Rewritable Photonic Integrated Circuit Canvas Based on Low-Loss Phase Change Material and Nanosecond Pulsed Lasers.

Programmable photonic integrated circuits (PICs) are an increasingly important platform in optical science and engineering. However, current programmable PICs are mostly formed through subtractive fabrication techniques, which limits the reconfigurability of the device and makes prototyping costly and time-consuming. A rewritable PIC architecture can circumvent these drawbacks, where PICs are repeatedly written and erased on a single PIC canvas. We demonstrate such a rewritable PIC platform by selective laser writing a layer of wide-band-gap phase change material (PCM) Sb2S3 with a low-cost benchtop setup. We show arbitrary patterning with resolution up to 300 nm and write dielectric assisted waveguides with a low optical loss of 0.0172 dB/µm. We envision that using this inexpensive benchtop platform thousands of PIC designs can be written, tested, and erased on the same chip without the need for lithography/etching tools or a nanofabrication facility, thus reducing manufacturing cost and increasing accessibility.

A Novel Strategy for Detecting Permittivity and Loss Tangent of Low-Loss Materials Based on Cylindrical Resonant Cavity.

Accurate measurement of the permittivity and loss tangent of low-loss materials is essential due to their special applications in the field of ultra large scale integrated circuits and microwave devices. In this study, we developed a novel strategy that can accurately detect the permittivity and loss tangent of low-loss materials based on a cylindrical resonant cavity supporting the TE111 mode in X band (8-12 GHz). Based on an electromagnetic field simulation calculation of the cylindrical resonator, permittivity is precisely retrieved by exploring and analyzing the perturbation of the coupling hole and sample size on the cutoff wavenumber. A more precise approach to measuring the loss tangent of samples with various thicknesses has been proposed. The test results of the standard samples verify that this method can accurately measure the dielectric properties of samples that have smaller sizes than the high Q cylindrical cavity method.

Insertion Loss and Phase Compensation Using a Circular Slot Via-Hole in a Compact 5G Millimeter Wave (mmWave) Butler Matrix at 28 GHz.

Fifth generation (5G) technology aims to provide high peak data rates, increased bandwidth, and supports a 1 millisecond roundtrip latency at millimeter wave (mmWave). However, higher frequency bands in mmWave comes with challenges including poor propagation characteristics and lossy structure. The beamforming Butler matrix (BM) is an alternative design intended to overcome these limitations by controlling the phase and amplitude of the signal, which reduces the path loss and penetration losses. At the mmWave, the wavelength becomes smaller, and the BM planar structure is intricate and faces issues of insertion losses and size due to the complexity. To address these issues, a dual-layer substrate is connected through the via, and the hybrids are arranged side by side. The dual-layer structure circumvents the crossover elements, while the strip line, hybrids, and via-hole are carefully designed on each BM element. The internal design of BM features a compact size and low-profile structure, with dimensions of 23.26 mm × 28.92 mm (2.17 λ0 × 2.69 λ0), which is ideally suited for the 5G mmWave communication system. The designed BM measured results show return losses, Sii and Sjj, of less than -10 dB, transmission amplitude of -8 ± 2 dB, and an acceptable range of output phase at 28 GHz.

Microstrip-Fed 3D-Printed H-Sectorial Horn Phased Array.

A 3D-printed phased array consisting of four H-Sectorial horn antennas of 200 g weight with an ultra-wideband rectangular-waveguide-to-microstrip-line transition operating over the whole LMDS and K bands (24.25-29.5 GHz) is presented. The transition is based on exciting three overlapped transversal patches that radiate into the waveguide. The transition provides very low insertion losses, ranging from 0.30 dB to 0.67 dB over the whole band of operation (23.5-30.4 GHz). The measured fractional bandwidth of the phased array including the transition was 20.8% (24.75-30.3 GHz). The antenna was measured for six different scanning angles corresponding to six different progressive phases α, ranging from 0° to 140° at the central frequency band of operation of 26.5 GHz. The maximum gain was found in the broadside direction α = 0°, with 15.2 dB and efficiency η = 78.5%, while the minimum was found for α = 140°, with 13.7 dB and η = 91.2%.

Analysis of Microstrip Line with Asymmetric Arch Type Cross-Sectional Structure Using Micro Pattern Transfer Printing Method.

This paper presents the manufacturing procedure and electrical properties of a microstrip line on flexible printed circuit boards (FPCBs) fabricated using the micro pattern transfer printing (MPTP) method for millimeter wave band application. The MPTP method presented herein is compared to the conventional FPCB process based on the degree of insertion loss as it pertains to the cross-sectional shape of the formed microstrip line. Electromagnetic field simulations were performed to confirm that the cross-sectional arch shape fabricated by the MPTP process reduces insertion loss in the high-frequency band. Based on the simulation, the microstrip transmission line was optimized to a width of 217 µm and a length of 30 cm, fabricated on a 50 µm thick poly-cyclohexylene dimethylene terephthalate (PCT) substrate to measure the insertion loss. The insertion loss fabricated using the MPTP method is measured as 0.37 dB/cm at 10 GHz, while the conventional FPCB is measured as 0.66 dB/cm. Through the analysis, it was confirmed that the FPCBs manufactured by the MPTP process show lower insertion loss compared to the conventional FPCBs.

ZnO-AuxCu1-x Alloy and ZnO-AuxAl1-x Alloy Vertically Aligned Nanocomposites for Low-Loss Plasmonic Metamaterials.

Hyperbolic metamaterials are a class of materials exhibiting anisotropic dielectric function owing to the morphology of the nanostructures. In these structures, one direction behaves as a metal, and the orthogonal direction behaves as a dielectric material. Applications include subdiffraction imaging and hyperlenses. However, key limiting factors include energy losses of noble metals and challenging fabrication methods. In this work, self-assembled plasmonic metamaterials consisting of anisotropic nanoalloy pillars embedded into the ZnO matrix are developed using a seed-layer approach. Alloys of AuxAl1-x or AuxCu1-x are explored due to their lower losses and higher stability. Optical and microstructural properties were explored. The ZnO-AuxCu1-x system demonstrated excellent epitaxial quality and optical properties compared with the ZnO-AuxAl1-x system. Both nanocomposite systems demonstrate plasmonic resonance, hyperbolic dispersion, low losses, and epsilon-near-zero permittivity, making them promising candidates towards direct photonic integration.

Elemental mapping of labelled biological specimens at intermediate energy loss in an energy-filtered TEM acquired using a direct detection device.

The technique of colour EM that was recently developed enabled localisation of specific macromolecules/proteins of interest by the targeted deposition of diaminobenzidine (DAB) conjugated to lanthanide chelates. By acquiring lanthanide elemental maps by energy-filtered transmission electron microscopy (EFTEM) and overlaying them in pseudo-colour over the conventional greyscale TEM image, a colour EM image is generated. This provides a powerful tool for visualising subcellular component/s, by the ability to clearly distinguish them from the general staining of the endogenous cellular material. Previously, the lanthanide elemental maps were acquired at the high-loss M4,5 edge (excitation of 3d electrons), where the characteristic signal is extremely low and required considerably long exposures. In this paper, we explore the possibility of acquiring the elemental maps of lanthanides at their N4,5 edge (excitation of 4d electrons), which occurring at a much lower energy-loss regime, thereby contains significantly greater total characteristic signal owing to the higher inelastic scattering cross-sections at the N4,5 edge. Acquiring EFTEM lanthanide elemental maps at the N4,5 edge instead of the M4,5 edge, provides ∼4× increase in signal-to-noise and ∼2× increase in resolution. However, the interpretation of the lanthanide maps acquired at the N4,5 edge by the traditional 3-window method, is complicated due to the broad shape of the edge profile and the lower signal-above-background ratio. Most of these problems can be circumvented by the acquisition of elemental maps with the more sophisticated technique of EFTEM Spectrum Imaging (EFTEM SI). Here, we also report the chemical synthesis of novel second-generation DAB lanthanide metal chelate conjugates that contain 2 lanthanide ions per DAB molecule in comparison with 0.5 lanthanide ion per DAB in the first generation. Thereby, fourfold more Ln3+ per oxidised DAB would be deposited providing significant amplification of signal. This paper applies the colour EM technique at the intermediate-loss energy-loss regime to three different cellular targets, namely using mitochondrial matrix-directed APEX2, histone H2B-Nucleosome and EdU-DNA. All the examples shown in the paper are single colour EM images only.

Numerical Modelling of a Distributed Acoustic Sensor Based on Ultra-Low Loss-Enhanced Backscattering Fibers.

In this study, a distributed acoustic sensor (DAS) was numerically modeled based on the non-ideal optical components with their noises and imperfections. This model is used to compare the response of DAS systems to standard single-mode fibers and ultra-low loss-enhanced backscattering (ULEB) fibers, a fiber with an array of high reflective points equally spaced along its length. It is shown that using ULEB fibers with highly reflective points improves the signal-to-noise ratio and linearity of the measurement, compared with the measurement based on standard single-mode fibers.

A Study of the Effect of Sintering Conditions of Mg0.95Ni0.05Ti3 on Its Physical and Dielectric Properties.

Mg0.95Ni0.05TiO3 ceramics were prepared by traditional solid-state route using sintering temperatures between 1300 and 1425 °C and holding time of 2-8 h. The sintered samples were characterized for their phase composition, micro-crystalline structure, unit-cell constant, and dielectric properties. A two-phase combination region was identified over the entire compositional range. The effect of sintering conditions was analyzed for various properties. Both permittivity (εr) and Q factor (Qf) were sensitive to sintering temperatures and holding times, and the optimum performance was found at 1350 °C withholding time of 4 h. The temperature coefficient of resonant frequency (τf) in a range from -45.2 to -52 (ppm/°C) and unit-cell constant were not sensitive to both the sintering temperature and holding time. An optimized Q factor of 192,000 (GHz) related with a permittivity (εr) of 17.35 and a temperature coefficient (τf) of -47 (ppm/°C) was realized for the specimen sintered at 1350 °C withholding time of 4 h. For applications of 5G communication device (filter, antennas, etc.), Mg0.95Ni0.05TiO3 is considered to be a suitable candidate for substrate materials.

Low-Loss and Tunable Localized Mid-Infrared Plasmons in Nanocrystals of Highly Degenerate InN.

Plasmonic response of free charges confined in nanostructures of plasmonic materials is a powerful means for manipulating the light-material interaction at the nanoscale and hence has influence on various relevant technologies. In particular, plasmonic materials responsive in the mid-infrared range are technologically important as the mid-infrared is home to the vibrational resonance of molecules and also thermal radiation of hot objects. However, the development of the field is practically challenged with the lack of low-loss materials supporting high quality plasmons in this range of the spectrum. Here, we demonstrate that degenerately doped InN nanocrystals (NCs) support tunable and low-loss plasmon resonance spanning the entire midwave infrared range. Modulating free-carrier concentration is achieved by engineering nitrogen-vacancy defects (InN1- x, 0.017 < x < 0.085) in highly degenerate NCs using a nonequilibrium gas-phase growth process. Despite the significant reduction in the carrier mobility relative to intrinsic InN, the mobility in degenerate InN NCs (>60 cm2/(V s)) remains considerably higher than the carrier mobility reported for other materials NCs such as doped metal oxides, chalcogenides, and noble metals. These findings demonstrate feasibility of controlled tuning of infrared plasmon resonances in a low-loss material of III-V compounds and open a gateway to further studies of these materials nanostructures for infrared plasmonic applications.

Comparison of Electron Imaging Modes for Dimensional Measurements in the Scanning Electron Microscope.

Dimensional measurements from secondary electron (SE) images were compared with those from backscattered electron (BSE) and low-loss electron (LLE) images. With the commonly used 50% threshold criterion, the lines consistently appeared larger in the SE images. As the images were acquired simultaneously by an instrument with the capability to operate detectors for both signals at the same time, the differences cannot be explained by the assumption that contamination or drift between images affected the SE, BSE, or LLE images differently. Simulations with JMONSEL, an electron microscope simulator, indicate that the nanometer-scale differences observed on this sample can be explained by the different convolution effects of a beam with finite size on signals with different symmetry (the SE signal's characteristic peak versus the BSE or LLE signal's characteristic step). This effect is too small to explain the >100 nm discrepancies that were observed in earlier work on different samples. Additional modeling indicates that those discrepancies can be explained by the much larger sidewall angles of the earlier samples, coupled with the different response of SE versus BSE/LLE profiles to such wall angles.

A Complete Overhaul of the Electron Energy-Loss Spectroscopy and X-Ray Absorption Spectroscopy Database: eelsdb.eu.

The electron energy-loss spectroscopy (EELS) and X-ray absorption spectroscopy (XAS) database has been completely rewritten, with an improved design, user interface, and a number of new tools. The database is accessible at https://eelsdb.eu/ and can now be used without registration. The submission process has been streamlined to encourage spectrum submissions and the new design gives greater emphasis on contributors' original work by highlighting their papers. With numerous new filters and a powerful search function, it is now simple to explore the database of several hundred EELS and XAS spectra. Interactive plots allow spectra to be overlaid, facilitating online comparison. An application-programming interface has been created, allowing external tools and software to easily access the information held within the database. In addition to the database itself, users can post and manage job adverts and read the latest news and events regarding the EELS and XAS communities. In accordance with the ongoing drive toward open access data increasingly demanded by funding bodies, the database will facilitate open access data sharing of EELS and XAS spectra.

Effect of Ca-Al-Si-O common glass on dielectric properties of low-temperature co-fired ceramic materials with different fillers.

High-density integration in single component used for mobile communication is highly demanded with the miniaturization trend in multi-functional light-weighted mobile communication devices. Embedding passive components into multi-layered ceramic chips is also increasingly needed for high integrity. The need for high strength materials to be used in handheld devices has also increased. To this end, many attempts to join different low-temperature co-fired ceramics (LTCC) materials with different dielectric constants have been made, but failed with de-laminations or internal cracks mainly due to difference of thermal expansion coefficients. It is thought that this difference could be minimized with the use of common glass in different LTCC materials. In this study, several candidates of common glass were mixed with various fillers of LTCC to have various dielectric constants in the radio-frequency, and to minimize the mismatch in joining. Ca-Al-Si-O glass was mixed with 1.3MgO-TiO2, cordierite and CaTiO3. Mixtures were tape-cast and sintered to be compared with their micro-structures, dielectric properties and thermo-mechanical characteristics. When 1.3MgO-TiO2 with volumetric ratio of 30% was mixed with Ca-Al-Si-O glass, the measured dielectric constant was 7.9, the quality factor was 3708. With 45 volumetric percent of cordierite, the dielectric constant was 5 and the quality factor was 1052.

Self-Assembled MXene@Fluorographene Hybrid for High Dielectric Constant and Low Loss Ferroelectric Polymer Composite Films.

Modern electrical applications urgently need flexible polymer films with a high dielectric constant (εr) and low loss. Recently, the MXene-filled percolative composite has emerged as a potential material choice because of the promised high εr. Nevertheless, the typically accompanied high dielectric loss hinders its applications. Herein, a facile and effective surface modification strategy of cladding Ti3C2Tx MXene (T = F or O; FMX) with fluorographene (FG) via self-assembly is proposed. The obtained FMX@FG hybrid yields high εr (up to 108 @1 kHz) and low loss (loss tangent tan δ = 1.16 @ 1 kHz) in a ferroelectric polymer composite at a low loading level (the equivalent of 1.5 wt % FMX), which is superior to its counterparts in our work (e.g., FMX: εr = 104, tan δ = 10.71) and other studies. It is found that the FG layer outside FMX plays a critical role in both the high dielectric constant and low loss from experimental characterizations and finite element simulations. For one thing, FG with a high F/C ratio would induce a favorable structure of high ß-phase crystallinity, extensive microcapacitor networks, and abundant interfacial dipoles in polymer composites that account for the high εr. For another, FG, as a highly insulating layer, can inhibit the formation of conductive networks and inter-FMX electron tunneling, which is responsible for conduction loss. The results demonstrate the potential of a self-assembled FMX@FG hybrid for high εr and low loss polymer composite films and offer a new strategy for designing advanced polymer composite dielectrics.

Two CMOS Wilkinson Power Dividers Using High Slow-Wave and Low-Loss Transmission Lines.

This work presents two Wilkinson power dividers (WPDs) using multi-layer pseudo coplanar waveguide (PCPW) structures. The PCPW-based WPDs were designed, implemented, and verified in a standard 180 nm CMOS process. The proposed PCPW features high slow-wave and low-loss performances compared to other common transmission lines. The two WPDs are based on the same PCPW structure parameters in terms of line width, spacing, and used metal layers. One WPD was realized in a straight PCPW-based layout, and the other WPD was realized in a meandered PCPW-based layout. Both the two WPDs worked up to V-band frequencies, as expected, which also demonstrates that the PCPW guiding structure is less susceptible to the effects of meanderings on the propagation constant and characteristic impedance. The meandered design shows that the measured insertion losses were about 5.1 dB, and its return losses were better than 17.5 dB at 60 GHz. In addition, its isolation, amplitude imbalance, and phase imbalance were 18.5 dB, 0.03 dB, and 0.4°, respectively. The core area was merely 0.2 mm × 0.23 mm, or 1.8 × 10-3λo2.

All-Organic PTFE Coated PVDF Composite Film Exhibiting Low Conduction Loss and High Breakdown Strength for Energy Storage Applications.

Plastic film capacitors are widely used in pulse and energy storage applications because of their high breakdown strength, high power density, long lifetime, and excellent self-healing properties. Nowadays, the energy storage density of commercial biaxially oriented polypropylene (BOPP) is limited by its low dielectric constant (~2.2). Poly(vinylidene fluoride) (PVDF) exhibits a relatively high dielectric constant and breakdown strength, making it a candidate material for electrostatic capacitors. However, PVDF presents significant losses, generating a lot of waste heat. In this paper, under the guidance of the leakage mechanism, a high-insulation polytetrafluoroethylene (PTFE) coating is sprayed on the surface of a PVDF film. The potential barrier at the electrode-dielectric interface is raised by simply spraying PTFE and reducing the leakage current, and then the energy storage density is increased. After introducing the PTFE insulation coating, the high-field leakage current in the PVDF film shows an order of magnitude reduction. Moreover, the composite film presents a 30.8% improvement in breakdown strength, and a 70% enhancement in energy storage density is simultaneously achieved. The all-organic structure design provides a new idea for the application of PVDF in electrostatic capacitors.

Low-Loss Dielectric Ink for Printed Radio Frequency and Microwave Devices.

Direct write printing is restricted by the lack of dielectric materials that can be printed with high resolution and offer dissipation factors at radio frequency (RF) within the range of commercial RF laminates. Herein, we outline the development of dielectric materials with dielectric loss below 0.006 in X and Ku frequency bands (8.2-18 GHz), the range required for radio frequency and microwave applications. The described materials were designed for printability and processability, specifically a prolonged viscosity below 1000 cps and a robust cure procedure, which requires minimal heat treatment. In the first stage of this work, nonpolar ring-opening metathesis polymerization (ROMP) is demonstrated at room temperature in an open-air environment with a low-viscosity monomer, 5-vinyl-2-norbornene, using the second-generation Grubbs catalyst (G-II). Differential scanning calorimetry (DSC) was used to study how the catalyst activity is increased with heating at various stages in the reaction, which is then used as a strategy to cure the material after printing. The resulting cured poly(5-vinyl-2-norbornene) material is then characterized for dielectric and mechanical performance before and after a secondary heat treatment, which mimics processing procedures to incorporate subsequent printed conductor layers for multilayer applications. After the secondary heat treatment, the material exhibits a 55.0% reduction in the coefficient of thermal expansion (CTE), an increase in glass-transition temperature (Tg) from 32.4 to 46.1 °C, and an increased 25 °C storage modulus from 428 to 1031 MPa while demonstrating a minimal change in dielectric loss. Lastly, samples of the developed dielectric material are printed with silver overtop to demonstrate how the material can be effectively incorporated into fully printed, multilayer RF applications.

Low-Loss Dual-Band Transparency Metamaterial with Toroidal Dipole.

In this paper, a low-loss toroidal dipole metamaterial composed of four metal split ring resonators is proposed and verified at microwave range. Dual-band Fano resonances could be excited by normal incident electromagnetic waves at 6 GHz and 7.23 GHz. Analysis of the current distribution at the resonance frequency and the scattered power of multipoles shows that both Fano resonances derive from the predominant novel toroidal dipole. The simulation results exhibit that the sensitivity to refractive index of the analyte is 1.56 GHz/RIU and 1.8 GHz/RIU. Meanwhile, the group delay at two Fano peaks can reach to 11.38 ns and 12.85 ns, which means the presented toroidal metamaterial has significant slow light effects. The proposed dual-band toroidal dipole metamaterial may offer a new path for designing ultra-sensitive sensors, filters, modulators, slow light devices, and so on.

On-Chip Reconfigurable Focusing through Low-Loss Phase Change Materials Based Metasurfaces.

Metasurfaces are useful subwavelength structures that can be engineered to achieve useful functionality. While most metasurfaces are passive devices, Phase Change Materials can be utilized to make active metasurfaces that can have numerous applications. One such application is on-chip beam steering which is of vital utility for numerous applications that can potentially lead to analog computations and non-Von Neumann computational architectures. This paper presents through numerical simulations, a novel metasurface that can realize beam steering through active phase switching of in-planted arrays of phase change material, Sb2S3. For the purpose of numerical demonstration of the principle, beam focusing has been realized, on-chip, through active switching of the Sb2S3 unit cell between the amorphous and crystalline phases. The presented architecture can realize on-chip transformation optics, mathematical operations, and information processing, thus opening the gates for future technologies.

Design of Power/Ground Noise Suppression Structures Based on a Dispersion Analysis for Packages and Interposers with Low-Loss Substrates.

In this study, power/ground noise suppression structures were designed based on a proposed dispersion analysis for packages and interposers with low-loss substrates. Low-loss substrates are suitable for maintaining signal integrity (SI) of high-speed channels operating at high data rates. However, when the power/ground noise is generated in the power delivery network (PDN), low-loss substrates cannot suppress the power/ground noise, thereby causing PDN-induced crosstalk and various power integrity (PI) issues. To solve these issues, noise suppression structures generating electromagnetic bandgap were proposed and designed. The mechanism of the proposed structures was examined based on a proposed dispersion analysis. The proposed structures were designed and fabricated in glass interposer test vehicles, and the effectiveness of the structures on power/ground noise suppression was experimentally validated by measuring the noise suppression band. The proposed dispersion analysis was also verified by comparing the derived noise stopband edges (fL and fU) with electromagnetic (EM) simulation and experimental results, and they all showed good agreement. Compared to EM simulation, the proposed method required smaller computational resources but showed good accuracy. Using the proposed dispersion analysis, various power/ground noise suppression bands were designed considering the applications and design rules of packages and interposers. With measurements and EM/circuit simulations, the effectiveness of the designed structure in maintaining SI/PI was verified. By adopting the designed structures, the noise transfer properties in the PDN were suppressed in the target suppression frequency band, which is key for PI design. Finally, it was verified that the proposed structures were capable of suppressing power/ground noise propagation in the PDN by analyzing PDN-induced crosstalk in the high-speed channel.