RESUMO
Untreated polyester films and fibers can be hardly printed or coated, in particular if aqueous inks or lacquers have to be applied. Therefore, an adequate primer layer has to be applied first. A cationic polymer formulation based on poly(dimethylamine-co-epichlorohydrin-co-ethylenediamine) (PDEHED) was used as primer layer for digital printing on polyester fabrics. Because of the exceedingly high requirements on the homogeneity of such layers, hyperspectral imaging was used for qualitative and quantitative monitoring of the distribution of the primer layer on the textiles. Multivariate data analysis methods based on the PLS algorithm were applied for quantification of the NIR reflection spectra using gravimetry as a reference method. Optimization of the calibration method resulted in various models with prediction errors of about 1.2 g/m2. The prediction performance of the models was proven in external validations using independent samples. Moreover, a special ink jet printing technology was tested for application of the aqueous primer formulation itself. Since possible clogging of jet nozzles in the print head might lead to inhomogeneity in the coatings such as missing tracks, the potential of hyperspectral imaging to detect such defects was investigated. It was demonstrated that simulated missing tracks can be clearly detected. Consequently, hyperspectral imaging has been proven to be a powerful analytical tool for in-line monitoring of the quality of printability improvement layers and similar systems.