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1.
Proc Natl Acad Sci U S A ; 120(18): e2120251119, 2023 05 02.
Artigo em Inglês | MEDLINE | ID: mdl-37094119

RESUMO

Scientific knowledge related to quantifying the monetized benefits for landscape-wide water quality improvements does not meet current regulatory and benefit-cost analysis needs in the United States. In this study we addressed this knowledge gap by incorporating the Biological Condition Gradient (BCG) as a water quality metric into a stated preference survey capable of estimating the total economic value (use and nonuse) for aquatic ecosystem improvements. The BCG is grounded in ecological principles and generalizable and transferable across space. Moreover, as the BCG translates available data on biological condition into a score on a 6-point scale, it provides a simple metric that can be readily communicated to the public. We applied our BCG-based survey instrument to households across the Upper Mississippi, Ohio, and Tennessee river basins and report values for a range of potential improvements that vary by location, spatial scale, and the scope of the water quality change. We found that people are willing to pay twice as much for an improvement policy that targets their home watershed (defined as a four-digit hydrologic unit) versus a more distant one. We also found that extending the spatial scale of a local policy beyond the home watershed does not generate additional benefits to the household. Finally, our results suggest that nonuse sources of value (e.g., bequest value, intrinsic aesthetic value) are an important component of overall benefits.


Assuntos
Ecossistema , Rios , Humanos , Estados Unidos , Ohio , Mississippi
2.
Small ; : e2404002, 2024 Aug 28.
Artigo em Inglês | MEDLINE | ID: mdl-39194487

RESUMO

The recovery of rare earth elements (REEs) from acidic wastewater is crucial to sustainable development, industrial processes, and human health. In this research, ß-cyclodextrin-based nanosponges (ß-CD/PVA-SA NSs) have been proposed as potential adsorbents for europium (Eu), dysprosium (Dy), and gadolinium (Gd) recovery. The nanosponges are synthesized by cross-linking ß-cyclodextrin (ß-CD) functionalized polyvinyl alcohol (PVA) and sodium alginate (SA). Experimental results indicate that ß-CD/PVA-SA NSs exhibit favorable selectivity for Eu, Dy, and Gd, with the maximum adsorption capacity of 222, 217, and 204 mg/g, respectively, in addition to stability and cyclicity. ß-CD/PVA-SA NSs maintain selective adsorption effects towards RE ions that are present in acidic mine drainage (AMD), thereby highlighting their potential for practical applications. Furthermore, density functional theory (DFT) simulations have unveiled the fundamental interactions between the functional groups anchored in ß-CD/PVA-SA NSs and the REEs, providing vital insights into their adsorption mechanism. Hence, the utilization of ß-CD/PVA-SA NSs has the potential to advance initiatives in remediating acidic water pollution and facilitating the sustainable recycling of RE resources.

3.
Mutagenesis ; 2024 Aug 09.
Artigo em Inglês | MEDLINE | ID: mdl-39120006

RESUMO

River water in Kosovo is exposed to various discharges from industrial and agricultural activities as well as to urban wastewater. Rivers Sitnica and Drenica are among the most affected ones and water samples drawn from these rivers show the presence of various toxic substances. Genotoxic effects are seen in fish living in these rivers indicating a cytotoxic and mutagenic potential of the river water. Aiming at substantiating these observations, we assessed cyto- and genotoxic effects of water samples collected at different locations from Drenica and Sitnica river. Samples drawn from Lake Badovc served for comparison. To address seasonal effects, samples were collected at different seasons/time points during the period summer 2016 - spring 2018. The water samples were analyzed employing primary rat hepatocytes as reliable in vitro cell model for the assessment of cytotoxic effects (mitotic arrest and cell death) and DNA damage/genotoxicity (micronucleus assay, Comet assay). The results do not account for significant effects associated with specific locations but demonstrate seasonal differences of the genotoxic potential of the water samples collected along both rivers, which are accompanied by a limited cytotoxic potential. Our data provide substantial support to earlier observations and strongly warrant the need for continuous chemical as well as biological monitoring of the river water in Kosovo, focusing on an improved toxicant profiling of the river water and investigations addressing the observed seasonal variations.

4.
Environ Sci Technol ; 58(29): 13065-13075, 2024 Jul 23.
Artigo em Inglês | MEDLINE | ID: mdl-38989840

RESUMO

A. butzleri is an underappreciated emerging global pathogen, despite growing evidence that it is a major contributor of diarrheal illness. Few studies have investigated the occurrence and public health risks that this organism possesses from waterborne exposure routes including through stormwater use. In this study, we assessed the prevalence, virulence potential, and primary sources of stormwater-isolated A. butzleri in fecally contaminated urban stormwater systems. Based on qPCR, A. butzleri was the most common enteric bacterial pathogen [25%] found in stormwater among a panel of pathogens surveyed, including Shiga-toxin producing Escherichia coli (STEC) [6%], Campylobacter spp. [4%], and Salmonella spp. [<1%]. Concentrations of the bacteria, based on qPCR amplification of the single copy gene hsp60, were as high as 6.2 log10 copies/100 mL, suggesting significant loading of this pathogen in some stormwater systems. Importantly, out of 73 unique stormwater culture isolates, 90% were positive for the putative virulence genes cadF, ciaB, tlyA, cjl349, pldA, and mviN, while 50-75% of isolates also possessed the virulence genes irgA, hecA, and hecB. Occurrence of A. butzleri was most often associated with the human fecal pollution marker HF183 in stormwater samples. These results suggest that A. butzleri may be an important bacterial pathogen in stormwater, warranting further study on the risks it represents to public health during stormwater use.


Assuntos
Arcobacter , Arcobacter/genética , Arcobacter/patogenicidade , Virulência , Microbiologia da Água , Cidades , Humanos
5.
BJOG ; 131(4): 401-414, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-37814514

RESUMO

BACKGROUND: The interaction between pollution and endometriosis is a pressing issue that demands immediate attention. The impact of pollution, particularly air and water pollution, or occupational hazards, on hormonal disruption and the initiation of endometriosis remains a major issue. OBJECTIVES: This narrative review aims to delve into the intricate connection between pollution and endometriosis, shedding light on how environmental factors contribute to the onset and severity of this disease and, thus, the possible public health policy implications. DISCUSSION: Endocrine-disrupting chemicals (EDCs) in pollutants dysregulate the hormonal balance, contributing to the progression of this major gynaecological disorder. Air pollution, specifically PM2.5 and PAHs, has been associated with an increased risk of endometriosis by enhancing chronic inflammation, oxidative stress, and hormonal imbalances. Chemical contaminants in water and work exposures, including heavy metals, dioxins, and PCBs, disrupt the hormonal regulation and potentially contribute to endometriosis. Mitigating the environmental impact of pollution is required to safeguard women's reproductive health. This requires a comprehensive approach involving stringent environmental regulations, sustainable practices, responsible waste management, research and innovation, public awareness, and collaboration among stakeholders. CONCLUSION: Public health policies have a major role in addressing the interaction between pollution and endometriosis in a long-term commitment.


Assuntos
Poluição do Ar , Endometriose , Poluentes Ambientais , Feminino , Humanos , Endometriose/etiologia , Poluentes Ambientais/toxicidade , Saúde da Mulher , Poluição do Ar/efeitos adversos , Meio Ambiente
6.
J Fluoresc ; 2024 Sep 12.
Artigo em Inglês | MEDLINE | ID: mdl-39264519

RESUMO

The quantification of pollutant metabolites in fish bile is an efficient approach to xenobiotic pollution monitoring in freshwaters since these measurements directly address exposure. Fluorescence excitation-emission matrix spectroscopy (EEMS) has demonstrated to be a highly specific and cost-effective technique for polycyclic aromatic hydrocarbon (PAH) and PAH-metabolite identification and quantification. EEMS ability to quantify these compounds strongly depends on the intensity and variability of the bile baseline fluorescence (BBF). We found large differences in BBF among Aequidens metae (AME) individuals and of these with Piaractus orinoquensis (PIO). Moreover, BBF was large enough that solvent dilutions of over 1:400 were needed to avoid inner filter effects. We used parallel factor analysis (PARAFAC) to model the intra- and inter-species BBF variability. PARAFAC successfully decomposed the EEMS set into three fluorophores present in all samples, although in concentrations spreading over ~ 3 orders of magnitude. One of the factors was identified as tryptophan. Tryptophan and Factor 2 were covariant and much more abundant in AME than in PIO, while Factor 3 was ~ 6 times more abundant in PIO than in AME. Also, tryptophan was ~ 10x more abundant in AME specimens immediately caught in rivers than in their laboratory-adapted peers. The PARAFAC decomposition effectiveness was confirmed by the positive proportionality of scores to dilution ratios. A large inner filter indicates that Factor 2 is as strong a light absorber as tryptophan. Our results stress the need to include bile matrix variable components for the detection and quantification of pollutant metabolites using PARAFAC.

7.
Philos Trans A Math Phys Eng Sci ; 382(2282): 20230271, 2024 Nov 09.
Artigo em Inglês | MEDLINE | ID: mdl-39307167

RESUMO

In this article, we report the modification and photocatalytic evaluation of commercial TiO2-P25 under visible light for methyl orange (MO) dye degradation under visible light. The activity of materials doped with N, Pd, Pt and Au on to the TiO2-P25 was evaluated, with optimal photocatalytic performance achieved using Au nanoparticles doped on an N-functionalized titania surface. X-ray diffraction (XRD), physical nitrogen adsorption/desorption isotherm curves, transmission electron microscopy (TEM), diffuse reflectance spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) were used to study the structural and textural properties of the samples. The chemical species present in the bulk and surface of the catalysts were identified using X-ray photoelectron spectroscopy (XPS) and microwave plasma-atomic emission spectroscopy. The results show that Au/N-TiO2 photocatalyst presents a remarkable enhanced activity for MO dye degradation, under visible light illumination, reaching 100% after 4 h. The enhanced photocatalytic activity using this composite is attributable to the well-dispersed and small size of Au nanoparticles, large surface area, reduction of band-gap energy and the interaction between nitrogen and Au which promoted a synergistic effect. This article is part of the discussion meeting issue 'Green carbon for the chemical industry of the future'.

8.
Environ Res ; : 120223, 2024 Oct 22.
Artigo em Inglês | MEDLINE | ID: mdl-39448014

RESUMO

Tetracyclines, a widely used class of antibiotics, and synthetic plastic products are both prevalent in the environment. When released into water bodies, these pollutants can pose significant risks due to their daily influx into aquatic ecosystems. Microplastics can adsorb tetracyclines, acting as a transport vector that enhances their impact on aquatic species. Understanding the co-exposure effects of microplastics and tetracyclines is crucial. This review comprehensively examines the occurrence and distribution of microplastics and tetracyclines across various environmental contexts. The interactions between these two contaminants are primarily driven by electrostatic interactions, hydrophobic effects, hydrogen bonding, π-π interactions, and others. Factors such as the presence of heavy metals, ions, and dissolved organic matter can influence the adsorption and desorption of tetracyclines onto microplastics. The stability of microplastic-tetracycline complexes is highly dependent on pH conditions. The combined pollution tetracyclines and microplastics leads to negative impacts on marine species. Future research should focus on understanding the adsorption behavior of tetracyclines on microplastics and developing effective treatment techniques for these contaminants in aquatic environments.

9.
Environ Res ; 253: 119142, 2024 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-38750997

RESUMO

Agricultural water resource utilization efficiency in China is facing significant challenges due to the dual constraints of carbon emissions and water pollution. The inefficiency in water usage in agriculture not only impacts the sustainability of water resources but also contributes to environmental degradation through increased carbon emissions and water pollution. Agricultural water resource utilization efficiency under the constraint of carbon emission and water pollution has been a critical issue in China from 2005 to 2022. This study employs the Quantile Autoregressive Distributed Lag (QARDL) method to comprehensively assess and analyze the complex relationship that exists between agricultural water usage, carbon emissions, and water pollution. By analyzing distinct quantiles of the data distribution, the research investigates how different levels of water resource utilization efficiency relate to carbon emissions and water pollution under various conditions. The findings reveal nuanced insights into the dynamic interactions among these components within the agricultural sector. This research project focuses on the efficiency of water resource utilization in agriculture while considering the constraints of carbon emission and water pollution. Given the dynamic and time-dependent character of these components, the QARDL methodology makes it possible to get a detailed knowledge of how they interact within the framework of agriculture. The study aims to give significant insights and policy suggestions to improve agricultural practices while minimizing environmental concerns linked to carbon emissions and water pollution.


Assuntos
Agricultura , Carbono , Recursos Hídricos , China , Carbono/análise , Poluição da Água/análise
10.
Environ Res ; 249: 118093, 2024 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-38237759

RESUMO

Plastic pollution has become a major environmental problem because it does not break down and poses risks to ecosystems and human health. This study focuses on the environmentally friendly synthesis of ZnO nanocubes using an extract from Ceropegia omissa H. Huber plant leaves. The primary goal is to investigate the viability of these nanocubes as visible-light photocatalysts for the degradation of bisphenol A (BPA). The synthesized ZnO nanocubes have a highly crystalline structure and a bandgap of 3.1 eV, making them suitable for effective visible-light photocatalysis. FTIR analysis, which demonstrates that the pertinent functional groups are present, demonstrates the chemical bonding and reducing processes that take place in the plant extract. The XPS method also studies zinc metals, oxygen valencies, and binding energies. Under visible light irradiation, ZnO nanocubes degrade BPA by 86% in 30 min. This plant-extract-based green synthesis method provides a long-term replacement for traditional procedures, and visible light photocatalysis has advantages over ultraviolet light. The study's results show that ZnO nanocubes may be good for the environment and can work well as visible light photocatalysts to break down organic pollutants. This adds to what is known about using nanoparticles to clean up the environment. As a result, this study highlights the potential of using environmentally friendly ZnO nanocubes as a long-lasting and efficient method of reducing organic pollutant contamination in aquatic environments.


Assuntos
Compostos Benzidrílicos , Luz , Fenóis , Extratos Vegetais , Poluentes Químicos da Água , Óxido de Zinco , Óxido de Zinco/química , Compostos Benzidrílicos/química , Fenóis/química , Fenóis/análise , Extratos Vegetais/química , Poluentes Químicos da Água/química , Catálise , Química Verde/métodos , Fotólise
11.
Environ Res ; 258: 119423, 2024 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-38889839

RESUMO

High concentration of chromium in aquatic environments is the trigger for researchers to remediate it from wastewater environments. However, conventional water treatment methods have not been satisfactory in removing chromium from water and wastewater over the last decade. Similarly, many adsorption studies have been focused on one aspect of the treatment, but this study dealt with all aspects of adsorption packages to come up with a concrete conclusion. Therefore, this study aimed to prepare pinecone biochar (PBC) via pyrolysis and apply it for Cr(VI) removal from wastewater. The PBC was characterized using FTIR, SEM-EDX, BET surface area, pHpzc, Raman analyses, TGA, and XRD techniques. Chromium adsorption was studied under the influence of PBC dose, solution pH, initial Cr(VI) concentration, and contact time. The characteristics of PBC are illustrated by FTIR spectroscopic functional groups, XRD non-crystallite structure, SEM rough surface morphology, and high BET surface area125 m2/g, pore volume, 0.07 cm3/g, and pore size 1.4 nm. On the other hand, the maximum Cr (VI) adsorption of 69% was found at the experimental condition of pH 2, adsorbent dosage 0.25 mg/50 mL, initial Cr concentration 100 mg/L, and contact time of 120 min. Similarly, the experimental data were well-fitted with the Langmuir adsorption isotherm at R2 0.96 and the pseudo-second-order kinetics model at R2 0.99. This implies the adsorption process is mainly attributed to monolayer orientation between the adsorbent and adsorbate. In the thermodynamics study of adsorption, ΔG was found to be negative implying the adsorption process was feasible and spontaneous whereas the positive values of ΔH and ΔS indicated the adsorption process was endothermic and increasing the degree of randomness, respectively. Finally, adsorbent regeneration and reusability were successful up to three cycles. In conclusion, biochar surface modification and reusability improvements are urgently required before being applied at the pilot scale.


Assuntos
Carvão Vegetal , Cromo , Termodinâmica , Águas Residuárias , Poluentes Químicos da Água , Cromo/química , Adsorção , Carvão Vegetal/química , Cinética , Poluentes Químicos da Água/química , Águas Residuárias/química , Purificação da Água/métodos , Eliminação de Resíduos Líquidos/métodos
12.
Environ Res ; 261: 119710, 2024 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-39102938

RESUMO

Zeolitic Imidazolate (metal organic) Frameworks (ZIFs) and Prussian Blue Analogues (PBAs) are promising materials in electrochemical sensing due to their unique properties. In this study, a composite material comprising NiFe-PBA and ZIF-67 was synthesized and made to form a uniform layer onto a glassy carbon electrode (GCE) to enhance electrochemical performance for furazolidone (FZD) detection. The synthesized NiFe-PBA/ZIF-67 composite exhibited excellent sensitivity, selectivity, and stability towards FZD detection, with a low limit of detection (LOD). The electrochemical behaviour of FZD on the NiFe-PBA/ZIF-67/GCE electrode was investigated, revealing a diffusion-controlled process. Differential pulse voltammetry (DPV) analysis demonstrated the synergetic effect of the PBA/MOF core-shell structure in enhancing FZD electro-reduction. The sensor exhibited exceptional LOD of 0.007 µM. Selectivity studies confirmed the sensor's ability to distinguish FZD from potential interferents. Extensive evaluations demonstrated the sensor's reproducibility, repeatability, and long-term stability, affirming its practical utility. Real sample analysis further validated the sensor's excellent analytical capabilities in diverse matrices.


Assuntos
Técnicas Eletroquímicas , Ferrocianetos , Poluentes Químicos da Água , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/química , Técnicas Eletroquímicas/métodos , Ferrocianetos/química , Eletrodos , Estruturas Metalorgânicas/química , Furazolidona/análise , Furazolidona/química , Limite de Detecção , Carbono/química , Zeolitas/química , Imidazóis
13.
Environ Res ; 254: 118883, 2024 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-38583658

RESUMO

While durian shell is often discharged into landfills, this waste can be a potential and zero-cost raw material to synthesize carbon-based adsorbents with purposes of saving costs and minimizing environmental contamination. Indole (IDO) is one of serious organic pollutants that influence aquatic species and human health; hence, the necessity for IDO removal is worth considering. Here, we synthesized a magnetic composite, denoted as MFOAC, based on activated carbon (AC) derived from durian shell waste incorporated with MnFe2O4 (MFO) to adsorb IDO in water. MFOAC showed a microporous structure, along with a high surface area and pore volume, at 518.9 m2/g, and 0.106 cm3/g, respectively. Optimization of factors affecting the IDO removal of MFOAC were implemented by Box-Behnken design and response surface methodology. Adsorption kinetics and isotherms suggested a suitable model for MFOAC to remove IDO. MFOAC was recyclable with 3 cycles. Main interactions involving in the IDO adsorption mechanism onto MFOAC were clarified, including pore filling, n-π interaction, π-π interaction, Yoshida H-bonding, H-bonding.


Assuntos
Carvão Vegetal , Compostos Férricos , Indóis , Compostos de Manganês , Poluentes Químicos da Água , Indóis/química , Poluentes Químicos da Água/química , Adsorção , Compostos de Manganês/química , Compostos Férricos/química , Carvão Vegetal/química , Animais , Purificação da Água/métodos
14.
Environ Res ; 244: 117945, 2024 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-38109954

RESUMO

Pollution from Combined Sewer Overflows (CSOs) cause diffuse environmental problems, which are still not satisfactorily addressed by current management practices. In this study, a sensitivity analysis was conducted on several CSO environmental impact indicators, with respect to parameters that characterise climate, urban catchment and the CSO structure activation threshold. The sensitivity analysis was conducted by running 10000 simulations with the Storm Water Management Model, using a simplified modelling approach. The indicators were calculated at yearly scale to evaluate overall potential effects on water bodies. The results could be used to estimate pollution load ranges, known the values of the input parameters, and to investigate suitable strategies to reduce pollution of the receiving water bodies. The percentage of impervious surface of the catchment was found the most influent parameter on all the indicators, and its reduction can contain the discharged pollutant mass. The activation threshold, instead, resulted the second least influent parameter on all the indicators, suggesting that its regulation alone would not be a suitable strategy to reduce CSO pollution. However, along with the reduction of the imperviousness, its increase could effectively decrease the concentration of pollutant in the overflow. The results also indicate that neither adopting sustainable urban drainage practices, nor interventions on the CSO device, significantly affect the frequency of the overflows. Therefore, restricting this latter was found to be ineffective for the reduction of both the discharged pollutant mass and the concentration of pollutant in the overflow.


Assuntos
Poluentes Ambientais , Esgotos , Monitoramento Ambiental , Chuva , Água
15.
J Water Health ; 22(8): 1556-1577, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-39212287

RESUMO

Freshwater pollution is a major concern in Ghana, directly impacting human health. However, the underlying drivers of exposure and risks are not comprehensively understood, emphasizing the severity and impact of these diseases. This study assessed the interaction between water and human health, specifically focusing on the risk factors for waterborne diseases and the drivers of water pollution among residents near the Tano River Basin, Ghana. A sample size of 400 households was selected from five communities within the basin based on their proximity to the Tano River. In addition, the study combined both spatial and non-spatial data sources to map potential flood zones for the basin. The study found that inadequate sanitation, poor hygiene practices, and contamination from illegal mining were the primary causative factors of waterborne diseases. Additionally, floods and improper waste management significantly contributed to disease outbreaks. The flood susceptibility analysis indicated that areas highly susceptible to flooding cover 21.2% of the basin, predominantly in the southern part. The results highlight the urgent need for comprehensive interventions to address the drivers of waterborne diseases. This study will contribute to the local authorities in developing plans to prevent waterborne diseases and mitigate their economic and public health impacts.


Assuntos
Rios , Doenças Transmitidas pela Água , Gana/epidemiologia , Humanos , Doenças Transmitidas pela Água/epidemiologia , Fatores de Risco , Inundações , Saneamento , Poluição da Água/análise
16.
Proc Natl Acad Sci U S A ; 118(29)2021 07 20.
Artigo em Inglês | MEDLINE | ID: mdl-34253602

RESUMO

Water pollution is a persistent problem in China, in part, because local governments fail to implement water quality standards set by national and provincial authorities. These higher authorities often lack regular information about the immediate and long-term achievement of remediation targets. Accordingly, central authorities have encouraged nongovernmental organizations to monitor local governments' remediation efforts. This study examines whether nongovernmental monitoring of urban waterways improves water quality by facilitating oversight of local governments or instigating public action for remediation. We randomly assigned urban waterways in Jiangsu province previously identified for remediation to be monitored by a partner nongovernmental organization for 15 mo. We further randomized whether the resulting information was disseminated to local and provincial governments, the public, or both. Disseminating results from monitoring to local and provincial governments improved water quality, but disseminating results to the public did not have detectable effects on water quality or residents' pursuit of remediation through official and volunteer channels. Monitoring can improve resource management when it provides information that makes local resource managers accountable to higher authorities.


Assuntos
Conservação dos Recursos Naturais/métodos , Poluição da Água/prevenção & controle , China , Cidades , Recuperação e Remediação Ambiental , Humanos , Disseminação de Informação , Governo Local , Parcerias Público-Privadas
17.
Ecotoxicol Environ Saf ; 281: 116616, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-38917589

RESUMO

The urgent need to address the severe environmental risk posed by chromium-contaminated industrial wastewater necessitates the development of eco-friendly cleanup methodologies. Utilizing the Ficus benghalensis plant extracts, the present study aims to develop green zinc oxide nanoparticles for the removal of Cr metal ions from wastewater. The leaves of Ficus benghalensis, often known as the banyan tree, were used to extract a solution for synthesizing ZnO NPs. These nanoparticles were developed with the goal of efficiently eliminating chromium (Cr) from industrial effluents. Batch studies were carried out to assess the efficiency of these synthesized ZnO NPs in treating leather industrial effluent, with aiming for optimal chromium removal. This involved measuring the nanoparticles' capacity to adsorb Cr ions from wastewater samples by comparing chromium levels before and after treatment. Removal efficiency for Cr was estimated through the batches such as optimization of pH, contact time, initial Cr concentration and sorbent dose of ZnO NPs were of the batches. These synthesized ZnO NPs were found to be successful in lowering chromium levels in wastewater to meet permissible limit. The nanoparticles exhibited their highest absorption capacity, reaching 94 % (46 mg/g) at pH 4, with a contact time of 7 hours with the optimum sorbent dose of 0.6 g/L. Hence, the excellent adsorption capabilities of these nanoparticles, together with their environmentally benign manufacturing technique, provide a long-term and efficient solution for chromium-contaminated wastewater treatment. Its novel nature has the potential to significantly improve the safety and cleanliness of water ecosystems, protecting the both i.e. human health and the environment.


Assuntos
Cromo , Ficus , Química Verde , Extratos Vegetais , Águas Residuárias , Poluentes Químicos da Água , Óxido de Zinco , Óxido de Zinco/química , Ficus/química , Cromo/análise , Cromo/química , Águas Residuárias/química , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/química , Extratos Vegetais/química , Química Verde/métodos , Resíduos Industriais/análise , Adsorção , Nanopartículas Metálicas/química , Eliminação de Resíduos Líquidos/métodos , Purificação da Água/métodos , Nanopartículas/química , Folhas de Planta/química
18.
Ecotoxicology ; 33(9): 1074-1085, 2024 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-39215898

RESUMO

In recent decades the Amazonian ecosystem has received large amounts of domestic and industrial effluents, as well as mining-related waste contributing significant quantities of metal to water bodies. Thus, the main objective of the study was to verify the sensitivity of a native Amazonian ostracod (Strandesia rondoniensis) species to isolated and mixed metal salts (CuSO4; ZnCl2; CdCl2 and HgCl2). The sensitivity will be compared to other species using species sensitivity distributions (SSDs) for an ecological risk assessment (ERA). The experiment consisted of simultaneously exposing each metal alone and in mixture, through a factorial design for toxicity with 25 different combinations for 48 h. For the ERA, metal concentrations measured in the water of various aquatic environments in the Amazon basin were considered based on the risk quotient values. The results showed that the metal toxicity gradient was Cd>Hg>Cu>Zn, respectively. The toxicity in the mixture showed that the combination of Cu-Cd and Cu-Zn better fit the model (CA), indicating mainly synergism when copper predominated in the mixture. Meanwhile, the Cu-Hg interaction fit the model better (IA), again indicating synergism when copper was at a higher concentration. The ERA showed a high risk (RQ > 1) for the Cd, Cu, and Hg metals.


Assuntos
Crustáceos , Monitoramento Ambiental , Poluentes Químicos da Água , Medição de Risco , Poluentes Químicos da Água/toxicidade , Animais , Crustáceos/efeitos dos fármacos , Brasil , Metais Pesados/toxicidade , Metais/toxicidade , Testes de Toxicidade
19.
Drug Chem Toxicol ; : 1-11, 2024 Aug 29.
Artigo em Inglês | MEDLINE | ID: mdl-39210515

RESUMO

Pesticide use increases annually, and Brazil is the world's largest consumer. However, unlike the European Union (EU), there is no established limit value for pesticide mixtures in drinking water, and therefore the concentration of pesticides can reach 3354 times the EU limit. Thus, determining the risk of exposure to pesticide mixtures and their main metabolites is challenging and requires the use of alternative methods. In the present study, the Common Carp Brain (CCB) cell line was used to evaluate the in vitro toxicity of relevant pesticide mixtures (glyphosate, 2,4-D, atrazine, and mancozeb) and their main metabolites after 72 h of exposure. The tested concentrations were based on the Acceptable Daily Intake (ADI) defined by Brazilian legislation. The results showed that cells exposed to lower concentrations of the pesticide mixtures and the pesticide + metabolite mixtures were affected by a decrease in cell confluence, resazurin metabolism, and wound healing capacity. The IBR index showed that lower concentrations had more severe effects, suggesting the absence of safe concentrations of these pesticide and metabolite mixtures for the CCB cell line within the tested concentration range. These findings raise concerns about the effects of exposure to these substances on animal and human health.

20.
Chem Biodivers ; : e202401037, 2024 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-39087919

RESUMO

Access to clean and safe water sadly remains an issue in the 21st century. Water reservoirs, whether groundwater or surface water, are routinely contaminated by various harmful Emerging Contaminants (ECs). One of most prevalent pollutants among these pollutants is Bisphenol A, which is classified as an Endocrine Disrupting Compound (EDC). This substance adversely interferes with the endocrine system, primarily by mimicking estrogen, and has been considered a potential contributor to Polycystic Ovary Syndrome (PCOS) with 82.70% of 1,391 women studied showing a positive correlation between BPA exposure and PCOS. PCOS is currently the most prevalent endocrine disorder affecting women of reproductive age; however, its pathogenesis remains unclear, complicating diagnosis and subsequently patient care. In this review, these topics are thoroughly examined, with particular emphasis on biochar, a new promising method for large-scale water purification. Biochar, derived from various organic waste materials, has emerged as a cost-effective substance with remarkable adsorption properties achieving up to 88% efficiency over four cycles of reuse, similar to that of activated carbon. This review interrogates the suitability of biochar for counteracting the issue of EDC pollutants.

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