Data-Driven AI Models within a User-Defined Optimization Objective Function in Cement Production.

This paper explores the energy-intensive cement industry, focusing on a plant in Greece and its mill and kiln unit. The data utilized include manipulated, non-manipulated, and uncontrolled variables. The non-manipulated variables are computed based on the machine learning (ML) models and selected by the minimum value of the normalized root mean square error (NRMSE) across nine (9) methods. In case the distribution of the data displayed in the user interface changes, the user should trigger the retrain of the AI models to ensure their accuracy and robustness. To form the objective function, the expert user should define the desired weight for each manipulated or non-manipulated variable through the user interface (UI), along with its corresponding constraints or target value. The user selects the variables involved in the objective function based on the optimization strategy, and the evaluation is based on the comparison of the optimized and the active value of the objective function. The differential evolution (DE) method optimizes the objective function that is formed by the linear combination of the selected variables. The results indicate that using DE improves the operation of both the cement mill and kiln, yielding a lower objective function value compared to the current values.

A systematic comparison of salt removal efficiency in washing treatment by using fly ashes from 13 MSWI plants in China.

Municipal solid waste incineration (MSWI) fly ash contains large amounts of Ca, Si, and other elements, giving it the potential to be used as a raw material for cement production. However, fly ash often contains a high content of salts, which greatly limits its blending ratio during cement production. These salts are commonly removed via water washing, but this process is affected by the nature and characteristics of fly ash. To clarify the influence of the ash characteristics on salt removal, a total of 60 fly ash samples from 13 incineration plants were collected, characterized, and washed. The ash characterization and cluster analysis showed that the incinerator type and flue gas purification technology/process significantly influenced the ash characteristics. Washing removed a high percentage of salts from fly ash, but the removal efficiencies varied significantly from each other, with the chlorine removal efficiency ranging from 73.76% to 96.48%, while the sulfate removal efficiency ranged from 6.92% to 51.47%. Significance analysis further revealed that the salt removal efficiency varied not only between the ash samples from different incinerators, but also between samples collected at different times from the same incinerator. The high variance of the 60 ash samples during salt removal was primarily ascribed to their different mineralogical and chemical characteristics. Mineralogical analysis of the raw and washed ash samples showed that the mineralogical forms and proportion of these salts in each ash sample greatly influenced their removal. The presence of less-soluble and insoluble chloride salts (e.g., CaClOH, Ca2Al(OH)6(H2O)2Cl etc.) in fly ash significantly affected the chlorine removal efficiency. This study also found that Fe, Mn, and Al in fly ash were negatively correlated with the dechlorination efficiency of fly ash. In summary, the different physical and chemical properties of fly ash caused great discrepancies in salt removal. Consequently, it is suggested to consider the potential impact of the ash source and ash generation time on salt removal to ensure a reliable treatment efficiency for engineering applications.

Mass flow, enrichment and potential environmental impacts of mercury in a preheater-precalciner cement plant using multiple mining and industrial wastes.

Cement plants (CPs) are one of the most important anthropogenic sources of mercury (Hg) emissions in China. Over 1000 cement production lines operate in China and use various raw materials; however, little data on Hg emissions is recorded on site. This study investigated a CP in Guizhou Province that uses multiple mining and industrial wastes as part of the circular economy policy. Among the various raw materials, carbide slag had the highest Hg content (2.6 mg/kg) and contributed half of the Hg input. High Hg concentration (27 mg/kg) in the kiln tail dust and a strong Hg enrichment factor (39) was found, which was determined as the ratio of total Hg accumulated within the clinker production process to the daily Hg input from raw materials and fuel. The clinker had negligible Hg (0.001 mg/kg), while the Hg in cement products (0.04 mg/kg) mostly came from additives and retarders. The estimated atmospheric emission factor of Hg from this CP was 161.5 mg Hg/t clinker, which was much higher than those of other CPs in Guizhou that employ low-Hg raw materials. A five-step sequential extraction experiment with kiln tail dust indicates that Hg mainly existed in fraction of F4 (73-96% of the total Hg, possibly as Hg2Cl2) and that some samples had high proportions of water-soluble Hg (up to 21% of the total), which may be easily released into surrounding water bodies and pose high environmental risks. Using low-Hg raw (or alternative raw) materials and conducting proper disposal of kiln tail dust will reduce the environmental risk of Hg from CPs.

Analysis of the heavy metals (As, Pb, Cu, Zn) by leaching and sequential extraction procedure from a municipal solid waste incinerator fly ash co-processing cement kiln plant.

The municipal solid waste incineration (MSWI) fly ash has been a major problem with the rapid development of the cities in China. And the cement rotary kiln co-processing technique is accepted as an effective method to dispose detrimental heavy metals in MSWI fly ash. This study focused on presented the total leaching content and the morphological distribution of the heavy metals in cement solid samples doped with MSWI fly ash. These samples were collected from a MSWI fly ash co-processing cement rotary kiln plant. The leaching test and the sequential extraction procedure were adopted to measure the migration characteristic of As, Pb, Cu, and Zn. In addition, the leachability of clinker samples under different simulated environmental conditions was also detected to analyze the security of the cement product doped with MSWI fly ash. This work demonstrates the feasibility of the cement rotary kiln MSWI fly ash co-processing technique and provides a scientific guidance to related plant.

Pathways and influential factors study on the formation of PBDD/Fs during co-processing BDE-209 in cement kiln simulation system.

The thermal processes of cement kilns are sources of polybrominated dibenzofurans and dioxins (PBDD/Fs); however, when co-processing decabromodiphenyl ether (BDE-209) soil in cement kilns, very few reports have investigated the mechanism of PBDD/Fs formation from BDE-209. Therefore, the pathways and factors that influence the formation of PBDD/Fs were investigated using Box-Behnken design (BBD) of the response surface methodology (RSM) at lab-scale. The PBDEs, HBr/Br2 and PBDD/Fs emissions in flue gas from the simulated thermal process were analyzed using gas chromatography/mass spectroscopy (GC/MS), high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS), and ion chromatography (IC). Density functional theory (DFT) was also used to further discuss the formation of PBDD/Fs. The major products of BDE-209 thermal decomposition in flue gas were 97.1% HBr/Br2 (a.v. 26.6%/70.6%) > 2.7% PBDEs >0.2% PBDD/Fs. Formation of precursors were the main pathways for PBDD/Fs, and those precursors were dominated by higher-brominated PBDEs (heptã deca-BDEs); debromination of BDE-209 was also a crucial pathway for the formation of PBDD/Fs throughout the thermal process. Interestingly, it was easier to form HpBDD/Fs from OBDD/Fs than from PBDEs. The O2 percentage and interaction factors of O2 percentage, temperature, and CaCO3 percentage have the largest influence on PBDD/Fs emissions and formation.

Co-processing of industrial trade rejects in cement plant.

In India non-hazardous industrial waste is generated at a staggering rate of about 30 million metric tonnes/year; considering the major generators (excluding power plant and mining industry waste) as per Ministry of Housing and Urban Affairs, Government of India (GoI), thus disposing of them is a challenge. The industrial waste generated from fast-moving consumer goods (FMCG) trade rejects and expired product is also enormous (although largely remains unaccounted) and needs to be disposed of by the producer as per the guidelines of the Ministry of Environment, Forests and Climate Change, GoI. Co-processing of this industrial trade rejects in cement plant can be a prominent solution as it reduces the disposal problem of the solid waste stream and provides an alternative methodology for complete thermal and material recovery of the waste with no by-products. Co-processing further reduces the use of conventional resources by utilizing the waste as an alternative fuel and raw materials. The study thus analyzes a co-processing trial of a month in a cement plant in the southern part of India and based on the obtained data, the environmental and operational sustainability was studied. The economic benefit obtainable was also analyzed based on the achieved substitution benefit. Parameters such as emission and quality of the final product were gauged. The leaching behavior of the final product was also analyzed. Thus, the findings will help in reducing the carbon footprints of the industrial wastes, specifically the FMCG trade waste, and will show the sustainability of co-processing waste in Indian cement plants.

Unintentional persistent organic pollutants in cement kilns co-processing solid wastes.

Co-processing solid waste in cement kilns has become increasingly widespread in recent years. Persistent organic pollutants (POPs) can be unintentionally produced and emitted from cement kilns, especially kilns in which solid waste is co-processed. Unintentionally produced POP formation and emission by cement kilns co-processing solid waste therefore need to be studied in detail to allow the potential risks posed by cement kiln co-processing techniques to be assessed. Many field studies and laboratory simulation experiments have been performed to investigate the formation and release of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). However, the formations, characteristics and emission factors of various emerging unintentionally produced POPs have not been comprehensively reviewed. Here, emissions of well-known unintentionally produced POPs (PCDD/Fs and polychlorinated biphenyls) and emerging unintentionally produced dioxin-like POPs (polybrominated dibenzo-p-dioxins and dibenzofurans, polychlorinated naphthalenes, and chlorinated and brominated polycyclic aromatic hydrocarbons) in cement kilns co-processing solid waste are reviewed, focusing on formations and influencing factors of those unintentional POPs. Data from field studies indicated that the main stages in which POPs are unintentionally produced in cement kilns co-processing solid waste are the cyclone preheater outlet, suspension preheater boiler, humidifier tower, and back-end bag filter. The raw material composition, chlorine and bromine contents, and temperature are the most important factors affecting POP formation. The homolog distributions and congener profiles of POPs formed unintentionally in cement kilns were compared, and it was found that larger amounts of less-chlorinated homologs than more-chlorinated homologs are emitted. Emission factors for various unintentionally produced POPs for cement kilns co-processing solid waste were summarized, and could be useful for compiling global emission inventories for pollutants covered by the Stockholm Convention. This comprehensive review improves our understanding of unintentional production and emissions of POPs by cement kilns co-processing solid waste.

Study on the evolution and transformation of chlorine during co-processing of hazardous waste incineration residue in a cement kiln.

The co-processing of hazardous waste in a cement kiln can eliminate a large quantity of hazardous wastes, but the excessive existence of chlorine will affect not only the operation of a cement kiln but also the quality of cement products. In this study, the mixtures of hazardous waste incineration residue and raw meal were incinerated in a high temperature tubular furnace. The distribution ratio of chlorine in flue gas, clinker and fly ash under different experiment conditions was obtained and the influence of the co-processing conditions on chlorine evolution and transformation was studied. The results showed that chlorine mainly existed in flue gas and clinker, and only less than 1% of chlorine existed in fly ash. The incineration temperature had a significant influence on the distribution of chlorine. The higher the incinerating temperature, the greater the distribution ratio of chlorine in flue gas and fly ash. The proportion of chlorine in all parts remained basically unchanged while the temperature was higher than 1300°C. With the increase of the retention time, the proportion of chlorine released into the flue gas increased. The distribution ratio of chlorine in each part remained unchanged after about 30 minutes. There were four stages of the rate of chlorine release. In addition, the chlorine content of the sample had little effect on the partition of chlorine. Some suggestions on the co-processing of hazardous waste in a cement kiln are put forward based on these experimental results.

Brominated dioxins and furans in a cement kiln co-processing municipal solid waste.

A field study and theoretical calculations were performed to clarify the levels, profiles, and distributions of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) in a cement kiln co-processing solid waste, with a focus on the PBDF formation mechanism. The raw materials contributed greatly to input of PBDD/Fs into the cement kiln. The PBDD/F concentrations in the raw materials were much higher than those in particle samples from different process stages in the cement kiln. The PBDD/F concentrations in the clinkers were 1.40% of the concentrations in the raw materials, which indicated that the high destruction efficiencies for PBDD/Fs by cement kiln. PBDD/F distribution patterns in particle samples collected from different process stages indicated the cement kiln backend was a major site for PBDD/F formation. PBDFs with high levels of halogenation, such as heptabrominated furans (HpBDF), were the dominant contributors to the total PBDD/F concentrations and accounted for 42%-73% of the total PBDD/F concentrations in the particle samples. Our results showed that co-processing of municipal solid waste in a cement kiln may influence the congener profile of PBDD/Fs, especially for the higher halogenated PBDD fraction. In addition, there were significant correlations between the decabromodiphenyl ether and heptabrominated furan concentrations, which is an indicator of transformation from polybrominated diphenyl ethers to PBDD/Fs. Theoretical calculations were performed and demonstrated that elimination of HBr and Br2 from polybrominated diphenyl ethers were the dominant formation pathways for PBDD/Fs. These pathways differed from that for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs).

A review on paint sludge from automotive industries: Generation, characteristics and management.

The automotive manufacturing process results in the consumption of several natural sources and the generation of various types of wastes. The primary source of hazardous wastes at an automotive manufacturing plant is the painting process, and the major waste fraction is paint sludge, which is classified with EU waste code of 080113* implying hazardous characteristics. The amount of the paint sludge generated increases every year with the worldwide increase in the car production. The characteristics of the paint sludge, which mainly designate the management route, are mainly determined by the type of the paint used, application technique employed, and the chemicals applied such as flocculants, detackifiers, pH boosters, antifoam agents, and biocides as well as the dewatering techniques preferred. Major routes for the disposal of the paint sludges are incineration as hazardous waste or combustion at cement kilns. Because of high dissolved organic carbon content of the paint, the paint sludge cannot be accepted by landfills according to European Union Legislations. More investigations are needed in the field of paint sludge recycling such as recycling it as a new paint or as other formulations, or making use of the sludge for the production of construction materials. Research on the applicability of the paint sludge in composting and biogasification can also be useful. Ongoing research is currently being conducted on new application techniques to increase the effectiveness of paint transfer, which helps to prevent the generation of paint sludge. Advancements in paint and coating chemistry such as the reduction in the coating layers with its thickness also help to decrease the level of paint sludge generation. Investigations on the effects of the chemicals on the recycling potential of paint sludges and consideration of these effects by the chemical manufacturer companies would be extremely important. This review presents the formation of paint sludge, the factors affecting its characteristics, common disposal routes, the findings of the field trips to automotive manufacturing plants in Turkey, and a summary of the characterization findings of the paint sludge samples from a plant in Turkey.

Physicochemical and microbiological characterization of cement kiln dust for potential reuse in wastewater treatment.

Cement kiln dust (CKD), a byproduct of cement manufacturing process, was collected from Misr Cement Co. at Qena, Egypt. CKD was characterized by X-ray diffraction and FTIR analysis. This byproduct was investigated for its physical-chemical characters, antibacterial activities on sewage water and the presence of nematode, parasites and algae in the treated water. The efficiency of CKD-treated water was also examined on Hibiscus sabdarriffa seed germination. Total bacteria, total and fecal coliform, as well as fecal streptococci were completely inhibited by CKD. Interestingly, zinc, manganese, iron, nickel and lead were completely absent from sewage water as these metals precipitated after treatment with 10gl(-1) CKD. On the other hand, among all the tested plant criteria, only root length was significantly reduced by 55% and 15% after zero and 3 days of CKD addition respectively compared to control. Furthermore, plant lipid peroxidation showed no significant differences between treated sewage water and control after zero and 3 days time addition of CKD. Catalase enzyme activity showed significant decrease by 56% and 64%, while peroxidase activity significantly increased up to 49% and 63% compared to untreated sewage after zero and 3 days of treatment, respectively. The absorption of lead, iron and copper by treated and untreated plants showed no significant differences. Chromium ions were highly absorbed (0.075mgl(-1)) by plants irrigated only with treated sewage water at zero time, and decreased gradually to 0.018mgl(-1) after 3 days of CKD addition. This study highlighted the efficiency of cement kiln dust as an antibacterial agent and its ability of scavenging heavy metals leading to the use of treated sewage water in activities such as crop irrigation.

The effective treatment of dye-containing simulated wastewater by using the cement kiln dust as an industrial waste adsorbent.

This study compares the adsorption behavior of both Methylene Blue (MB) and Congo Red (CR) dyes on the surfaces of cement kiln dust (CKD) powder from the experimentally simulated wastewater solution. The cement kiln dust powder was characterized using X-ray Fluorescence (XRF), X-ray diffraction (XRD), N2 adsorption-desorption Brunauer-Emmett-Teller (BET), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy (SEM) tests. The adsorption for such dyes was studied under varying mixing contact times, temperatures, and pH as well as various initial concentrations of both dyes and adsorbent using the batch mode experiments. Pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were applied, and the results revealed that the pseudo-second-order fitted well to the kinetic data. Thermodynamic parameters stated that the adsorption process was endothermic. Studying Linear and nonlinear forms of Langmuir and Freundlich's adsorption isotherms revealed that the adsorption process was followed by both homogeneous mono-layer and heterogeneous multilayer coverage on the active sites of cement kiln dust particles. The data showed that the adsorption capacities of the methylene blue and Congo red dyes were 58.43 and 123.42 mg/g, respectively and cement kiln dust is an adsorbent with little cost for the treatment of wastewater.

Mechanical Behavior and Microstructure Evaluation of Quicklime-Activated Cement Kiln Dust-Slag Binder Pastes.

Cement kiln dust (CKD) is a by-product of cement production, which has the shortcomings of low utilization and high-temperature activation. This study combined CKD and slag as precursors for preparing pastes through quicklime activation under ambient conditions. The effects of quicklime and CKD content on the workability (flowability and setting time), macro-mechanical properties, and micro-structure of the CKD-slag binders were analyzed. The experimental results showed that the rapid precipitation of Ca2+, Si4+, and Al3+ ions from the CKD provided more nucleation sites for the formation of calcium aluminosilicate hydrate (C-(A)-S-H) gel and enhanced the reactivity of the binder system under the influence of the activator (CaO). The specimens had the highest unconfined compressive strength (UCS) (24.6 MPa) after 28 days with 10% quicklime content and 60% CKD content; scanning electron microscopy with energy-dispersive X-ray (SEM-EDX) analysis showed that the Ca/Si ratio of the C-(A)-S-H gel was minimized, leading to a denser microstructure and better binding ability under this mixing proportion. Therefore, this study may provide novel binder materials with a high proportion of CKD under ambient conditions.

Effect of silica fume substitution by limestone powder and cement kiln dust on the shrinkage, durability, and sustainability of UHPC.

Silica fume is usually used in UHPC, three times more than that for normal concrete, to enhance mechanical properties and durability. However, silica fume (SF) is an expensive material and has high production costs. This work is aimed at investigating the shrinkage and durability performance of previously developed UHPC mixtures utilizing the two calcareous waste materials, namely limestone powder (LSP) and cement kiln dust (CKD), by partially replacing the silica fume. The optimally selected mixtures of UHPC, having flow and strength above the minimum required, were used for detailed investigation in terms of shrinkage and durability characteristics. The results showed that by replacing SF with up to 20% of LSP and up to 20% of CKD, the mechanical properties of UHPC remained satisfactory compared to the control mixture with 100% SF. However, the ultimate shrinkage was higher for mixtures incorporating LSP or CKD, indicating the need for more volume of steel fibers to compensate for the shrinkage strains. The developed UHPCs also exhibited high resistance against reinforcement corrosion and sulfate attack, making them suitable for use in aggressive exposure conditions. However, special attention needs to be paid to the CKD content, where it is recommended to limit the content of CKD to about 15% or less to control the durability performance of the UHPCs. In addition, the sustainability analysis of developed UHPC mixtures was carried out using the life-cycle assessment and eco-strength intensity index. The results indicated that the UHPC mixtures possess a higher life-cycle and are therefore more sustainable.

Influence of Cement Kiln Dust on Long-Term Mechanical Behavior and Microstructure of High-Performance Concrete.

Cement production in the world market is steadily increasing. In 2000, it was 1600 million tons, while as of 2013, the annual amount exceeded 4000 million tons. The burning of cement clinker is associated with the generation of waste. It is estimated that the amount of cement kiln dust (CKD), during combustion, reaches about 15-20%, which means 700 million tons per year. However, not all types of by-products are reusable due to high alkali, sulfate, and chloride contents, which can adversely affect the environment. One environmentally friendly solution may be to use CKD in the production of high-performance concrete (HPC), as a substitute for some of the cement. This paper presents a study of the short- and long-term physical and mechanical properties of HPC with 5%, 10%, 15%, and 20% CKD additives. The experiments determined density, water absorption, porosity, splitting tensile strength, compressive strength, modulus of elasticity, ultrasonic pulse velocity, and evaluated the microstructure of the concrete. The addition of CKD up to 10% caused an increase in the 28- and 730-day compressive strengths, while the values decreased slightly when CKD concentration increased to 20%. Splitting tensile strength decreased proportionally with 5-20% amounts of CKD regardless of HPC age. Porosity, absorbability, and ultrasonic pulse velocity decreased with increasing cement dust, while the bulk density increased for HPC with CKD. Microstructure analyses showed a decrease in the content of calcium silicate hydrate (C-S-H), acceleration of setting, and formation of wider microcracks with an increase in CKD. From the results, it was shown that a 15% percentage addition of CKD can effectively replace cement in the production of HPC and contribute to reducing the amount of by-product from the burning of cement clinker.

A review of binders used in cemented paste tailings for underground and surface disposal practices.

Increased public awareness of environmental issues coupled with increasingly stringent environmental regulations pertaining to the disposal of sulphidic mine waste necessitates the mining industry to adopt more competent and efficient approaches to manage acid rock drainage. Cemented paste tailings (CPT) is an innovative form of amalgamated material currently available to the mining industry in developed countries. It is made usually from mill tailings mingled with a small amount of binder (customarily Portland cement) and water. The high cost associated with production and haulage of ordinary Portland cement and its alleged average performance as a sole binder in the long term (due to vulnerability to internal sulphate attack) have prompted users to appraise less expensive and technically efficient substitutes for mine tailings paste formulations. Generally, these binders include but are not limited to sulphate resistant cements, and/or as a partial replacement for Portland cement by artificial pozzolans, natural pozzolans, calcium sulphate substances and sodium silicates. The approach to designing environmentally efficient CPT is to ensure long-term stability and effective control over environmental contaminants through the use of composite binder systems with enhanced engineering properties to cater for inherit deficiencies in the individual constituents. The alkaline pore solution created by high free calcium rich cement kiln dust (CKD) (byproduct of cement manufacturing) is capable of disintegrating the solid glassy network of artificial pozzolans to produce reactive silicate and aluminate species when attacked by (OH(-)) ions. The augmented pozzolanic reactivity of CKD-slag and CKD-fly ash systems may produce resilient CPT. Since cemented paste comprising mine tailings and binders is a relatively new technology, a review of the binding materials used in such formulations and their performance evaluation in mechanical fill behaviour was considered pertinent in the study.

Incorporation and solidification mechanism of manganese doped cement clinker.

Using municipal and industrial solid waste as a substitute raw material and fuel in cement rotary kiln co-processing is considered an economic and environmentally friendly alternative to the use of traditional fuels. However, the presence of heavy metals in solid waste is a growing concern in the cement rotary kiln co-processing technique. The solidification mechanism of heavy metals in cement clinker is directly related to their stabilization. Cement clinkers doped with manganese oxide (MnO2: 0.0%-5.0% wt%) were prepared in a laboratory to investigate the impacts of extrinsic Mn on cement clinker calcination. The insignificant changes in X-ray diffractometer patterns indicated that the fixed Mn had little influence on the mineral lattice structure. Raman spectra and X-ray photoelectron spectroscopy revealed the transformation of the silicate phase when the Mn dose was increased. Moreover, the satisfactory solidification ratio confirmed the incorporation of Mn in the cement clinker. These results provided evidence of the influence rule of Mn in the cement clinker calcination process. Furthermore, Raman spectroscopy showed great potential for the qualitative and semi-quantitative analysis of the cementitious materials derived from cement rotary kiln co-processing. These results will be important for the further development of green cement manufacturing technology.

Formation kinetics and reaction behavior of pentavalent chromium formed in the cement kiln co-processing of solid waste.

Cement kiln co-processing is becoming the main strategy to dispose of hazardous waste containing Cr. A newly-discovered pentavalent Cr compound, which was proved to be formed during cement kiln co-processing of solid waste, is partly responsible for the water-soluble Cr released from the cement. However, the formation characteristics and the solubility of Cr(V) are still unclear to date. In this study, the reaction kinetics and further redox reactions of Cr(V) at high temperature were examined, and its crystal structure and solubility were also explored. At the temperature range of 1000-1200 °C, the formation rate of Ca5(CrO4)3O0.5 reached over 90 % within 10 min, and then slowly increased to near 100 % from 10 min to 10 h. shows that Ca5(CrO4)3O0.5 is formed by interface reaction at an early period, and by diffusion at a later period. The kinetic analysis indicates that Ca5(CrO4)3O0.5 is initially formed through an interface reaction and subsequently through diffusion. Ca5(CrO4)3O0.5 was identified and assigned as hexagonal crystal group (P63/m). Approximately 0.55 g and 0.15 g of Ca5(CrO4)3O0.5 dissolve in neutral water at 100 °C and 50 °C, and the concentrations of Cr(V) in water reach 550 and 150 mg/L, respectively. Additionally, this study finds that at the temperature range of 400-700 °C Ca5(CrO4)3O0.5 can be oxidized into CaCrO4, and at the temperature higher than 1400 °C, it can be further converted into Ca3(CrO4)2 and reduced into CaCr2O4. This study gives a deep insight into Cr oxidation-reduction reaction during thermal treatment of solid waste. These insights provide a comprehensive understanding of Cr oxidation-reduction reactions during the thermal treatment of solid waste, offering valuable guidance for waste management strategies.

Preparation of coated MgFe layered double hydroxide nanoparticles on cement kiln dust and intercalated with sodium dodecyl sulfate as an intermediate layer for the adsorption of estrogen from water.

Estrogenic hormones, found as micropollutants in water systems, give rise to grave concerns for human health and marine ecosystems, triggering a cascade of adverse effects. This research presents an innovative manufacturing approach using nanoscale layered double hydroxides of magnesium and iron, with sodium dodecyl sulfate surfactant, to create highly efficient sorbent cement kiln dust (CKD) based beads (CKD/MgFe-SDS-LDH-beads). These beads effectively remove estrone from water. Optimization of the preparation process considered factors like molar Mg/Fe ratio, CKD dosage, pH, and SDS dosage using Response Surface Methodology (RSM). The adsorption process was well-characterized by Langmuir isotherm and pseudo-second-order kinetic models, demonstrating a remarkable 6.491 mg/g sorption capacity. Results proved that the calcite was the main component of the CKD with miners of dolomite, and quartz. Adsorption capacity, surface charges, and the availability of vacant sites may be the main mechanisms responsible of removal process. Experimental tests confirmed the beads' potential for estrone removal, aligning with the Bohart-Adams and Thomas-BDST models. This study introduces a promising, eco-friendly solution for addressing water contamination challenges.

Co-processing of plastic waste in a cement kiln: a better option.

This paper deals with the techniques to use plastic waste for co-processing in cement kiln for energy recovery. Plastics, a versatile material and friend to the common man, have now become one of the most serious environmental issues when it is discarded into the environment. The focus of this study is on eco-friendly disposal of plastic waste. Plastic is user-friendly, but because of its incomplete lifecycle, it has become a global issue. It is commonly disposed of by land filling or incinerating the waste, which adds to the pollution load at later stages. The authors' focus is on innovative techniques to use waste plastics in different proportions for the co-processing in cement kiln in order to highlight the energy recovery of the entire plant. It is a good solution to the waste disposal problems that arise due to plastic waste as well as municipal solid waste. The use of plastic waste as an alternative fuel for cement plants is suggested in this paper. The authors also promote this approach and suggest encouraging its calorific value utilization in the cement manufacturing plant. A systematic approach has been presented in this work to mitigate the energy consumption in the cement industries as well as environmental hazards due to plastic and municipal solid waste.