Micro-mechanisms of failure in nano-structured maraging steels characterised throughin situmechanical tests.

High-pressure-torsion (HPT) processing introduces a large density of dislocations that form sub-grain boundaries within the refined nano-scale structure, leading to changes in precipitate morphology compared to hot-rolled maraging steels. The impact of such nanostructuring on the deformation and fracture micro-mechanisms is being reported for the first time usingin situcharacterization techniques along with transmission electron microscopy and atom probe tomography analysis, in this study. Digital image correlation has been used to quantify the full field strain maps in regions of severe strain localization as well as to determine the fracture toughness through critical crack tip opening displacements. It is seen that the phenomenon of planar slip leads to strain softening under uniaxial deformation and to crack branching under a triaxial stress state in hot rolled maraging steels. On the other hand, nano-structuring after HPT processing creates a large number of high angle grain boundaries as dislocation barriers, leading to strain hardening under uniaxial tension and nearly straight crack path with catastrophic fracture under triaxial stress state. Upon overaging, the hot-rolled sample shows signature of transformation induced plasticity under uniaxial tension, which is absent in the HPT processed overaged samples, owing to the finer reverted austenite grains containing higher Ni concentration in the latter. In the overaged fracture test samples of both the hot-rolled and HPT conditions, crack tips show a signature of strain induced transformation of the reverted austenite to martensite, due to the accompanying severe strain gradients. This leads to a higher fracture toughness even while achieving high strengths in the overaged conditions of the nanocrystalline HPT overaged samples. The results presented here will aid in design of suitable heat treatment or microstructure engineering of interface dominated nano-scale maraging steels with improved damage tolerance.

Alkalinity Regulation and Optimization of Cementitious Materials Used in Ecological Porous Concrete.

Ecological porous concrete (EPC) is one of the novel formulations of concrete with unique phytogenic properties. However, achieving both low alkalinity and high strength in EPC proves challenging due to the inherently high alkalinity of the pore environment, which hinders the growth of the plant and affects its ecological benefits significantly. This research investigated the utilization of 15 types of chemical admixtures and diatomaceous earth as alkali-reducing agents to optimize the properties of silicate cementitious materials for the applications of EPC. To identify the most effective agents, the pH value and compressive strength of the cement paste were adopted as the screening criteria for the selection of the essential alkali-reducing ingredients. Subsequently, a composite approach combining chemical admixtures and DE was employed to explore the synergistic effects on the pH and strength of silicate cementitious materials. The results revealed that a combination of 8% DE, 5% oxalic acid, and 5% iron sulfate functioned effectively and resulted in desirable performance for the concrete. This synergistic blend effectively consumed a large amount of Ca(OH)2, reducing the pH of cement paste to 10.48 within 3 days. Furthermore, the hydration reaction generated C-S-H with a low Ca/Si ratio, leading to a remarkable increase in the compressive strength of the concrete, reaching 89.7 MPa after 56 days. This composite approach ensured both low alkalinity and high strength in silicate cementitious materials, providing a theoretical basis for the application and promotion of EPC in the ecological field.

Properties of Cemented Filling Materials Prepared from Phosphogypsum-Steel Slag-Blast-Furnace Slag and Its Environmental Effect.

Phosphogypsum (PG) occupies a large amount of land due to its large annual production and low utilization rate, and at the same time causes serious environmental problems due to toxic impurities. PG is used for mine backfill, and industrial solid waste is a curing agent for PG, which can save the filling cost and reduce environmental pollution. In this paper, PG was used as a raw material, combined with steel slag (SS) and ground granulated blast-furnace slag (GGBS) under the action of an alkali-activated agent (NaOH) to prepare all-solid waste phosphogypsum-based backfill material (PBM). The effect of the GGBS to SS ratio on the compressive strength and toxic leaching of PBM was investigated. The chemical composition of the raw materials was obtained by XRF analysis, and the mineral composition and morphology of PBM and its stabilization/curing mechanism against heavy metals were analyzed using XRD and SEM-EDS. The results showed that the best performance of PBM was achieved when the contents of PG, GGBS, and SS were 80%, 13%, and 7%, the liquid-to-solid ratio was 0.4, and the mass concentration of NaOH was 4%, with a strength of 2.8 MPa at 28 days. The leaching concentration of fluorine at 7 days met the standard of groundwater class IV (2 mg/L), and the leaching concentration of phosphorus was detected to be less than 0.001 mg/L, and the leaching concentration of heavy metals met the environmental standard at 14 d. The hydration concentration in PBM met the environmental standard. The hydration products in PBM are mainly ettringite and C-(A)-S-H gel, which can effectively stabilize the heavy metals in PG through chemical precipitation, physical adsorption, and encapsulation.

Application of Biological Glue-Clay Composite Substrate in Slope Ecological Restoration.

Given the issues of soil cracking, poor water retention during drought, and erosion damage caused by rainfall, we conducted an in-depth study on the water retention properties, cracking resistance, and scouring resistance of biogel-amended clay using evaporation cracking and scouring tests. The hydrophysical properties and cohesive aggregation mechanism of biogel-amended clay were explored, and the results showed that the incorporation of biogel improved the water retention, cracking resistance, and scour resistance of the clay samples. With an increase in the biogel content, the biogel mucous membrane inside the samples improved the cohesion between soil particles, reduced the generation and development of cracks, and improved the cracking resistance. There was no significant cracking of the samples after the biogel content reached 0.3%, which changed the migration of water in the sample, prevented water evaporation, and improved the water retention of the clay samples. Biofilm can change the migration of water in the sample, prevent some evaporation, and reduce the evaporation rate. To a certain extent, it can enhance the water retention capacity of the sample. Enhanced biofilm content significantly reduced scouring in the process of rainfall and runoff erosion of the sample, and biofilm content of 0.2% significantly reduced the surface of the specimen damaged by erosion. The hydrophysical properties of the composite-adhesive-amended clay samples were significantly improved compared with those of the single-bioadhesive-amended clay samples.

Remediation of surface water contaminated by pathogenic microorganisms using calcium peroxide: Matrix effect, micro-mechanisms and morphological-physiological changes.

Calcium peroxide (CaO2), a common solid peroxide, has been increasingly used in contaminated site remediation due to its ability to release oxygen (O2) and hydrogen peroxide (H2O2) and its environmental friendliness. Our present study is first to explore micromechnisms of CaO2 to efficaciously inactivate pathogen indicators including gram-negative bacterium of Escherichia coli (E. coli), gram-positive bacterium of Staphylococcus aureus (S. aureus), and virus of Escherichia coli-specific M13 bacteriophage (VCSM13) under low concentration (≤ 4 mmol L-1 (mM)). The inactivation mechanisms of E. coli, S. aureus (1 mmol L-1 CaO2) and VCSM13 (4 mmol L-1) were mainly attributed to OH- (32∼58%) and •OH (34∼42%), followed by H2O2 (13∼20%) and O2•- (10∼12%) generated from CaO2, with the observed morphological and physiological-associated damages. Also, average steady-state concentrations of (OH-, •OH, H2O2, and O2•-) and their reaction rate constants with E. coli and VCSM13 were determined. Accordingly, the micro-mechanism model of inactivation was established and validated, and the inactivation efficiency of the same order of magnitude of pathogen was predicted. Furthermore, during the common environmental factors, the copper ions was found to be promote CaO2 inactivation of pathogens, and dissolved organic matter (DOM) fractions had a negative effect on CaO2 inactivation. The present study explored the mechanisms of CaO2 inactivation of pathogens in real surface water, laying the foundation for its potential use in the inactivation of water-borne microbial pathogens.

Analysis of Notch Effect in 3D-Printed ABS Fracture Specimens Containing U-Notches.

In this paper a fracture assessment in additive manufactured acrylonitrile butadiene styrene (ABS) fracture specimens containing U-notches is performed. We performed 33 fracture tests and 9 tensile tests, combining five different notch radii (0 mm, 0.25 mm, 0.50 mm, 1 mm and 2 mm) and three different raster orientations: 0/90, 30/-60 and 45/-45. The theory of critical distances (TCD) was then used in the analysis of fracture test results, obtaining additional validation of this theoretical framework. Different versions of TCD provided suitable results contrasting with the experimental tests performed. Moreover, the fracture mechanisms were evaluated using scanning electron microscopy in order to establish relationships with the behaviour observed. It was demonstrated that 3D-printed ABS material presents a clear notch effect, and also that the TCD, through both the point method and the line method, captured the physics of the notch effect in 3D-printed ABS. Finally, it was observed that the change in the fracture mechanisms when introducing a finite notch radius was limited to a narrow band behind the original defect, which appeared in cracked specimens but not in notched specimens.

A biomimetic study of natural attachment mechanisms: imaging cellulose and chitin part 2.

To create a model of a biomimetic product from the A. minus hook after a biomimetic methodology has been applied, this paper describes an investigation into the most appropriate method of shape acquisition for the purposes of reproduction and product development towards manufacture. This morphological study investigates confocal microscopy, SEM and other microscopy techniques. Confocal microscopy was selected as being most appropriate and small structures of cellulose and insect cuticle imaged. The benefits and disadvantages of this approach are noted. This paper is the result of research into microscopy techniques coupled with state-of-the-art manufacturing techniques. The result is this experiment with a single-phase confocal microscope to capture their 3-D images, both of cellulose and of chitin, without any specimen-specific treatment. Emphasis must be placed upon the cleanliness of the process since so many Natural attachment mechanisms are of this order of size and confocal microscopy offers opportunities for physical examination of microstructures and their interaction, in situ, with non-destructive inspection. This methodology has to develop further for the source of Nature's designs to be rifled for ideas.