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1.
Sensors (Basel) ; 18(7)2018 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-29970804

RESUMO

A novel high performance optical fiber refractive index (RI) sensor based on the hybrid transverse magnetic (TM) mode of Tamm plasmon polariton (TPP) and surface plasmon polariton (SPP) is proposed. The structure of the sensor is a multi-mode optical fiber with a one dimensional photonic crystal (1 DPC)/metal multi-films outer coated on its fiber core. A simulation study of the proposed sensor is carried out with the geometrical optical model to investigate the performance of the designed sensor with respect to the center wavelength, bilayer period and the thickness of silver layer. Because the lights transmitted in the fiber sensor have much larger incident angles than those in the prism based sensors, the center wavelength of the 1 DPC should shift to longer wavelength. When the coupling between TM-TPP and SPP is stronger, the sensor exhibits better performance because the electromagnetic field of the TPP-SPP hybrid mode is enhanced more in the analyte. Compared to most conventional fiber surface plasmon resonance sensors, the figure of merit of the proposed sensor is much higher while the sensitivity is comparable. The idea of utilizing TPP-SPP hybrid mode for RI sensing in the solid-core optical fiber structure presented in this paper could contribute to the study of the fiber RI sensor based on TPP.

2.
J Synchrotron Radiat ; 24(Pt 2): 376-385, 2017 03 01.
Artigo em Inglês | MEDLINE | ID: mdl-28244430

RESUMO

The propagation within a one-dimensional photonic crystal of a single ultra-short and ultra-intense pulse delivered by an X-ray free-electron laser is analysed with the framework of the time-dependent coupled-wave theory in non-linear media. It is shown that the reflection and the transmission of an ultra-short pulse present a transient period conditioned by the extinction length and also the thickness of the structure for transmission. For ultra-intense pulses, non-linear effects are expected: they could give rise to numerous phenomena, bi-stability, self-induced transparency, gap solitons, switching, etc., which have been previously shown in the optical domain.

3.
Carbohydr Polym ; 327: 121646, 2024 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-38171671

RESUMO

Achieving excellent ultraviolet (UV) blocking properties and maintaining high light transmittance are highly challenging. In this study, a facile and green polymer-assisted vacuum filtration strategy was used to prepare cellulose nanocrystal (CNC) one-dimensional photonic crystal (1DPhC) films with excellent UV-blocking performance and good transparency. The polymer-assisted self-assembly behaviors of CNC and the hydrogen bonding interaction between CNC, polyethylene glycol (PEG), and graphene oxide (GO) drive the homogeneous distribution and parallel alignment of GO. The UV absorption of GO and high reflection of UV resulting from the chiral nematic structure of CNCs result in excellent UV-blocking and high visible light transmission. Besides, the strong hydrogen bonding interaction among CNC, PEG, and GO endows the films with obviously increased mechanical properties. The UV-blocking and the transparency of the CNC composite films could reach 98.3 % and 60.5 %, respectively. Besides, the strain at break of the composite film reached 1.72 ± 0.11 %, which was 535.94 % of neat CNC films. The CNC composite films present great potential in the field of UV-blocking glass, sensors, anti-counterfeiting measures, radiation protection, and so on.

4.
Materials (Basel) ; 17(3)2024 Jan 24.
Artigo em Inglês | MEDLINE | ID: mdl-38591376

RESUMO

We investigate the transmittance spectrum of a multichannel filter composed of dielectric (A) and plasma (P) materials in the microwave region within the transfer matrix formalism. Two configurations of the proposed filter are studied under the influence of an applied magnetic field: (1) a periodic structure containing (A/P)N unit cells surrounded by air and (2) the introduction of a second dielectric material (D) acting as a defect layer to produce an (AP)N/2/D/(AP)N/2 structure. Our findings reveal that in the periodic case, the number of resonant states of the transmittance increases with number N; however, the observed blue and red shifts depend on the intensity and orientation of the applied magnetic field. We present contour plots of the transmission coefficients that show the effect of the incident angle on the shifts of the photonic band gaps. Furthermore, we find that the introduction of a defect layer generates additional resonant states and merges the central resonant peak into a miniband of resonances. Moreover, we show that the number of resonant peaks and their locations can be modulated by increasing the unit cell number, N, as well as increasing the width of the inserted defect layer. Our proposed structures enable the design of novel photonic filters using magnetized plasma materials operating in the microwave region.

5.
ACS Appl Mater Interfaces ; 16(22): 29141-29152, 2024 Jun 05.
Artigo em Inglês | MEDLINE | ID: mdl-38773701

RESUMO

Poor interfacial quality and low refractive index contrast (Δn) are critical challenges for the development of high-performance one-dimensional photonic crystals (1DPhCs) via solution methods that impede their optical efficiency. Herein, we introduce an innovative approach by hybridizing hollow SiO2 with poly(vinyl alcohol), referred to as PHS, followed by alternate assembly with TiO2 via spin-coating, achieving a 1DPhC with Δn = 0.76 at the wavelength of 550 nm. This method circumvents the need for high-temperature treatment and complex curing conditions, resulting in a 1DPhC with superior interfacial and optical characteristics. By adjusting the thickness of the PHS layers, we can finely tune the reflectance spectrum, attaining over 99% reflectance at the photonic band gap. Furthermore, 1DPhC demonstrates excellent adhesion to polycarbonate substrates and retains its optimal optical performance even after rigorous environmental testing, including hygrothermal cycles, exposure to hot water, friction, and solvent sonication. This research paves the way for the facile fabrication of high-performance 1DPhCs under mild conditions, offering new perspectives for photonic material processing.

6.
Biosensors (Basel) ; 14(1)2024 Jan 14.
Artigo em Inglês | MEDLINE | ID: mdl-38248420

RESUMO

Photonic crystals (PCs) are promising tools for label-free sensing in drug discovery screening, diagnostics, and analysis of ligand-receptor interactions. Imaging of PC surface modes has emerged as a novel approach to the detection of multiple binding events at the sensor surface. PC surface modification and decoration with recognition units yield an interface providing the highly sensitive detection of cancer biomarkers, antibodies, and oligonucleotides. The RAD51 protein plays a central role in DNA repair via the homologous recombination pathway. This recombinase is essential for the genome stability and its overexpression is often correlated with aggressive cancer. RAD51 is therefore a potential target in the therapeutic strategy for cancer. Here, we report the designing of a PC-based array sensor for real-time monitoring of oligonucleotide-RAD51 recruitment by means of surface mode imaging and validation of the concept of this approach. Our data demonstrate that the designed biosensor ensures the highly sensitive multiplexed analysis of association-dissociation events and detection of the biomarker of DNA damage using a microfluidic PC array. The obtained results highlight the potential of the developed technique for testing the functionality of candidate drugs, discovering new molecular targets and drug entities. This paves the way to further adaption and bioanalytical use of the biosensor for high-content screening to identify new DNA repair inhibitor drugs targeting the RAD51 nucleoprotein filament or to discover new molecular targets.


Assuntos
Anticorpos , Neoplasias , Humanos , Diagnóstico por Imagem , Biomarcadores Tumorais , Reparo do DNA , DNA de Cadeia Simples , Oligonucleotídeos , Rad51 Recombinase
7.
Materials (Basel) ; 15(21)2022 Nov 04.
Artigo em Inglês | MEDLINE | ID: mdl-36363395

RESUMO

One-dimensional photonic crystal structures have been widely used to enhance fluorescence. However, its fluorescence enhancement is low-fold because of a weak excitation field region. In this paper, we used a genetic algorithm to assist in the design of two photonic crystals based on Al2O3 and TiO2 materials. One of them has a defect consisting of SiO2. The Fabry-Perot cavity (FP cavity) formed by the sandwiched photonic crystal achieves up to 14-fold enhancement of the excitation electric field. We modulate the electric field radiation distribution of the fluorescent material by using photonic forbidden bands. For a 3.18 µm thick layer of the fluorescent solution, the structure achieves up to 60-fold fluorescence enhancement. We also discussed that the reason for the different enhancement abilities in different places is the phase change caused by the optical path difference. This design is expected to have applications in display, imaging, etc.

8.
Nanomaterials (Basel) ; 12(1)2021 Dec 28.
Artigo em Inglês | MEDLINE | ID: mdl-35010022

RESUMO

In this work the features of the resonance in a rectangular dielectric surface-relief gratings, illuminated with a limited cross-section Gaussian beam, have been studied. The rigorous coupled wave method and beam decomposition into the plane waves by the Fourier transform have been used. It is shown that there is a resonant wavelength for each thickness of the dielectric grating. The value of resonant wavelength depends on the beam angle of incidence on the gratings. Moreover, the two types of resonances can occur in the grating at certain grating parameters. The power reflection coefficient is practically equal to unity for the first type of resonance and is much smaller than unity, for the second one. The obtained results extend the knowledge regarding the nature of the waveguide resonance in the dielectric grating, considering the limited cross section beam, and they can increase its use in many applications.

9.
ACS Appl Mater Interfaces ; 9(17): 14817-14826, 2017 May 03.
Artigo em Inglês | MEDLINE | ID: mdl-28406026

RESUMO

There are four prerequisites when applying all types of thin-film solar cells to power-generating window photovoltaics (PVs): high power-generation efficiency, longevity and high durability, semitransparency or partial-light transmittance, and colorful and aesthetic value. Solid-type thin-film Cu(In,Ga)S2 (CIGS) or Cu(In,Ga)(S,Se)2 (CIGSSe) PVs nearly meet the first two criteria, making them promising candidates for power-generating window applications if they can transmit light to some degree and generate color with good aesthetic value. In this study, the mechanical scribing process removes 10% of the window CIGSSe thin-film solar cell with vacant line patterns to provide a partial-light-transmitting CIGSSe PV module to meet the third requirement. The last concept of creating distinct colors could be met by the addition of reflectance colors of one-dimensional (1D) photonic crystal (PC) dichroic film on the black part of a partial-light-transmitting CIGSSe PV module. Beautiful violets and blues were created on the cover glass of a black CIGSSe PV module via the addition of 1D PC blue-mirror-yellow-pass dichroic film to improve the aesthetic value of the outside appearance. As a general result from the low external quantum efficiency (EQE) and absorption of CIGSSe PVs below a wavelength of 400 nm, the harvesting efficiency and short-circuit photocurrent of CIGSSe PVs were reduced by only ∼10% without reducing the open-circuit voltage (VOC) because of the reduced overlap between the absorption spectrum of CIGSSe PV and the reflectance spectrum of the 1D PC blue-mirror-yellow-pass dichroic film. The combined technology of partial-vacancy-scribed CIGSSe PV modules and blue 1D PC dichroic film can provide a simple strategy to be applied to violet/blue power-generating window applications, as such a strategy can improve the transparency and aesthetic value without significantly sacrificing the harvesting efficiency of the CIGSSe PV modules.

10.
ACS Appl Mater Interfaces ; 8(42): 28844-28852, 2016 Oct 26.
Artigo em Inglês | MEDLINE | ID: mdl-27670778

RESUMO

With the aim to build a multifunctional solid fluorescent controller, a one-dimensional photonic crystal and CdSe fluorescent single layer were separated on the opposite sides of quartz substrates. The separation structure remarkably facilitates materials selection for the fluorescent controller, which allows one to freely choose the fluorescent substance and constituents of 1DPC from a wide range of available materials with the best desirable properties and without caring about the interactions between them. Fluorescent enhancement and weakened effect were successfully achieved when the excitation light was irradiated from different sides of the fluorescent device. In addition, the fluorescent intensity can be altered reversibly along with environmental pH values according to the change of a pH-responsive one-dimensional photonic crystal layer, which is quite different from a previously reported quenching mode. Meanwhile, the original position of the photonic stop band is essential for deciding what pH value would produce the best effect of fluorescent control. It provides a way to adjust the effect of fluorescent controller according to certain applied situations. The mechanism of fluorescent variation was confirmed by the assistance of a finite-difference time-domain simulation. Furthermore, this device is also able to modulate fluorescent wavelength and full width at half-maximum by overlapping the photonic stop band and the emission of CdSe. Therefore, this method offers a universal strategy for the fabrication of fluorescent controllers.

11.
ACS Appl Mater Interfaces ; 7(6): 3641-6, 2015 Feb 18.
Artigo em Inglês | MEDLINE | ID: mdl-25647806

RESUMO

We demonstrate the fabrication and performance of tunable, elastic organic/inorganic composite one-dimensional photonic crystals (1DPCs) in the visible spectrum. By controlling the composition of high refractive index metal oxide nanoparticle/polymer composites, a refractive index difference of 0.18 between the filled and unfilled polymer layers can be achieved while maintaining desirable flexibility and elasticity. This index contrast is achieved with a loading of 70 wt % zirconium dioxide nanoparticles within a slide-ring elastomer matrix, which is composed of topologically cross-linked polyrotaxane polyols. The large refractive index contrast enables high reflectivity while simultaneously minimizing the number of layers necessary, compared to purely polymer systems. Because the films are both flexible and elastic, these nanocomposite 1DPCs can function as colorimetric strain sensors. We demonstrate the sensing behavior of these 1DPCs by applying over 40% strain, resulting in a visible color shift across the visible spectrum from red to blue. 1DPCs of just 6 periods maintain reflectance of 40% throughout the visible spectrum, with a tensile mechanochromic sensitivity (Δλ/Δεmax) as high as -6.05 nm/%.

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