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1.
Small ; : e2400221, 2024 Apr 08.
Artigo em Inglês | MEDLINE | ID: mdl-38586921

RESUMO

Aqueous zinc-ion batteries (ZIBs) stand out as a promising next-generation electrochemical energy storage technology, offering notable advantages such as high specific capacity, enhanced safety, and cost-effectiveness. However, the application of aqueous electrolytes introduces challenges: Zn dendrite formation and parasitic reactions at the anode, as well as dissolution, electrostatic interaction, and by-product formation at the cathode. In addressing these electrode-centric problems, additive engineering has emerged as an effective strategy. This review delves into the latest advancements in electrolyte additives for ZIBs, emphasizing their role in resolving the existing issues. Key focus areas include improving morphology and reducing side reactions during battery cycling using synergistic effects of modulating anode interface regulation, zinc facet control, and restructuring of hydrogen bonds and solvation sheaths. Special attention is given to the efficacy of amino acids and zwitterions due to their multifunction to improve the cycling performance of batteries concerning cycle stability and lifespan. Additionally, the recent additive advancements are studied for low-temperature and extreme weather applications meticulously. This review concludes with a holistic look at the future of additive engineering, underscoring its critical role in advancing ZIB performance amidst the complexities and challenges of electrolyte additives.

2.
Small ; : e2310912, 2024 Mar 04.
Artigo em Inglês | MEDLINE | ID: mdl-38438937

RESUMO

All-solid-state lithium batteries (ASSLBs) are highly promising as next-generation energy storage devices owing to their potential for great safety and high energy density. This work demonstrates that composite solid polymer electrolyte with vertically-aligned card-house structure can simultaneously improve the high rate and long-term cycling performance of ASSLBs. The vertical alignment of laponite nanosheets creates fast and uniform Li+ ion transport channels at the nanosheets/polymer interphase, resulting in high ionic conductivity of 8.9 × 10-4 S cm-1 and Li+ transference number of 0.32 at 60 °C, as well as uniformly distributed solid electrolyte interphase. Such electrolyte is characterized by high mechanical strength, low flammability, excellent structural stability and stable ion transport channels. In addition, the ASSLB cell with the electrolyte and LiFePO4 cathode delivers a high discharge specific capacity of 124.8 mAh g-1 , which accounts for 85.6% of its initial capacity after 500 cycles at 1C. The reasonable design through structural control strategy by interconnecting the vertically-aligned nanosheets open a way to fabricate high performance composite solid polymer electrolytes.

3.
Eur J Appl Physiol ; 124(1): 343-352, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-37517068

RESUMO

PURPOSE: Polluted environments can adversely affect lung function and exercise performance. Evidence suggests that some nutrient supplements may offset pollution's detrimental effects. This study examined the effect of polyphenol supplementation on lung function and exercise performance in an ozone-polluted environment. METHODS: Ten male cyclists (mean ± SD: age, 43.8 ± 12.4 years; height, 177.8 ± 7.1 cm; weight, 76.03 ± 7.88 kg; VO2max 4.12 ± 0.72 L min-1) initially completed a baseline maximal incremental test and maximal effort 4 km time trial in ambient air. Thereafter cyclists completed two trials in an ozone-polluted environment (0.25 ppm) following seven days of supplementation with either polyphenol (PB) or placebo (PL). Experimental trials consisted of a three-stage submaximal test (50%, 60% and 70% incremental peak power) followed by a 4 km time trial. Lung function was measured pre- and post-exercise via spirometry and adverse respiratory symptoms with a Likert scale. RESULTS: Ozone exposure significantly reduced (p < 0.05) lung function relative to ambient air. There were no significant differences (p > 0.05) in measured variables across the three submaximal intensities. There was a small (d = 0.31) non-significant difference (p = 0.09) in 4 km performance in PB (406.43 ± 50.29 s) vs. PL (426.20 ± 75.06 s). Oxygen consumption during the time trial was greater in PB (3.49 ± 0.71 L min-1) vs PL (3.32 ± 0.71 L min-1, p = 0.01, d = 0.24). Cough severity (SOC) was lower (p = 0.03) with PB relative to PL. CONCLUSION: PB supplementation may provide small benefits to performance and reduce cough symptoms during high-intensity exercise in ozone-polluted environments.


Assuntos
Desempenho Atlético , Ozônio , Adulto , Humanos , Masculino , Pessoa de Meia-Idade , Ciclismo , Tosse/induzido quimicamente , Suplementos Nutricionais , Pulmão , Consumo de Oxigênio , Ozônio/efeitos adversos , Pós
4.
Eur J Appl Physiol ; 124(7): 2005-2017, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38376510

RESUMO

PURPOSE: This study examined the repeated bout effect of two resistance training bouts on cycling efficiency and performance. METHODS: Ten male resistance-untrained cyclists (age 38 ± 13 years; height 180.4 ± 7.0 cm; weight 80.1 ± 10.1; kg; VO2max 51.0 ± 7.6 ml.kg-1.min-1) undertook two resistance training bouts at six-repetition maximum. Blood creatine kinase (CK), delayed-onset of muscle soreness (DOMS), counter-movement jump (CMJ), squat jump (SJ), submaximal cycling and time-trial performance were examined prior to (Tbase), 24 (T24) and 48 (T48) h post each resistance training bout. RESULTS: There were significantly lower values for DOMS (p = 0.027) after Bout 2 than Bout 1. No differences were found between bouts for CK, CMJ, SJ and submaximal cycling performance. However, jump height (CMJ and SJ) submaximal cycling measures (ventilation and perceived exertion) were impaired at T24 and T48 compared to Tbase (p < 0.05). Net efficiency during submaximal cycling improved at Bout 2 (23.8 ± 1.2) than Bout 1 (24.3 ± 1.0%). There were no changes in cycling time-trial performance, although segmental differences in cadence were observed between bouts and time (i.e. Tbase vs T24 vs T48; p < 0.05). CONCLUSION: Cyclists improved their cycling efficiency from Bout 1 to Bout 2 possibly due to the repeated bout effect. However, cyclists maintained their cycling completion times during exercise-induced muscle damage (EIMD) in both resistance training bouts, possibly by altering their cycling strategies. Thus, cyclists should consider EIMD symptomatology after resistance training bouts, particularly for cycling-specific technical sessions, regardless of the repeated bout effect.


Assuntos
Desempenho Atlético , Ciclismo , Treinamento Resistido , Humanos , Masculino , Treinamento Resistido/métodos , Adulto , Ciclismo/fisiologia , Desempenho Atlético/fisiologia , Mialgia/fisiopatologia , Músculo Esquelético/fisiologia , Creatina Quinase/sangue , Consumo de Oxigênio/fisiologia
5.
Eur J Appl Physiol ; 124(6): 1659-1668, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38198009

RESUMO

PURPOSE: To determine if post-exercise heart rate variability, in the form of logged transformed root mean square of successive differences of the R-R intervals (LnRMSSD) can be measured reliably during the recovery from a submaximal cycle test and what the relationship of LnRMSSD is with training status of the cyclists. METHODS: Fourteen male cyclists participated in the reliability part for the study, which included performing six Lamberts Submaximal Cycle Test (LSCT), during which recovery LnRMSSD was measured over 30 s (LnRMSSD30 s), 60 s LnRMSSD60 s)and 90 s LnRMSSD90 s). In addition, fifty male and twenty female cyclists completed a peak power output (PPO) test (including VO2peak) and 40 km time trial (40 km TT) before which they performed the LSCT as a standardized warm-up. Relationships between the LnRMSSD and PPO, VO2peak and 40 km TT time were studied. RESULTS: Due to the design of the LSCT, submaximal heart and breathing rate were similar at the end of stage 3 of the LSCT, as well as during the recovery periods. The highest reliability was found in LnRMSSD60 s (ICC: 0.97) with a typical error of the measurement (TEM: 5.8%). In line with this the strongest correlations were found between LnRMSSD60 s and PPO (r = 0.93[male]; 0.85[female]), VO2peak (r = 0.71[male]; 0.63[female];) and 40 km TT (r = - 0.83[male]; - 0.63[female]). CONCLUSIONS: LnRMSSD60 s can be measured reliably after the LSCT and can predict PPO, VO2peak and 40 km TT performance well in trained-to-elite cyclists. These findings suggest that recovery LnRMSSD can potentially play an important role in monitoring and fine-tuning training prescriptions in trained-to-elite cyclists.


Assuntos
Ciclismo , Teste de Esforço , Frequência Cardíaca , Humanos , Masculino , Frequência Cardíaca/fisiologia , Ciclismo/fisiologia , Feminino , Adulto , Teste de Esforço/métodos , Reprodutibilidade dos Testes , Consumo de Oxigênio/fisiologia , Atletas
6.
Molecules ; 29(10)2024 May 07.
Artigo em Inglês | MEDLINE | ID: mdl-38792041

RESUMO

Using silicon/reduced graphene oxide (Si/rGO) composites as lithium-ion battery (LIB) anodes can effectively buffer the volumetric expansion and shrinkage of Si. Herein, we designed and prepared Si/rGO-b with a sandwiched structure, formed by a duple combination of ammonia-modified silicon (m-Si) nanoparticles (NP) with graphene oxide (GO). In the first composite process of m-Si and GO, a core-shell structure of primal Si/rGO-b (p-Si/rGO-b) was formed. The amino groups on the m-Si surface can not only hybridize with the GO surface to fix the Si particles, but also form covalent chemical bonds with the remaining carboxyl groups of rGO to enhance the stability of the composite. During the electrochemical reaction, the oxygen on the m-Si surface reacts with lithium ions (Li+) to form Li2O, which is a component of the solid-electrolyte interphase (SEI) and is beneficial to buffering the volume expansion of Si. Then, the p-Si/rGO-b recombines with GO again to finally form a sandwiched structure of Si/rGO-b. Covalent chemical bonds are formed between the rGO layers to tightly fix the p-Si/rGO-b, and the conductive network formed by the reintroduced rGO improves the conductivity of the Si/rGO-b composite. When used as an electrode, the Si/rGO-b composite exhibits excellent cycling performance (operated stably for more than 800 cycles at a high-capacity retention rate of 82.4%) and a superior rate capability (300 mA h/g at 5 A/g). After cycling, tiny cracks formed in some areas of the electrode surface, with an expansion rate of only 27.4%. The duple combination of rGO and the unique sandwiched structure presented here demonstrate great effectiveness in improving the electrochemical performance of alloy-type anodes.

7.
Scand J Med Sci Sports ; 33(9): 1677-1689, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37322619

RESUMO

PURPOSE: Carbohydrate (CHO) intake periodization via the sleep low train low (SL-TL) diet-exercise model increases fat oxidation during exercise and may enhance endurance-training adaptation and performance. Conversely, training under environmental heat stress increases CHO oxidation, but the potential of combined SL-TL and heat stress to enhance metabolic and performance outcomes is unknown. METHODS: Twenty-three endurance-trained males were randomly assigned to either control (n = 7, CON), SL-TL (n = 8, SLTemp ) or SL-TL + heat stress (n = 8, SLHeat ) groups and prescribed identical 2-week cycling training interventions. CON and SLTemp completed all sessions at 20°C, but SLHeat at 35°C. All groups consumed matched CHO intake (6 g·kg-1 ·day-1 ) but timed differently to promote low CHO availability overnight and during morning exercise in both SL groups. Submaximal substrate utilization was assessed (at 20°C), and 30-min performance tests (at 20 and 35°C) were performed Pre-, Post-, and 1-week post-intervention (Post+1). RESULTS: SLTemp improved fat oxidation rates at 60% MAP (~66% VO2peak ) at Post+1 compared with CON (p < 0.01). Compared with SLTemp , fat oxidation rates were significantly lower in SLHeat at Post (p = 0.02) and Post+1 (p < 0.05). Compared with CON, performance was improved at Post in SLTemp in temperate conditions. Performance was not different between any groups or time points in hot conditions. CONCLUSION: SL-TL enhanced metabolic adaptation and performance compared with CON and combined SL-TL and heat stress. Additional environmental heat stress may impair positive adaptations associated with SL-TL.


Assuntos
Carboidratos da Dieta , Resistência Física , Humanos , Masculino , Exercício Físico , Dieta , Adaptação Fisiológica , Resposta ao Choque Térmico
8.
Eur J Appl Physiol ; 2023 Nov 30.
Artigo em Inglês | MEDLINE | ID: mdl-38032386

RESUMO

The study aimed to investigate the effects of sodium bicarbonate (NaHCO3) intake with divergent verbal and visual information on constant load cycling time-to-task failure, conducted within the severe intensity domain. Fifteen recreational cyclists participated in a randomized double-blind, crossover study, ingesting NaHCO3 or placebo (i.e., dextrose), but with divergent information about its likely influence (i.e., likely to induce ergogenic, inert, or harmful effects). Performance was evaluated using constant load cycling time to task failure trial at 115% of peak power output estimated during a ramp incremental exercise test. Data on blood lactate, blood acid-base balance, muscle electrical activity (EMG) through electromyography signal, and the twitch interpolation technique to assess neuromuscular indices were collected. Despite reduced peak force in the isometric maximal voluntary contraction and post-effort peripheral fatigue in all conditions (P < 0.001), neither time to task failure, EMG nor, blood acid-base balance differed between conditions (P > 0.05). Evaluation of effect sizes of all conditions suggested that informing participants that the supplement would be likely to have a positive effect (NaHCO3/Ergogenic: 0.46; 0.15-0.74; Dextrose/Ergogenic: 0.45; 0.04-0.88) resulted in improved performance compared to control. Thus, NaHCO3 ingestion consistently induced alkalosis, indicating that the physiological conditions to improve performance were present. Despite this, NaHCO3 ingestion did not influence performance or indicators of neuromuscular fatigue. In contrast, effect size estimates indicate that participants performed better when informed that they were ingesting an ergogenic supplement. These findings suggest that the apparently ergogenic effect of NaHCO3 may be due, at least in part, to a placebo effect.

9.
Molecules ; 28(13)2023 Jun 21.
Artigo em Inglês | MEDLINE | ID: mdl-37446558

RESUMO

Li3V2(PO4)3 (LVP) is one of the candidates for high-energy-density cathode materials matching lithium metal batteries due to its high operating voltage and theoretical capacity. However, the inevitable side reactions of LVP with a traditional liquid-state electrolyte under high voltage, as well as the uncontrollable growth of lithium dendrites, worsen the cycling performance. Herein, a hybrid solid-state electrolyte is prepared by the confinement of a lithium-containing ionic liquid with a mesoporous SiO2 scaffold, and used for a LVP-cathode-based lithium metal battery. The solid-state electrolyte not only exhibits a high ionic conductivity of 3.14 × 10-4 S cm-1 at 30 °C and a wide electrochemical window of about 5 V, but also has good compatibility with the LVP cathode material. Moreover, the cell paired with a solid-state electrolyte exhibits good reversibility and can realize a stable operation at a voltage of up to 4.8 V, and the discharge capacity is well-maintained after 100 cycles, which demonstrates excellent capacity retention. As a contrast, the cell paired with a conventional liquid-state electrolyte shows only an 87.6% discharge capacity retention after 100 cycles. In addition, the effectiveness of a hybrid solid-state electrolyte in suppressing dendritic lithium is demonstrated. The work presents a possible choice for the use of a hybrid solid-state electrolyte compatible with high-performance cathode materials in lithium metal batteries.


Assuntos
Líquidos Iônicos , Lítio , Dióxido de Silício , Eletrólitos , Íons , Eletrodos
10.
Nanotechnology ; 33(40)2022 Jul 13.
Artigo em Inglês | MEDLINE | ID: mdl-35679816

RESUMO

Heteroatom-doped carbon can significantly improve the electrochemical performance of LiFePO4cathodes, but it is limited by the complex preparation process and expensive dopants. A self-assembled S-doped LiFePO4@N/S-doped C core-shell structured composites were synthesized by a convenient solvothermal method are reported. The structure and the electrochemical performance of the composites were characterized. In the S-doped LiFePO4@N/S-doped C composites, the glucose-derived carbon microspheres were attached by LiFePO4/C particles to form secondary particles in the core-shell structure. The thioacetamide regulated the morphology of LiFePO4/C particles and provided N and S atoms to dope the composites. The S-doped LiFePO4@N/S-doped C composites delivered specific discharge capacities of 157.81 mAh g-1at 0.1 C and 121.26 mAh g-1at 5 C, and capacity retention of 99.88% after 100 charge/discharge cycles. The excellent electrochemical performance of the S-doped LiFePO4@N/S-doped C composites can be attributed to the synergism of thioacetamide and glucose.

11.
Int J Sport Nutr Exerc Metab ; 32(4): 296-310, 2022 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-35231883

RESUMO

This systematic review analyzed whether carbohydrate source (food vs. supplement) influenced performance and gastrointestinal (GI) symptoms during endurance exercise. Medline, SPORTDiscus, and citations were searched from inception to July 2021. Inclusion criteria were healthy, active males and females aged >18 years, investigating endurance performance, and GI symptoms after ingestion of carbohydrate from a food or supplement, <60 min before or during endurance exercise. The van Rosendale scale was used to determine risk of bias, with seven studies having low risk of bias. A total of 151 participants from 15 studies were included in the review. Three studies provided 0.6-1 g carbohydrate/kg body mass during 5-45 min precycling exercise (duration 60-70 min) while 12 studies provided 24-80 g/hr carbohydrate during exercise (60-330 min). Except one study that suggested a likely harmful effect (magnitude-based inferences) of a bar compared to a gel consumed during exercise on cycling performance, there were no differences in running (n = 1) or cycling (n = 13) performance/capacity between food and supplemental sources. Greater GI symptoms were reported with food compared with supplemental sources. Highly heterogenous study designs for carbohydrate dose and timing, as well as exercise protocol and duration, make it difficult to compare findings between studies. A further limitation results from only one study assessing running performance. Food choices of carbohydrate consumed immediately before and during endurance exercise result in similar exercise performance/capacity responses to supplemental carbohydrate sources, but may slightly increase GI symptoms in some athletes, particularly with exercise >2 hr.


Assuntos
Resistência Física , Corrida , Ciclismo/fisiologia , Carboidratos da Dieta/farmacologia , Suplementos Nutricionais , Feminino , Humanos , Masculino , Resistência Física/fisiologia , Corrida/fisiologia
12.
Biol Sport ; 39(2): 329-340, 2022 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-35309528

RESUMO

Changes and relationships between cycling performance indicators following a one-year strength and conditioning training have not been totally clarified. The aims of this study are to investigate (i) the effect of a combined one-year strength and conditioning training programme on performance indicators and the possible relationships between these indicators, and (ii) the existence of possible endurance-functional-adaptive windows (EFAWs) linked to changes in muscular strength and body composition markers. Functional and lactate threshold power (FTP and LTP), maximal strength (1RM) and body composition (body mass index [BMI], body cell mass [BCM] and phase angle [PA]) were measured at the beginning and the end of a one-year strength and conditioning training programme of thirty cyclists. Correlations, differences, and predictive analysis were performed among parameters. Significant differences were found between pre- and post-conditioning programme results for FTP, LTP, 1RM (p < 0.0001) and BCM (p = 0.038). When expressed as power output (W), FTP and LTP were significantly correlated with 1RM (r = 0.36, p = 0.005 and r = 0.37, p = 0.004, respectively), body mass (r = 0.30 and p = 0.02), BCM (r = 0.68, p < 0.001) and PA (r = 0.42 and 0.39, respectively and p < 0.001). When expressed as W·kg-¹, these power thresholds were strongly correlated with body mass (r = -0.56 and -0.61, respectively) and BMI (r = -0.57 and -0.61 respectively) with p < 0.001. Predictive polynomial regressions revealed possible endurance and strength adaptation zones. The present findings indicated beneficial impacts of one-year strength and conditioning training on cycling performance indicators, confirmed the correlation between performance indicators, and suggested the existence of different EFAWs. Strategies aiming to improve performance should consider cyclist characteristics and performance goals to achieve EFAWs and thereby enhance cycling performance.

13.
Angew Chem Int Ed Engl ; 60(30): 16506-16513, 2021 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-34010506

RESUMO

Lithium (Li)-magnesium (Mg) alloy with limited Mg amount, which can also be called Mg-doped Li (Li-Mg), has been considered as a potential alternative anode for high energy density rechargeable Li metal batteries. However, the optimum doping-content of Mg in Li-Mg anode and the mechanism of the improved performance are not well understood. Herein, density functional theory (DFT) calculations are used to investigate the effect of Mg amount in Li-Mg anode. The Li-Mg with about 5 wt. % Mg (abbreviated as Li-Mg5) has the lowest absorption energy of Li, thus all the surface area can be "controlled" by Mg atoms, leading to the smooth and continuous deposition of Li on the surface around the Mg center. A localized high concentration electrolyte enables Li-Mg5 to exhibit the best cycling stability in Li metal batteries with high-loading cathode and lean electrolyte under 4.4 V high-voltage, which is approaching the demand of practical application. This electrolyte also helps generate an inorganic-rich solid electrolyte interphase, which leads to smooth, compact and less corrosion layer on the Li-Mg5 surface. Both theoretical simulations and experimental results prove that Li-Mg5 has optimum Mg content and gives best battery cycling performance.

14.
Scand J Med Sci Sports ; 30(5): 849-857, 2020 May.
Artigo em Inglês | MEDLINE | ID: mdl-31977120

RESUMO

The purpose of this study was to compare the effects of 3 weeks with three weekly sessions (ie, nine sessions in total) of short intervals (SI; n = 9; 3 series with 13 × 30-second work intervals interspersed with 15-second recovery and 3-minutes recovery between series) against effort-matched (rate of perceived effort based) long intervals (LI; n = 9; 4 series of 5-minute work intervals with 2.5-minutes recovery between series) on performance parameters in elite cyclists ( V ˙ O 2max 73 ± 4 mL min-1  kg-1 ). There were no differences between groups in total volume and intensity distribution of training during the intervention period. SI achieved a larger (P < .05) relative improvement in peak aerobic power output than LI (3.7 ± 4.3% vs -0.3 ± 2.8%, respectively), fractional utilization of V ˙ O 2max at 4 mmol L-1 [La- ] (3.0 ± 5.8 percent points vs -3.5 ± 2.7 percent points, respectively), and larger relative increase in power output at 4 mmol L-1 [La- ] (2.0 ± 6.7% vs -2.8 ± 3.4, respectively), while there was no group difference in change of V ˙ O 2max . Improvements in performance measured as mean power output during 20-minute cycling test were greater (P < .01) in SI compared with LI (4.7 ± 4.4% vs -1.4 ± 2.2%, respectively). Mean effect size of the improvement in the above variables revealed a small to large effect of SI training vs LI training. The data thus demonstrate that the present SI protocol induces superior training adaptations compared with the present LI protocol in elite cyclists.


Assuntos
Desempenho Atlético/fisiologia , Ciclismo/fisiologia , Treino Aeróbico/métodos , Treinamento Intervalado de Alta Intensidade/métodos , Consumo de Oxigênio , Adolescente , Adulto , Humanos , Masculino , Fatores de Tempo , Adulto Jovem
15.
Small ; 15(47): e1904545, 2019 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-31588653

RESUMO

Aqueous Zn-MnO2 batteries using mild electrolyte show great potential in large-scale energy storage (LSES) application, due to high safety and low cost. However, structure collapse of manganese oxides upon cycling caused by the conversion mechanism (e.g., from tunnel to layer structures for α-, ß-, and γ-phases) is one of the most urgent issues plaguing its practical applications. Herein, to avoid the phase conversion issue and enhance battery performance, a structurally robust novel phase of manganese oxide MnO2 H0.16 (H2 O)0.27 (MON) nanosheet with thickness of ≈2.5 nm is designed and synthesized as a promising cathode material, in which a nanosheet structure combined with a novel H+ /Zn2+ synergistic intercalation mechanism is demonstrated and evidenced. Accordingly, a high-performance Zn/MON cell is achieved, showing a high energy density of ≈228.5 Wh kg-1 , impressive cyclability with capacity retention of 96% at 0.5 C after 300 cycles, as well as exhibiting rate performance of 115.1 mAh g-1 at current rate of 10 C. To the best current knowledge, this H+ /Zn2+ synergistic intercalation mechanism is first reported in an aqueous battery system, which opens a new opportunity for development of high-performance aqueous Zn ion batteries for LSES.

16.
Nitric Oxide ; 85: 44-52, 2019 04 01.
Artigo em Inglês | MEDLINE | ID: mdl-30685420

RESUMO

Dietary nitrate (NO3-) supplementation via beetroot juice (BR) is known to improve endurance performance in untrained and moderately trained individuals. However, conflicting results exist in well-trained individuals. Evidence suggests that the effects of NO3- are augmented during conditions of reduced oxygen availability (e.g., hypoxia), thereby increasing the probability of performance improvements for well-trained athletes in hypoxia vs. normoxia. This randomized, double-blinded, counterbalanced-crossover study examined the effects of 7 days of BR supplementation with 12.4 mmol NO3- per day on 10-km cycling time trial (TT) performance in 12 well-trained cyclists in normoxia (N) and normobaric hypoxia (H). Linear mixed models for repeated measures revealed increases in plasma NO3- and NO2- after supplementation with BR (both p < 0.001). Further, TT performance increased with BR supplementation (∼1.6%, p < 0.05), with no difference between normoxia and hypoxia (p = 0.92). For respiratory variables there were significant effects of supplementation on VO2 (p < 0.05) and VE (p < 0.05) such that average VO2 and VE during the TT increased with BR, with no difference between normoxia and hypoxia (p ≥ 0.86). We found no effect of supplementation on heart rate, oxygen saturation or muscle oxygenation during the TT. Our results provide new evidence that chronic high-dose NO3- supplementation improves cycling performance of well-trained cyclists in both normoxia and hypoxia.


Assuntos
Beta vulgaris/química , Suplementos Nutricionais , Sucos de Frutas e Vegetais , Hipóxia/metabolismo , Oxigênio/metabolismo , Adulto , Estudos Cross-Over , Relação Dose-Resposta a Droga , Humanos , Masculino , Consumo de Oxigênio , Fatores de Tempo , Adulto Jovem
17.
J Sports Sci ; 37(3): 291-297, 2019 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-30020858

RESUMO

The purpose of this study was to analyze the pacing strategy and its affective consequences during self-paced cycling time trials (TT) performed at different severity of hypoxia. Eight competitive cyclists performed five 30 min self-paced TTs at their best performance in the following conditions: 1) normobaric normoxia (NNSL); 2) normobaric hypoxia under two simulated altitudes: 2000 m (NH2000) and 3500 m (NH3500) and 3) normobaric hypoxia but the cyclists were deceived and thought to be at sea level for 2000 m (DecNH2000) and 3500 m (DecNH3500). Power Output (PO), oxygen uptake (VO2), and blood lactate concentration ([La]) were recorded to assess exercise intensity and physiological adaptations. The rate of perceived exertion (RPE) and pleasure were measured with a CR10 Borg scale to evaluate the affective load (AL). PO and VO2 decreased with the severity of hypoxia but no significantly difference on performance was measured between deceived and real conditions, except for pacing strategy. The started intensity depends on the exercise expectations, but PO was rapidly adjusted with the physiological constraints and the rate of increase of RPE. Finally, AL did not reach maximal values so that the athletes sustained a physiological and emotional reserve to perform a final spurt.


Assuntos
Afeto , Desempenho Atlético/fisiologia , Desempenho Atlético/psicologia , Ciclismo/fisiologia , Ciclismo/psicologia , Retroalimentação Psicológica , Adulto , Altitude , Atletas , Frequência Cardíaca , Humanos , Hipóxia , Ácido Láctico/sangue , Masculino , Consumo de Oxigênio , Esforço Físico , Adulto Jovem
18.
Scand J Med Sci Sports ; 28(12): 2473-2480, 2018 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-30113750

RESUMO

The importance of accumulated time ≥90% of maximal oxygen consumption (VO2max ) to improve performance in well-trained endurance athletes is well established. The present study compared the acute effects of adding vibrations (VIB; 40 Hz) with the work intervals during a high-intensity cycling session (HIT) with a traditional HIT session without vibration (TRAD) on time ≥90% of VO2max , time ≥90% of peak heart rate (HRpeak ), electromyography (EMG) activity, and mean power in well-trained cyclists (n = 10, VO2max =78.6 ± 7.4 mL/min/kg). The order of VIB and TRAD was randomized and consisted of 6 × 5-minutes work intervals performed with the highest possible mean power across the work intervals (2.5-minutes standardized relief periods). VIB was superior to TRAD on time ≥90% of VO2max , (10.99 ± 7.00 vs 6.95 ± 5.28 minutes, respectively), time ≥90% of HRpeak (24.61 ± 2.38 vs 19.97 ± 4.12 minutes, respectively), and averaged EMG activity in m. Vastus Lateralis during the work intervals (all P < 0.05). The EMG/power output ratio across all work intervals was higher in VIB than TRAD (P < 0.05). Mean values across work intervals showed no difference between VIB and TRAD in mean power, rate of perceived exertion, or blood lactate concentration. Thus, the present study indicated that adding vibration to the work intervals during a HIT session can acutely increase the physiological responses of the cardiovascular system and increase time ≥90% VO2max and should therefore be considered in order to optimize the exercise stimulus of well-trained cyclists.


Assuntos
Ciclismo/fisiologia , Treinamento Intervalado de Alta Intensidade , Consumo de Oxigênio , Vibração , Adulto , Eletromiografia , Frequência Cardíaca , Humanos , Ácido Láctico/sangue , Masculino , Adulto Jovem
19.
J Sports Sci ; 36(10): 1095-1102, 2018 May.
Artigo em Inglês | MEDLINE | ID: mdl-28721747

RESUMO

This study compared the responses of two priming exercises of similar fatigue on the adjustment of the oxygen uptake time constant (τV̇O2) in cycling. Ten healthy young adults (25 ± 3 yr) performed: three step transitions from a 20-W baseline to the power output (PO) below the gas exchange threshold (MOD, MODPRE); a 3-min bout (P3MIN) at 90% of peak PO (POpeak), followed by MOD (MOD3MIN); and a 6-min bout (P6MIN) at 80% of POpeak, followed by MOD (MOD6MIN). The O2 supply-to-O2 demand ([HHb]/V̇O2) ratio was calculated for MODPRE, MOD3MIN, and MOD6MIN. Neuromuscular fatigue was measured isometrically pre- and post-priming exercise. Reductions in maximal voluntary contraction (-29 ± 6 vs -34 ± 7%) and high-frequency doublet amplitude (-48 ± 13 vs -43 ± 11%) were not significantly different between P3MIN vs P6MIN, suggesting similar fatigue. τV̇O2 for MOD3MIN and MOD6MIN were similar, being ~25% smaller than MODPRE. The [HHb]/V̇O2 ratio was significantly greater in MODPRE (1.13 ± 0.12) compared to MOD3MIN (1.02 ± 0.04) and MOD6MIN (1.02 ± 0.04). This study showed that priming exercise of shorter duration and higher intensity, was sufficient to accelerate V̇O2 kinetics similarly to that observed subsequent to P6MIN when the muscle fatigue was similar.


Assuntos
Ciclismo/fisiologia , Fadiga Muscular/fisiologia , Consumo de Oxigênio/fisiologia , Exercício de Aquecimento/fisiologia , Adulto , Feminino , Frequência Cardíaca/fisiologia , Humanos , Ácido Láctico/sangue , Masculino , Percepção/fisiologia , Esforço Físico/fisiologia , Troca Gasosa Pulmonar/fisiologia , Fatores de Tempo , Adulto Jovem
20.
J Sports Sci Med ; 17(3): 485-491, 2018 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-30116122

RESUMO

This study aimed to assess the separate and combined effects of a cooling glove (CG) and a gel-cooling jacket (CJ) used during a half-time break on manual dexterity performance (Purdue Pegboard test) and subsequent repeat-sprint cycling performance in hot conditions. Twelve male athletes performed four experimental trials (within subjects, counterbalanced design) that consisted of: wearing a CG, wearing a CJ, combination of CG and CJ (CG+J) or a no-cooling control (NC) for 15 min during a 20 min half-time break performed between 2 x 30 min repeated-sprint cycling bouts in heat (35.0 ± 1.2°C and 52.5 ± 7.4% RH). Manual dexterity (dominant and non-dominant hand) was assessed immediately before and after the first-half of exercise, then immediately after cooling and the second-half of exercise. No differences were found for manual dexterity performance between trials or over time (p > 0.05). Additionally, no differences were found for power and work performance variables assessed during the second-half of exercise (p > 0.05), however participants felt 'cooler' wearing CG+J compared to NC (Thermal Sensation scale; p = 0.041). Further, no differences were found between trials for changes in gastrointestinal core temperature for any time period assessed (p > 0.05). In conclusion, the cooling trials did not affect manual dexterity or second-half repeated-sprint cycling performance compared to NC.


Assuntos
Desempenho Atlético/fisiologia , Vestuário , Temperatura Baixa , Destreza Motora/fisiologia , Temperatura Corporal , Exercício Físico , Temperatura Alta , Humanos , Masculino , Adulto Jovem
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