials with excellent properties have been widely used in energy storage, adsorption, water treatment, aerospace and functional packaging, and so on. Waste plastic packaging and biomass materials are excellent precursor materials of carbon materials due to their rich sources and high carbon content. Thus, the conversion from waste plastic packaging and biomass materials to carbon materials attracts much attention. However, closely related reviews are lacking up to now. In this work, the pyrolysis routes of the pyrolysis of plastic packaging wastes and biomass materials for conversion to high-value carbons and the influence factors were analyzed. Additionally, the applications of these obtained carbons were summarized. Furthermore, the limitations of the current pyrolysis technology are put forward and the research prospects are forecasted. Therefore, this review can provide a useful reference and guide for the research on the pyrolysis of plastic packaging wastes and biomass materials and the conversion to high-value carbon.

13.
Food Chem ; 443: 138567, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38295567

RESUMO

In this work, assessment of microplastics (MPs) in commercial vegetable edible oils from Italy and Spain, including extra-virgin olive oil, olive oil, sunflower oil, and mixed seed oil, has been conducted for the first time. The method was based on sample dilution with ethanol:n-hexane (1:3, v/v), homogenization, vacuum filtration on macroporous silicon filters with 5 µm pore diameter to collect MPs, and automatic µ-FTIR spectroscopy for MPs detection and characterization. In the analysis of oil samples, a mean MPs abundance of 1140 ± 350 MPs/L was found. Observed MPs were characterized, being most of them fragments (81.2 %), with particle sizes < 100 µm (77.5 %), and mainly composed of polyethylene (50.3 %) and polypropylene (28.7 %), among others. Statistical analysis revealed that there were not significant differences (p-value > 0.05) in the abundance of MPs between oil samples or types.


Assuntos
Óleos de Plantas , Verduras , Óleos de Plantas/química , Microplásticos , Plásticos , Espanha , Azeite de Oliva/química , Itália
14.
Sci Total Environ ; 946: 174000, 2024 Oct 10.
Artigo em Inglês | MEDLINE | ID: mdl-38901589

RESUMO

Plastic overproduction and the resulting increase in consumption has made plastic pollution ubiquitous in all ecosystems. Recognizing this, the United Nations (UN) has started negotiations to establish a global treaty to end plastic pollution, especially in the marine environment. The basis of the treaty has been formulated in terms of turning off the tap, signaling the will to prevent plastic pollution at its source. Based on the distribution of plastic production by sector, the plastic packaging sector consumes the most plastic. The volume and variety of chemicals used in plastic packaging, most of which is single-use, is a major concern. Single-use plastics including packaging is one of the most dominant sources of plastic pollution. Plastic waste causes pollution in water, air and soil by releasing harmful chemicals into the environment and can also lead to exposure through contamination of food with micro- and nano-plastic particles and chemicals through packaging. Marine life and humans alike face risks from plastic uptake through bioaccumulation and biomagnification. While the contribution of plastics ingested to chemical pollution is relatively minor in comparison to other pathways of exposure, the effect of plastic waste on marine life and human consumption of seafood is beyond question. To reduce the long-term impact of plastic, it is crucial to establish a global legally binding instrument to ensure the implementation of upstream rather than downstream solutions. This will help to mitigate the impact of both chemicals and microplastics, including from packaging, on the environment.


Assuntos
Microplásticos , Plásticos , Poluentes Químicos da Água , Microplásticos/análise , Plásticos/análise , Poluentes Químicos da Água/análise , Monitoramento Ambiental , Medição de Risco , Humanos
15.
Materials (Basel) ; 17(8)2024 Apr 17.
Artigo em Inglês | MEDLINE | ID: mdl-38673212

RESUMO

The properties of recycled post-consumer rigid polyethylene packaging waste were studied, using sorted waste washed in the laboratory with water alone and with added detergent, and compared with large-scale high-intensity washed flakes. The washed flakes were compounded using three different temperature profiles in a twin-screw extruder and then injection molded. A higher compounding temperature reduced the thermo-oxidative stability, the average molecular mass, and the viscosity of the samples. Rheological measurements suggested that changes in chain branching occurred at different compounding temperatures. The strength and the elongation at break were also influenced by the compounding temperature in both the molten and solid states. Detergent washing maintained the thermo-oxidative stability in contrast to washing with water. The large-scale washed samples had a relatively high thermo-oxidative stability, a higher melt elasticity, and a lower elongation at break in both the molten and solid states than the laboratory-scale washed samples. The thermal properties, melt elasticity, Young's modulus, yield stress, and yield strain of the samples were not, however, significantly affected by either the compounding temperature or the washing medium and intensity. The results indicated that recycled post-consumer rigid polyethylene packaging waste has properties that can support further applications in new products.

16.
Waste Manag ; 174: 371-381, 2024 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-38101233

RESUMO

Patterns and effects of delivery food waste (DFW) in small cities remain unknown. Therefore, a case study was, for the first time conducted targeting residents of a typical small city (Jiuquan, China) using direct weighing (511 samples or 843 orders) and a questionnaire survey (471 samples). The results showed that the vast majority of DFW was avoidable (approximately 79 % of the total), meaning a high level of wasting food derived from residents for such a small city, and the associated emission of avoidable DFW was primarily attributed to its upstream stage (approximately 81 % of the total), indicating that it is more significant environmental benefit in the prevention and reducing waste than its final management. The amount of DFW generated by urban residents was significantly higher than that of township residents (213 ± 132 vs 145 g/cap/order, P < 0.01), and age was found to be the most important factor determining DFW, especially in groups II & III (20-30 and 30-40 years old). Thus, mitigation strategies targeting young urban residents have the greatest overall effect. Plastic packaging waste also represents a large component of total DFW (19 %), and replacing plastic tableware with sharing tableware can be an effective waste reduction strategy.


Assuntos
Eliminação de Resíduos , Eliminação de Resíduos/métodos , Alimentos , Perda e Desperdício de Alimentos , Cidades , China
17.
Waste Manag ; 180: 9-22, 2024 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-38503033

RESUMO

Austria must recycle more packaging materials. Especially for plastic packaging waste, significant increases are necessary to reach the EU recycling targets for 2025 and 2030. In addition to improving separate collection and introducing a deposit system for specific fractions, the share of plastic packaging in mixed municipal solid waste (MSW) could be utilized. In Austria, about 1.8milliontonnes of mixed MSW are generated. This includes about 110,000 t/a of plastic packaging waste. Most of the mixed MSW (94 %) is sent directly or via residues from pre-treatment, such as mechanical-biological treatment or waste sorting, to waste incineration. While materials such as glass and metals can also be recovered from the bottom ash, combustible materials such as plastics must be recovered before incineration. This work aims to evaluate the recovery potential of plastic packaging waste in mixed MSW with automated waste sorting. For this purpose, two of the largest Austrian waste sorting plants, with a total annual throughput of about 280,000 t/a, were investigated. The investigation included regular sampling of selected output streams and sorting analysis. The results show that the theoretical recovery potential of plastic packaging from these two plants is 6,500 t/a on average. An extrapolation to Austria results in a potential of about 83,000 t/a. If losses due to further treatment, such as sorting and recycling, are considered, about 30,000 t/a of recyclate could be returned to plastic production. This would correspond to an increase in plastic packaging recycling rate from 25 % to 35 %.


Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Resíduos Sólidos , Eliminação de Resíduos/métodos , Áustria , Plásticos , Reciclagem/métodos , Embalagem de Produtos
18.
Waste Manag ; 178: 135-143, 2024 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-38401427

RESUMO

Whether plastic packaging waste is disposed of in different bins (source separation, S) or in a single bin (post source separation, P) is generally assumed to impact the waste stream's quality. To elucidate this question, we evaluated the quality of LDPE, HDPE, and PP plastic waste from both separation systems (S and P) through a concise analytical strategy. The materials received similar treatment after collection (e.g., washing, NIR-sorting). A multivariate approach to ATR-FTIR spectroscopy was developed to assess their material composition and the effect of washing. Results were complemented by TGA, DSC, and py-GC/MS analysis. The material performance was investigated by a lab-scale extrusion and granulation, followed by an assessment of the mechanical properties and the melt volume rate. Our study reveals the HDPE materials to be of good quality, regardless of their source. For LDPE and PP, the P-materials are fractionally more contaminated after washing. Both PP-materials display poor material performance with highly fluctuating elongations-at-break (between 30% and 380%). S-LDPE was found to contain more polymeric impurities than P-LDPE. We conclude that the quality depends strongly on the material type and on the treatment after collection (washing, sorting). The multivariate approach to FTIR data evaluation we propose aims at simplifying the quality evaluation of polyolefin waste plastics and may serve as a basis for future work in this field.


Assuntos
Plásticos , Reciclagem , Polietileno , Espectroscopia de Infravermelho com Transformada de Fourier , Polímeros , Embalagem de Produtos
19.
Environ Pollut ; 323: 121197, 2023 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-36736818

RESUMO

The occurrence of microplastic contaminants in food intended for human consumption has been widely explored. Yet, investigations on plastic and other particle debris in baby food packaging remain scarce to date. Our study shows the release of abundant micro-sized and submicron-sized particles, floccules (<300 µm), and fragments (1-50 µm) during the simulated use of commercially available single-use breastmilk storage bags. Six best-selling products of breastmilk storage bags were selected in our study. Most of the particles released from breastmilk storage bags that were identified as plastics were found to be polyethylene (PE), polyethylene terephthalate (PET), and nylon-6 using micro-Raman spectroscopy. The weight of the particles released from three randomly selected bags of the same product type was determined to be in the range of 0.22 and 0.47 mg. Submicron-sized particles (<0.8 µm) with irregular spherical or oval shapes were present. Microplastics and other particles ingested by infants from the use of breastmilk storage bags were estimated to be 0.61-0.89 mg/day based on the average daily breastmilk intake by infants. This study provides new insights into the exposure to microplastics and other particle debris in commonly used infant products.


Assuntos
Microplásticos , Poluentes Químicos da Água , Lactente , Humanos , Plásticos , Leite Humano/química , Monitoramento Ambiental , Poluentes Químicos da Água/análise
20.
Adv Food Nutr Res ; 103: 313-359, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-36863838

RESUMO

Microplastics from food packaging material have risen in number and dispersion in the aquatic system, the terrestrial environment, and the atmosphere in recent decades. Microplastics are of particular concern due to their long-term durability in the environment, their great potential for releasing plastic monomers and additives/chemicals, and their vector-capacity for adsorbing or collecting other pollutants. Consumption of foods containing migrating monomers can lead to accumulation in the body and the build-up of monomers in the body can trigger cancer. The book chapter focuses the commercial plastic food packaging materials and describes their release mechanisms of microplastics from packaging into foods. To prevent the potential risk of microplastics migrated into food products, the factors influencing microplastic to the food products, e.g., high temperatures, ultraviolet and bacteria, have been discussed. Additionally, as many evidences shows that the microplastic components are toxic and carcinogenic, the potential threats and negative effects on human health have also been highlighted. Moreover, future trends is summarized to reduce the microplastic migration by enhancing public awareness as well as improving waste management.


Assuntos
Poluentes Ambientais , Microplásticos , Humanos , Microplásticos/toxicidade , Plásticos , Embalagem de Alimentos , Carcinogênese
SELEÇÃO DE REFERÊNCIAS
DETALHE DA PESQUISA