A sonochemical assisted synthesis of hollow sphere structured tin (IV) oxide on graphene oxide sheets for the low-level detection of environmental pollutant mercury in biological samples and foodstuffs.

In modern approaches for nanomaterials synthesis, ultrasonication plays an important role in providing the larger surface area and smaller crystalline size properties that are favorable to electrochemical techniques. Herein, we report the tin (IV) oxide on graphene oxide nanoparticles were synthesized (SnO2@GO NPs) by ultrasonic methodology (UZ SONOPULS HD 3400 Ultrasonic homogenizer) with the total power of 400 W and the (frequency of 20 kHz; 140 W/dm3). The formation of as-prepared SnO2@GO NPs and its surface morphology were scrutinized over XRD, XPS, TEM, and FESEM. Besides, the sonochemically prepared SnO2@GO NPs were employed for the determination of environmental hazardous mercury (Hg). As a result, the modified electrode acquired a very low-level detection limit of 1.2 nM with a wider range of 0.01-10.41-µM and 14.52-225.4-µM for the detection of Hg. Finally, the practical applicability of SnO2@GO NPs in spiked human blood serum and tuna fish samples shows appreciable found and recovery values. .

Survival assessment of simple food webs for dye wastewater after photocatalytic degradation using SnO2/GO nanocomposites under sunlight irradiation.

The release of textile effluent into the natural waters poses a serious threat to the aquatic ecosystem. Here, SnO2/GO nanocomposites were synthesized with tunable morphology by the addition of GO with a sonochemical method. The material was characterized using X-ray Diffraction (XRD), scanning electronic microscopy (SEM), Ultraviolet-visible spectroscopy (UV-vis), and infrared spectrometry (IR). The photocatalytic degradation of Rhodamine B (RhB) and textile dye wastewater (TDW) using SnO2/GO nanocomposites was studied under sunlight irradiation. The SnO2/GO nanocomposites exhibited high photocatalytic activity towards the degradation of RhB and TDW with up to 95% removal efficiency. The catalyst dosage, concentration variation, and reusability of the catalyst were also examined to optimize the reaction conditions for the degradation of dye. Bioassays were used to investigate the survival growth rate of simple food webs such as Chlorella pyrenoidosa (CP), Artemia salina (AS) and Danio rerio (DR) in the treated and untreated solution. These simple food web model animals showed good reliability for analyzing the toxicity of the treated and untreated wastewater. Further, histology was analyzed to find out the influence of the dye solution in the animal model. These results suggest that the SnO2/GO nanocomposite shows promising efficiency in the wastewater treatment, which is further confirmed in the toxicity analysis.