Towards a metadata scheme for the description of materials - the description of microstructures.

The property of any material is essentially determined by its microstructure. Numerical models are increasingly the focus of modern engineering as helpful tools for tailoring and optimization of custom-designed microstructures by suitable processing and alloy design. A huge variety of software tools is available to predict various microstructural aspects for different materials. In the general frame of an integrated computational materials engineering (ICME) approach, these microstructure models provide the link between models operating at the atomistic or electronic scales, and models operating on the macroscopic scale of the component and its processing. In view of an improved interoperability of all these different tools it is highly desirable to establish a standardized nomenclature and methodology for the exchange of microstructure data. The scope of this article is to provide a comprehensive system of metadata descriptors for the description of a 3D microstructure. The presented descriptors are limited to a mere geometric description of a static microstructure and have to be complemented by further descriptors, e.g. for properties, numerical representations, kinetic data, and others in the future. Further attributes to each descriptor, e.g. on data origin, data uncertainty, and data validity range are being defined in ongoing work. The proposed descriptors are intended to be independent of any specific numerical representation. The descriptors defined in this article may serve as a first basis for standardization and will simplify the data exchange between different numerical models, as well as promote the integration of experimental data into numerical models of microstructures. An HDF5 template data file for a simple, three phase Al-Cu microstructure being based on the defined descriptors complements this article.

Digital Multiphase Composites via Additive Manufacturing.

Mechanical properties of traditional engineering materials are typically coupled to each other, presenting a challenge to practitioners with multi-dimensional material property requirements. In this work, continuous, independent control over multiple mechanical properties is demonstrated in composite materials realized using additive manufacturing. For the first time, composites additively manufactured from rigid plastic, soft elastomer, and liquid constituents are experimentally characterized, demonstrating materials which span four orders of magnitude in modulus and two orders of magnitude in toughness. By forming analytical mappings between relative concentrations of constituents at the microscale and resulting macroscale material properties, inverse material design is enabled; the method is showcased by printing artifacts with prescribed toughness and elasticity distributions. The properties of these composites are placed in the context of biological tissues, showing they have promise as mechanically plausible tissue mimics.

Segmentability evaluation of back-scattered SEM images of multiphase materials.

Segmentation methods are very useful tools in the Electron Microscopy inspection of materials, enabling the extraction of quantitative results from microscopy images. Back-Scattered Electron (BSE) images carry information of the mean atomic number in the interaction volume and hence can be used to quantify the phase composition in multiphase materials. Since phase composition and proportion affects the material properties and hence its applications, the segmentation accuracy of such images rendered of critical importance for material science. In this work, the notion of segmentability for BSE images is proposed to define the ability of an image to be segmented accurately. This notion can be used to guide the image acquisition process so that segmentability is maximized and segmentation accuracy is ensured. An index is devised to quantify segmentability based on a combination of the modified Fisher Discrimination Ratio and of the second Minkowski functional capturing intensity and spatial aspects of BSE images respectively. The suggested Segmentability Index (SI) is validated in synthetic BSE images which are generated with a novel algorithm allowing the independent control of spatial distribution of phases and their grayscale intensity histograms. Additionally, SI is applied in real-synthetic BSE images, where the real greyscale distributions of Ordinary Portland Cement (OPC) clinker crystallographic phases are used, to demonstrate the ability of SI to indicate the optimum choice of critical image acquisition settings leading to the more accurate segmentation output.

Surface stress decomposition in large amplitude oscillatory interfacial dilatation of complex interfaces.

HYPOTHESIS: Multiphase materials are often subjected to large deformations during processing, but the rheological responses of complex interfaces (e.g. stabilized by proteins) in this nonlinear deformation regime are still poorly understood. We expect nonlinearities in the response to be introduce by changes of the interfacial network and surface density of the emulsifier. EXPERIMENTS: Large amplitude oscillatory dilatation (LAOD) experiments were performed on WPI-, pea albumin-, pea globulin- and rapeseed lecithin-stabilized interfaces and analyzed with a general stress decomposition (GSD). With GSD, the stress response was decomposed into the four stress terms (τ1-τ4). Here, τ1 and τ2 represent, the elastic and viscous contribution of the odd Fourier harmonics, and τ3 and τ4 represent the dissipative and recoverable contribution of the even harmonics. FINDINGS: Analysis of WPI-, pea albumin-, pea globulin- and rapeseed lecithin-stabilized interfaces revealed that higher odd harmonics (k≥3) describe in-plane network responses and that even harmonics describe surface density changes. Analysis of these complex interfaces showed that GSD is a valuable tool for (quantitative) description of interfacial responses in LAOD, providing new insights into the origin of asymmetric nonlinear stress responses.

Al-Al3Ni In Situ Composite Formation by Wire-Feed Electron-Beam Additive Manufacturing.

The regularities of microstructure formation in samples of multiphase composites obtained by additive electron beam manufacturing on the basis of aluminum alloy ER4043 and nickel superalloy Udimet-500 have been studied. The results of the structure study show that a multicomponent structure is formed in the samples with the presence of Cr23C6 carbides, solid solutions based on aluminum -Al or silicon -Si, eutectics along the boundaries of dendrites, intermetallic phases Al3Ni, AlNi3, Al75Co22Ni3, and Al5Co, as well as carbides of complex composition AlCCr, Al8SiC7, of a different morphology. The formation of a number of intermetallic phases present in local areas of the samples was also distinguished. A large amount of solid phases leads to the formation of a material with high hardness and low ductility. The fracture of composite specimens under tension and compression is brittle, without revealing the stage of plastic flow. Tensile strength values are significantly reduced from the initial 142-164 MPa to 55-123 MPa. In compression, the tensile strength values increase to 490-570 MPa and 905-1200 MPa with the introduction of 5% and 10% nickel superalloy, respectively. An increase in the hardness and compressive strength of the surface layers results in an increase in the wear resistance of the specimens and a decrease in the coefficient of friction.

Temperature-Dependent Phase Evolution in FePt-Based Nanocomposite Multiple-Phased Magnetic Alloys.

A quaternary Fe-Pt-Nb-B alloy has been fabricated by the melt spinning method with the purpose of the formation of crystallographically coherent multiple magnetic phases, emerging from the same metastable precursor, as well as to investigate the phase interactions and the influence of their coupling on magnetic performances. For this purpose, extended structural and magnetic investigations were undertaken by making use of X-ray diffraction, transmission electron microscopy, and 57Fe Mössbauer spectroscopy, as well as magnetic measurements using SQUID magnetometry. It was documented that intermediate metastable phases formed during primary crystallization, in intermediate stages of annealing, and a growth-dominated mode was encountered for the secondary crystallization stage upon annealing at 700 °C and 800 °C where fcc Fe3Pt and fct Fe2B polycrystalline were formed. The Mössbauer investigations have documented rigorously the hyperfine parameters of each of the observed phases. The fcc A1 FePt phase was shown to exhibit a peculiar ferromagnetic transition, and this transition has been proven to occur gradually between 300 K and 77 K. The magnetic measurements allowed us to identify the annealing at 700 °C as optimal for obtaining good magnetic features. Coercive field dependence shows similarities to the random anisotropy model for samples annealed at 500 °C to 700 °C which are nanocrystalline. These results show good perspectives for use in applications where different magnetic states are required at different operating temperatures.

Traceable measurement and imaging of the complex permittivity of a multiphase mineral specimen at micron scales using a microwave microscope.

This paper describes traceable measurements of the dielectric permittivity and loss tangent of a multiphase material (particulate rock set in epoxy) at micron scales using a resonant Near-Field Scanning Microwave Microscope (NSMM) at 1.2GHz. Calibration and extraction of the permittivity and loss tangent is via an image charge analysis which has been modified by the use of the complex frequency to make it applicable for high loss materials. The results presented are obtained using a spherical probe tip, 0.1mm in diameter, and also a conical probe tip with a rounded end 0.01mm in diameter, which allows imaging with higher resolution (≈10µm). The microscope is calibrated using approach-curve data over a restricted range of gaps (typically between 1% and 10% of tip diameter) as this is found to give the best measurement accuracy. For both tips the uncertainty of scanned measurements of permittivity is estimated to be±10% (at coverage factor k=2) for permittivity ⪝10. Loss tangent can be resolved to approximately 0.001. Subject to this limit, the uncertainty of loss tangent measurements is estimated to be±20% (at k=2). The reported measurements inform studies of how microwave energy interacts with multiphase materials containing microwave absorbent phases.