Fabrication of Activated Carbon Decorated with ZnO Nanorod-Based Electrodes for Desalination of Brackish Water Using Capacitive Deionization Technology.

Capacitive deionization (CDI) is a promising and cost-effective technology that is currently being widely explored for removing dissolved ions from saline water. This research developed materials based on activated carbon (AC) materials modified with zinc oxide (ZnO) nanorods and used them as high-performance CDI electrodes for water desalination. The as-prepared electrodes were characterized by cyclic voltammetry, and their physical properties were studied through SEM and XRD. ZnO-coated AC electrodes revealed a better specific absorption capacity (SAC) and an average salt adsorption rate (ASAR) compared to pristine AC, specifically with values of 123.66 mg/g and 5.06 mg/g/min, respectively. The desalination process was conducted using a 0.4 M sodium chloride (NaCl) solution with flow rates from 45 mL/min to 105 mL/min under an applied potential of 1.2 V. Furthermore, the energy efficiency of the desalination process, the specific energy consumption (SEC), and the maximum and minimum of the effluent solution concentration were quantified using thermodynamic energy efficiency (TEE). Finally, this work suggested that AC/ZnO material has the potential to be utilized as a CDI electrode for the desalination of saline water.

Effect of fuel preheating on performance, emission and combustion characteristics of a diesel engine fuelled with Vateria indica methyl ester blends at various loads.

The present study examines the preheated (95 °C) and unheated (35 °C) Vateria indica methyl ester (VIME) blends by studying the engine performance, combustion, and emission characteristics at various loads. A single-cylinder, TV1 Kirloskar direct injection diesel engine is used to carry out the tests. Biodiesel produced from Dhupa fat through the transesterification process is used as a renewable fuel in a diesel engine. In this work, diesel (B0), VIME (B100), and two binary blends (B30 and B50) are used. VIME has a higher viscosity, higher density, and lower calorific value than diesel, resulting in lesser brake thermal efficiency (BTE) and higher brake specific energy consumption (BSEC). Due to high viscosity of the biodiesel, preheating of fuel is done before injecting into cylinder. Preheating reduces the viscosity, and enhances the atomization and vaporization of fuel, resulting in improved engine performance. For a given blend of VIME biodiesel and diesel, the preheated blend has better BTE, decreased BSEC and lesser CO and HC emissions, with a slight increment in NOX emission compared to the unheated blend. The preheated B30 blend has a BTE value of 30.3% which is close to the BTE value of 30.1% of unheated diesel at 100% load condition. CO, HC, and soot emissions are decreased by 16.2%, 34.4%, and 16.5%, respectively, for preheated B100 fuel compared to unheated B100, at full load.

Degradation of hydroxychloroquine by electrochemical advanced oxidation processes.

In this work, the degradation of hydroxychloroquine (HCQ) drug in aqueous solution by electrochemical advanced oxidation processes including electrochemical oxidation (EO) using boron doped diamond (BDD) and its combination with UV irradiation (photo-assisted electrochemical oxidation, PEO) and sonication (sono-assisted electrochemical oxidation, SEO) was investigated. EO using BDD anode achieved the complete depletion of HCQ from aqueous solutions in regardless of HCQ concentration, current density, and initial pH value. The decay of HCQ was more rapid than total organic carbon (TOC) indicating that the degradation of HCQ by EO using BDD anode involves successive steps leading to the formation of organic intermediates that end to mineralize. Furthermore, the results demonstrated the release chloride (Cl-) ions at the first stages of HCQ degradation. In addition, the organic nitrogen was converted mainly into NO3 - and NH4 + and small amounts of volatile nitrogen species (NH3 and NOx). Chromatography analysis confirmed the formation of 7-chloro-4-quinolinamine (CQLA), oxamic and oxalic acids as intermediates of HCQ degradation by EO using BDD anode. The combination of EO with UV irradiation or sonication enhances the kinetics and the efficacy of HCQ oxidation. PEO requires the lowest energy consumption (EC) of 63 kWh/m3 showing its cost-effectiveness. PEO has the potential to be an excellent alternative method for the treatment of wastewaters contaminated with HCQ drug and its derivatives.

Mineralization of pyrrole, a recalcitrant heterocyclic compound, by electrochemical method: Multi-response optimization and degradation mechanism.

In this study, the electrochemical (EC) oxidation of a recalcitrant heterocyclic compound namely pyrrole has been reported using platinum coated titanium (Pt/Ti) electrodes. Response surface methodology (RSM) comprising of full factorial central composite design (CCD) with four factors and five levels has been used to examine the effects of different operating parameters such as current density (j), aqueous solution pH, conductivity (k) and treatment time (t) in an EC batch reactor. Pyrrole mineralization in aqueous solution was examined with multiple responses such as chemical oxygen demand (COD) (response, Y1) and specific energy consumption (SEC) in kWh/kg of COD removed (response, Y2). During multiple response optimization, the desirability function approach was employed to concurrently maximize Y1 and minimize Y2. At the optimum condition, 82.9% COD removal and 7.7 kWh/kg of COD removed were observed. Degradation mechanism of pyrrole in wastewater was elucidated at the optimum condition of treatment by using UV-visible spectroscopy, Fourier transformed infra-red spectroscopy (FTIR), cyclic voltammetry (CV), ion chromatography (IC), higher performance liquid chromatography (HPLC) and gas chromatography-mass spectroscopy (GC-MS). The degradation pathway of pyrrole was proposed on the basis of the various analysis.

Performance of a convective, infrared and combined infrared- convective heated conveyor-belt dryer.

A conveyor-belt dryer was developed using a combined infrared and hot air heating system that can be used in the drying of fruits and vegetables. The drying system having two chambers was fitted with infrared radiation heaters and through-flow hot air was provided from a convective heating system. The system was designed to operate under either infrared radiation and cold air (IR-CA) settings of 2000 W/m(2) with forced ambient air at 30 °C and air flow of 0.6 m/s or combined infrared and hot air convection (IR-HA) dryer setting with infrared intensity set at 2000 W/m(2) and hot at 60 °C being blown through the dryer at a velocity of 0.6 m/s or hot air convection (HA) at an air temperature of 60 °C and air flow velocity 0.6 m/s but without infrared heating. Apple slices dried under the different dryer settings were evaluated for quality and energy requirements. It was found that drying of apple (Golden Delicious) slices took place in the falling rate drying period and no constant rate period of drying was observed under any of the test conditions. The IR-HA setting was 57.5 and 39.1 % faster than IR-CA and HA setting, respectively. Specific energy consumption was lower and thermal efficiency was higher for the IR-HA setting when compared to both IR-CA and HA settings. The rehydration ratio, shrinkage and colour properties of apples dried under IR-HA conditions were better than for either IR-CA or HA.

Integration of capacitive deionization and forward osmosis for high water recovery and ultrapure water production: concept, modelling and performance analysis.

Forward Osmosis (FO), a membrane desalination technology and Capacitive Deionization (CDI), an electrically operated desalination technology, are numerically integrated utilizing four different configurations for the high-water recovery rate and ultrapure water production from brackish water resource. To minimize the wastewater rejection, the CDI desorption stream is continuously fed to the FO unit, efficiently recovering the remaining freshwater. To produce ultrapure water, freshwater stream obtained from FO is provided to the CDI cell, which adsorbs the remaining dissolved solute particles. These two configurations serve the purpose of both industrial as well as domestic water supply requirements. Continuing this concept, the formation of the other two configurations allows us to obtain fresh water and ultrapure water simultaneously and up to a 90% freshwater recovery rate for the areas with inadequate supply. The performance parameters to assess the integration are the Water Recovery Rate (WRR) and Specific Energy Consumption (SEC). The first configuration (CDI-FO), proposed for a high freshwater recovery rate, resulted in 79.33% WRR with an SEC of 0.689kWh/m3. While, for the second configuration (FO-CDI), 34.25% water was recovered as 2.87 ppm ultrapure water along with 34.25% freshwater. The third proposed configuration (CDI-FO-CDI) had a WRR of 79.33%, 14.67% of which was recovered as ultrapure water of concentration 2.86 ppm. The fourth configuration (CDI-FO-FO) developed for high water recovery, removed the maximum of water from the feed stream with a WRR of 91.33% and remained energy-efficient, consuming an SEC of 0.908kWh/m3.

Optimizing electricity generation through the utilization of wasted heat from process streams in a LURGI methanol plant.

In the realm of petrochemical operations, persistent efforts have been made to curtail specific energy consumption; however, certain heat sources continue to be underutilized. This paper investigates the condition of a Lurgi methanol plant to identify process streams with enough wasted heat that have the potential to produce electricity. After a thorough analysis, one particular zone is identified where an air cooler package and seawater exchanger are used to decrease the temperature of crude methanol vapor. To harness this untapped heat for electricity generation, an organic Rankine cycle (ORC) is proposed. In the quest for efficient electricity production, three distinct working fluids-dry (R600a), wet (R134a), and isentropic (R11)- are scrutinized to compare their performance in generating electricity within the ORC system. In addition, the maximum amount of electricity that can be generated from this waste heat recovery (WHR) project is determined and optimized using a multi-objective optimization method. By leveraging genetic algorithms, the system's exergy is enhanced while minimizing costs. A comprehensive economic comparison is conducted using probability analysis to evaluate each system's financial viability. The results show that dry and isentropic working fluids yield the best results for electricity production, generating approximately 9-10 MW. The return on investment (ROI) for these working fluids is also nearly similar, at 16 %. Among the chosen working fluids, R600a is selected as the superior option due to its lower outlet temperature for crude methanol. Additionally, because the cooling water flow for the condenser of the ORC is identified as a limitation in the current petrochemical plant, a new optimization is conducted with a constraint on the flow of cooling water, aiming for approximately 3000 tons/h. The results show that the proposed WHR-ORC system can generate a maximum of approximately 7.5 MW net electricity in the studied petrochemical plant, while also reducing CO2 emissions by up to 40,000 tons per year. The innovative methodology showcased in this research underscores its economic viability, paving the way for heightened energy efficiency and environmentally conscious methanol production practices.

Impact of temperature and forward osmosis membrane properties on the concentration polarization and specific energy consumption of hybrid desalination system.

This study investigates how temperature and forward osmosis (FO) membrane properties, such as water permeability (A), solute permeability (B), and structural parameter (S), affect the specific energy consumption (SEC) of forward osmosis-reverse osmosis system. The results show that further SEC reduction beyond the water permeability of 3 LMH bar-1 is limited owing to high concentration polarization (CP). Increasing S by 10-fold increases FO recovery by 177.6%, causing SEC decreases by 33.6%. However, membrane with smaller S also increases external CP. To reduce SEC, future work should emphasize mixing strategies to reduce external CP. Furthermore, increasing the temperature from 10 to 40 °C can reduce SEC by 14.3%, highlighting the energy-saving potential of temperature-elevated systems. The factorial design indicates that at a lower temperature, increasing A and decreasing S have a more significant impact on reducing SEC. This underlines the importance of developing advanced FO membranes, particularly for lower-temperature processes.

Assessing thermoelectric membrane distillation performance: An experimental design approach.

Thermoelectric membrane distillation has shown promise as a new membrane distillation technique capable of improving energy consumption metrics. This study features an experimental design approach to investigating the performance of a thermoelectric membrane distillation system. Screening and full factorial designs were implemented in Minitab 16 to determine the optimal process conditions for minimizing the specific energy consumption of the system. The process parameter with the most significant impact on the specific energy consumption of thermoelectric membrane distillation systems was determined and a mathematical model for predicting the specific energy consumption was derived. The study showed that adjusting the feed flowrate, the most influential continuous parameter, from a sub-optimal level to an optimal level, while keeping other process variables at their optimal levels, could lead to a 34% reduction in the system's specific energy consumption. At the optimized process parameters of the thermoelectric membrane distillation system, the minimized specific energy consumption fell about 35% below the threshold value of 1,000 kWh/m3 found among the efficient membrane distillation systems in the literature.•Thermoelectric heat exchanger provides the driving force for the membrane distillation process•Seven process variables are assumed to influence the energy consumption of the distillation process•The variables are screened before being analyzed in a full factorial experimental design.

Detailed assessment of specific exergetic costing, energy consumption, and environmental impacts of a rotary kiln in cement industry.

Türkiye is one of the biggest developing countries and the second biggest cement exporter in the world. In 2021, the country exported around $1billion of cement, which is responsible for over 8% of emissions globally. In order to fulfill the EU norms, energy, emissions, and cost reduction investments continue in the country. The aim of this paper is to perform a detailed exergoeconomic assessment of a rotary burner to increase the energy and exergy performance and decrease energy consumption, exergy costs and environmental impacts of a real scale cement factory in Türkiye. During the 2-year period, detailed data has been obtained from the factory by real time detection of clinker manufacturing process. By applying the specific exergy costing (SPECO) method, energy and exergy destructions, and exergetic cost distributions for the rotary burner are calculated in detail. The 1st and 2nd law efficiencies of the overall factory, specific energy (SEC) and exergy (SExC) consumption, and SPECO for clinker production are calculated to be 59.84%, 39.04%, 4786.75 MJ/ton, 5230.38 MJ/ton, and 10.11 $/MJ, respectively. The use of magnesia-spinel composite refractory bricks and the anzast layer formation decreased the SPECO by 2.71% corresponding to a saving of $2,280,000 preventing 13.74 MtCO2 emissions yearly.

Performance of Hypersaline Brine Desalination Using Spiral Wound Membrane: A Parametric Study.

Desalination of hypersaline brine is known as one of the methods to cope with the rising global concern on brine disposal in high-salinity water treatment. However, the main problem of hypersaline brine desalination is the high energy usage resulting from the high operating pressure. In this work, we carried out a parametric analysis on a spiral wound membrane (SWM) module to predict the performance of hypersaline brine desalination, in terms of mass transfer and specific energy consumption (SEC). Our analysis shows that at a low inlet pressure of 65 bar, a significantly higher SEC is observed for high feed concentration of brine water compared with seawater (i.e., 0.08 vs. 0.035) due to the very low process recovery ratio (i.e., 1%). Hence, an inlet pressure of at least 75 bar is recommended to minimise energy consumption. A higher feed velocity is also preferred due to its larger productivity when compared with a slightly higher energy requirement. This study found that the SEC reduction is greatly affected by the pressure recovery and the pump efficiencies for brine desalination using SWM, and employing them with high efficiencies (ηR ≥ 95% and ηpump ≥ 50%) can reduce SEC by at least 33% while showing a comparable SEC with SWRO desalination (<5.5 kWh/m3).

Seawater Reverse Osmosis Performance Decline Caused by Short-Term Elevated Feed Water Temperature.

The shortage of fresh water resources has made the desalination of seawater a widely adopted technology. Seawater reverse osmosis (SWRO) is the most commonly used method for desalination. The SWRO process is energy-intensive, and most of the energy in SWRO is spent on pressurizing the seawater to overcome the osmotic barrier for producing fresh water. The pressure needed depends on the salinity of the seawater, its temperature, and the membrane surface properties. Membrane compaction occurs in SWRO due to hydraulic pressure application for long-term operations and operating temperature fluctuations due to seasonal seawater changes. This study investigates the effects of short-term feed water temperature increase on the SWRO process in a full-scale pilot with pretreatment and a SWRO installation consisting of a pressure vessel which contains seven industrial-scale 8" diameter spiral wound membrane elements. A SWRO feed water temperature of 40 °C, even for a short period of 7 days, caused a permanent performance decline illustrated by a strong specific energy consumption increase of 7.5%. This study highlights the need for membrane manufacturer data that account for the water temperature effect on membrane performance over a broad temperature range. There is a need to develop new membranes that are more tolerant to temperature fluctuations.

Minimizing Specific Energy Consumption of Electrochemical Hydrogen Compressor at Various Operating Conditions Using Pseudo-2D Model Simulation.

With the increased usage of hydrocarbon-based fossil fuels, air pollution and global warming have accelerated. To solve this problem, renewable energy, such as hydrogen technology, has gained global attention. Hydrogen has a low volumetric density and thus requires compression technologies at high pressures to reduce storage and transportation costs. Techniques for compressing hydrogen include using mechanical and electrochemical hydrogen compressors. Mechanical compressors require higher specific energy consumption than electrochemical hydrogen compressors. Here, we used an electrochemical hydrogen compressor as a pseudo-two-dimensional model focused on electroosmotic drag, water back-diffusion, and hydrogen crossover flux at various temperatures, polymer electrolyte membrane thicknesses, and relative humidity conditions. To date, there have been few studies based on various operating conditions to find the optimal conditions. This study was conducted to determine the optimal parameters under various operating conditions. A numerical analysis demonstrated that the specific energy consumption was low in a specific current density section when the temperature was decreased. At the above-mentioned current density, the specific energy consumption decreased as the temperature increased. The polymer electrolyte membrane thickness yielded similar results. However, according to the relative humidity, it was confirmed that the higher the relative humidity, the lower the specific energy consumption in all of the current density sections. Therefore, when comparing temperatures of 30 °C and 80 °C at 145 A/m2, operating at 30 °C reduces the specific energy consumption by 12.12%. At 3000 A/m2 and 80 °C, the specific energy consumption is reduced by 11.7% compared to operating at 30 °C. Using N117 compared to N211 at 610 A/m2 for polymer electrolyte membranes can reduce specific energy consumption by 10.4%. Using N211 in the 1500 A/m2 condition reduces the specific energy demand by 9.6% compared to N117.

Employing electro-peroxone process for degradation of Acid Red 88 in aqueous environment by Central Composite Design: A new kinetic study and energy consumption.

The Azo dyes are primarily employed in textile industries to produce high amounts of colored organic and inorganic wastewater. Therefore, their treatments are critical. In this research, the removal and mineralization of Acid red 88 (AR88), as a widely used mono Azo dye, was inspected by the Electro-peroxone(E-peroxone) method. It is a coupling of electrochemically produced H2O2 and ozone that can produce robust hydroxyl radicals. The Central Composite Design (CCD) was applied to explore the influence of operational variables on the removal of AR88 as a response. The optimal conditions predicted by the CCD were as the following; Applied current at 0.7 A, pH at 7.35, O3 Flowrate at 1.03 L min-1 and the concentration of AR88 at 527.29 mg. L-1. The Pareto chart showed that the concentration of AR88 has a significant influence on the response. At the predicted optimal conditions, the actual and predicted AR 88 removal were 95.4 and 92.96%, respectively. The removal of COD after 45 min was 70% representing the excessive efficiency of E-peroxone in mineralization of AR88. The E-peroxone follows the pseudo-first-order kinetics (kobs-E-peroxone = 6.56 × 10-2 min-1), which was more remarkable than the single ozonation, and electrolysis. The calculated specific energy consumption (SEC) in the E-peroxone was 40.14 kWh/Kg AR 18 removal, which was lower than the individual ozonation, and electrolysis methods. The operative production of H2O2 from O2 at the cathode is the critical factor in the high removal of AR88 in this process.

Long-Term Treatment of Highly Saline Brine in a Direct Contact Membrane Distillation (DCMD) Pilot Unit Using Polyethylene Membranes.

Membrane distillation (MD) is an attractive separation process for wastewater treatment and desalination. There are continuing challenges in implementing MD technologies at a large industrial scale. This work attempts to investigate the desalination performance of a pilot-scale direct contact membrane distillation (DCMD) system using synthetic thermal brine mimicking industrial wastewater in the Gulf Cooperation Council (GCC). A commercial polyethylene membrane was used in all tests in the DCMD pilot unit. Long-term performance exhibited up to 95.6% salt rejection rates using highly saline feed (75,500 ppm) and 98% using moderate saline feed (25,200 ppm). The results include the characterization of the membrane surface evolution during the tests, the fouling determination, and the assessment of the energy consumption. The fouling effect of the polyethylene membrane was studied using Humic acid (HA) as the feed for the whole DCMD pilot unit. An optimum specific thermal energy consumption (STEC) reduction of 10% was achieved with a high flux recovery ratio of 95% after 100 h of DCMD pilot operation. At fixed operating conditions for feed inlet temperature of 70 °C, a distillate inlet temperature of 20 °C, with flowrates of 70 l/h for both streams, the correlations were as high as 0.919 between the pure water flux and water contact angle, and 0.963 between the pure water flux and salt rejection, respectively. The current pilot unit study provides better insight into existing thermal desalination plants with an emphasis on specific energy consumption (SEC). The results of this study may pave the way for the commercialization of such filtration technology at a larger scale in global communities.

Evaluation of the Specific Energy Consumption of Sea Water Reverse Osmosis Integrated with Membrane Distillation and Pressure-Retarded Osmosis Processes with Theoretical Models.

In this study, theoretical models for specific energy consumption (SEC) were established for water recovery in different integrated processes, such as RO-PRO, RO-MD and RO-MD-PRO. Our models can evaluate SEC under different water recovery conditions and for various proportions of supplied waste heat. Simulation results showed that SEC in RO increases with the water recovery rate when the rate is greater than 30%. For the RO-PRO process, the SEC also increases with the water recovery rate when the rate is higher than 38%, but an opposite trend can be observed at lower water recovery rates. If sufficient waste heat is available as the heat source for MD, the integration of MD with the RO or RO-PRO process can significantly reduce SEC. If the total water recovery rate is 50% and MD accounts for 10% of the recovery when sufficient waste heat is available, the SEC values of RO, RO-PRO, RO-MD and RO-MD-PRO are found to be 2.28, 1.47, 1.75 and 0.67 kWh/m3, respectively. These critical analyses provide a road map for the future development of process integration for desalination.

A systematic approach towards optimization of brackish groundwater treatment using nanofiltration (NF) and reverse osmosis (RO) hybrid membrane filtration system.

This research compares the performance efficiencies of Nanofiltration (NF), Reverse osmosis (RO), and Nanofiltration-Reverse Osmosis (NF-RO) hybrid membrane filtration systems, for treatment of brackish groundwater in Delhi-NCR region. Central composite design (CCD) of response surface methodology (RSM) were applied to formulate predictive models for the optimization and simulation of various responses, viz. Water flux, salt rejection, permeate recovery and specific energy consumption (SEC). Three different input factors (feed concentration, pH and pressure) were evaluated. Significance of RSM model was tested and validated with use of an analysis of variance (ANOVA). The models were also compared graphically for their prediction ability. The optimum conditions were determined by numerical optimization of the NF and RO membrane pilot plants. Finally, hybrid configurations of NF and RO were investigated utilising the optimum conditions to identify the technology suitable for the remediation of brackish groundwater. Despite, RO membrane eliminating over 99% of TDS from groundwater, the lower recovery rate renders it environmentally unfavourable. Result indicates that recovery of the hybrid system (40.35%) was greater than that of RO alone (18.796%) and SEC also decreases (5.090-3.8 kW H/m3). Hence, combining a hybrid membrane arrangement with NF-RO to treat brackish groundwater for improved recovery and lower SEC is a viable alternative.

Optimization of Continuous FAME Production in High-Performance Bumpy Surface Rotor Reactor under Theoretical Molar Ratio by Response Surface Methodology.

The continuous production of fatty acid methyl ester (FAME) from waste cooking oil (WCO) via transesterification was carried out under theoretical methanol to oil molar ratio using a high-performance bumpy surface rotor reactor (BSRR). Three types of rotors with different area fractions (AF) of 6.9%, 13.8% and 27.6% were used to equip the BSRR. The selection of the highest performance rotor was compared by factorial experiments. Absolute methanol with 99.9 vol% purity was used as the reactant and potassium hydroxide with 90 wt% purity was used as the base catalyst. Response surface methodology (RSM) was applied to design the experiments and predict the optimal conditions. The three variables in RSM were 0.58-1.43 wt% potassium hydroxide concentration [KOH], 2160-3840 rpm rotor speed, and 1.38-4.74 L/min flow rate. The performance was the specific energy consumption (SEC). The highest performance rotor was AF27.6%. In the first step, the transesterification process was performed using [KOH] 1.5 wt%, a rotor speed of 3000 rpm and a flow rate of 2.027 L/min to produce 98.6 wt% FAME and using SEC at 12.5 W h/kg. In the second step, RSM predicted the optimal condition of [KOH] 1.016 wt%, rotor speed 2910 rpm, flow rate 2.134 L/min and FAME content 97.3 wt%. The actual FAME content averaged 97.16 wt%. The biodiesel properties complied with the EN 14214 standard. This biodiesel production can reduce the cost of methanol by one-half and the cost of KOH by one-third. The energy consumption is only 0.012 kW・h/kg, so the methanol recovery process is not necessary. It has low KOH residue, so washing with water is superfluous and uses minimal energy, which can reduce a lot of costs. The high flow rate of 128 L/h can be used to scale up commercial production.

Event-driven enabled regression aided multi-loop control for SEC minimisation in SWRO desalination considering salinity variation.

This paper addresses the energy minimised operation of seawater reverse osmosis (SWRO) desalination process by simultaneous manipulation of feed pressure and reject valve opening. The specific energy consumption (SEC) analysis of SWRO desalination process for maintaining constant permeate flow during feed salinity variation is performed. The analysis is carried out to identify the suitable manipulating variables that can reduce the energy requirement for regulating permeate flow during feed salinity variation. Based on the analysis, a multi-loop control strategy using event-driven programming paradigm aided by regression based predictive model is proposed. The proposed methodology is more desirable than traditional event-driven multi-loop PID control due to smoother control transition and energy reduction. The investigation of SEC and analysis of proposed control strategy were performed using a previously validated dynamic model for SWRO desalination process. The simulation results show that the proposed methodology is superior to conventional PID control by enabling energy-minimised operation of RO process with significant reduction of feed pressure. The analysis shows that the proposed control approach reduces the feed pressure requirement by approximately 300 kPa during feed salinity variation.

Seasonal atmospheric water harvesting yield and water quality using electric-powered desiccant and compressor dehumidifiers.

Atmospheric water harvesting (AWH) is an emerging technology for decentralized water supply and is proving to be viable for use in emergencies, military deployment, and sustainable industries. The atmosphere is a freshwater reservoir that contains 12,900 km3 of water, 6-fold more than the volume of global rivers. Dehumidification water harvesting technologies can be powered by solar, wind, or electric sources. Compressor/refrigerant-based dehumidifiers operate via dew point condensation and provide a cold surface upon which water vapor can condense. Conversely, desiccant-based technologies saturate water vapor using a sorbent that is then heated, and the supersaturated water vapor condenses on a surface when interacting with cooler ambient process air. This work compares productivity, energy consumption, efficiency, cost and quality of water produced of two water-harvesting mechanisms. Electric-powered compressor and desiccant dehumidifiers were operated outdoors for more than one year in the arid southwestern USA, where temperatures ranged from 3.1 to 43.7 °C and relative humidity (RH) ranged from 6 to 85%. The compressor system harvested >2-fold more water than the desiccant system when average RH during the run cycle was >30%, average temperature was >20 °C, and average dew point temperature was >5 °C. Desiccant systems performed more favorably when average RH during the run cycle was <30%, average temperature was <20 °C, and average dew point temperature was <5 °C. Water collected by compressor-based technologies had conductivity up to 180 µS/cm, turbidity up to 190 NTU, and aluminum, iron and manganese near or above the US EPA secondary drinking water standard. Dissolved organic carbon (DOC) averaged <2 mg C/L but ranged up to 12 mg C/L. Water collected by desiccant-based technologies had significantly lower conductivity, metals, and turbidity, and DOC was always <6 mg/L. Aldehydes such as formaldehyde and acetaldehyde and carboxylic acids such as formic acid and acetic acid were primary contributors to DOC. The differences in harvested water quality were attributed to differences in the condensation method between compressor and desiccant AWH technologies. Multiple strategies could be employed to prevent these volatile organic compounds (VOCs) from contributing to DOC in harvested water, such as pretreating air to remove VOCs or post-treating DOC in harvested liquid water.