Single-Shot Multispectral Encoding: Advancing Optical Lithography for Encryption and Spectroscopy.

Most modern optical display and sensing devices utilize a limited number of spectral units within the visible range, based on human color perception. In contrast, the rapid advancement of machine-based pattern recognition and spectral analysis could facilitate the use of multispectral functional units, yet the challenge of creating complex, high-definition, and reproducible patterns with an increasing number of spectral units limits their widespread application. Here, we report a technique for optical lithography that employs a single-shot exposure to reproduce perovskite films with spatially controlled optical band gaps through light-induced compositional modulations. Luminescent patterns are designed to program correlations between spatial and spectral information, covering the entire visible spectral range. Using this platform, we demonstrate multispectral encoding patterns for encryption and multivariate optical converters for dispersive optics-free spectroscopy with high spectral resolution. The fabrication process is conducted at room temperature and can be extended to other material and device platforms.

Temperature-Dependent Excitonic Light Manipulation with Atomically Thin Optical Elements.

Monolayer 2D semiconductors, such as WS2, exhibit uniquely strong light-matter interactions due to exciton resonances that enable atomically thin optical elements. Similar to geometry-dependent plasmon and Mie resonances, these intrinsic material resonances offer coherent and tunable light scattering. Thus far, the impact of the excitons' temporal dynamics on the performance of such excitonic metasurfaces remains unexplored. Here, we show how the excitonic decay rates dictate the focusing efficiency of an atomically thin lens carved directly out of exfoliated monolayer WS2. By isolating the coherent exciton radiation from the incoherent background in the focus of the lens, we obtain a direct measure of the role of exciton radiation in wavefront shaping. Furthermore, we investigate the influence of exciton-phonon scattering by characterizing the focusing efficiency as a function of temperature, demonstrating an increased optical efficiency at cryogenic temperatures. Our results provide valuable insights into the role of excitonic light scattering in 2D nanophotonic devices.

Effect of fractional picosecond laser therapy using a diffractive optical lens on histological tissue reaction.

BACKGROUND AND OBJECTIVES: Fractional ablative resurfacing techniques are preferred treatments for facial rejuvenation of aged skin. This study was performed to investigate the cutaneous effects of using a fractional picosecond laser at 1064 nm with a diffractive lens. METHODS: The penetration depth according to the location of the handpiece tip was evaluated using an acrylic panel. Laser induced optical breakdown (LIOB) and cutaneous damage were observed after hematoxylin and eosin staining in guinea pigs. Collagen formation was evaluated using Victoria staining, Masson's trichrome (MT) staining, and immunohistochemical staining for collagen type III. RESULTS: The penetration depth for LEVEL 1 was 499.98-935.23 µm (average: 668.75 ± 182.84 µm); the LIOB cavity area was 1664.17 ± 650.52 µm2. The penetration depth of LEVEL 2 was 257.12-287.38 µm (average: 269.77 ± 14.55 µm) with an LIOB cavity area of 1335.85 ± 214.41 µm2. At LEVEL 3, that was 36.17-53.69 µm (average: 52.15 ± 20.81 µm) and the LIOB cavity area was 1312.67 ± 1069.12 µm2. No epidermal tissue damage was observed and collagen formation was observed from day 14 under all conditions. CONCLUSION: Diffractive optical element (DOE) lens arranged laser treatment system controlled the position of LIOB occurrence and an irradiating area.

A Centimeter-Scale Dielectric Metasurface for the Generation of Cold Atoms.

The single-beam magneto-optical trap (MOT) based on the diffractive optical element offers a new route to develop compact cold atom sources. However, the optical efficiency in the previous single-beam MOT systems is usually low and unbalanced, which will affect the quality of the trapped atoms. To solve this issue, we developed a centimeter-scale dielectric metasurface optical chip with dynamic phase distributions, which was used to split a single incident laser beam into five separate ones with well-defined polarization states and uniform energy distributions. The measured diffraction efficiency of the metasurface is up to 47%. A single-beam MOT integrated with the metasurface optical chip was then used to trap the 87Rb atoms with numbers ∼1.4 × 108 and temperatures ∼7.0 µK. The proposed concept in this work may provide a promising solution for developing ultracompact cold atom sources.

Subwavelength Diffractive Optical Elements for Generation of Terahertz Coherent Beams with Pre-Given Polarization State.

Coherent terahertz beams with radial polarization of the 1st, 2nd, and 3rd orders have been generated with the use of silicon subwavelength diffractive optical elements (DOEs). Silicon elements were fabricated by a technology similar to the technology used before for the fabrication of DOEs forming laser terahertz beams with pre-given mode content. The beam of the terahertz Novosibirsk Free Electron Laser was used as the illuminating beam. The experimental results are in good agreement with the results of the computer simulation.

Head-Mounted Miniature Motorized Camera and Laser Pointer Driven by Eye Movements.

Recording a video scene as seen by an observer, materializing where is focused his visual attention and allowing an external person to point at a given object in this scene, could be beneficial for various applications such as medical education or remote training. Such a versatile device, although tested at the experimental laboratory demonstrator stage, has never been integrated in a compact and portable way in a real environment. In this context, we built a low-cost, light-weight, head-mounted device integrating a miniature camera and a laser pointer that can be remotely controlled or servo-controlled by an eye tracker. Two motorizations were implemented and tested (pan/tilt and Rilsey-prisms-based). The video was both recorded locally and transmitted wirelessly. Risley prisms allowed finer remote control of camera or laser pointer orientation (0.1° vs. 0.35°), but data processing and Wi-Fi transmission incur significant latency (~0.5 s) limiting the servo-controlling by eye movements. The laser beam was spatially shaped by a Diffractive Optical Element to facilitate object illumination or recognition. With this first proof-of-concept prototype, the data stream needs to be optimized to make full use of the eye tracker, but this versatile device can find various applications in education, healthcare or research.

Design of a Multimodal Oculometric Sensor Contact Lens.

Oculometric data, such as gaze direction, pupil size and accommodative change, play a key role nowadays in the analysis of cognitive load and attentional activities, in particular with the development of Integrated Visual Augmentation Systems in many application domains, such as health, defense and industry. Such measurements are most frequently obtained by different devices, most of them requiring steady eye and body positions and controlled lighting conditions. Recent advances in smart contact lens (SCL) technology have demonstrated the ability to achieve highly reliable and accurate measurements, preserving user mobility, for instance in measuring gaze direction. In this paper, we discuss how these three key functions can be implemented and combined in the same SCL, considering the limited volume and energy consumption constraints. Some technical options are discussed and compared in terms of their ability to be implemented, taking advantage of recent developments in the field.

Simplifying the Experimental Detection of the Vortex Topological Charge Based on the Simultaneous Astigmatic Transformation of Several Types and Levels in the Same Focal Plane.

It is known that the astigmatic transformation can be used to analyze the topological charge of a vortex beam, which can be implemented by using various optical methods. In this case, in order to form an astigmatic beam pattern suitable for the clear detection of a topological charge, an optical adjustment is often required (changing the lens tilt and/or the detection distance). In this article, we propose to use multi-channel diffractive optical elements (DOEs) for the simultaneous implementation of the astigmatic transformations of various types and levels. Such multi-channel DOEs make it possible to insert several types of astigmatic aberrations of different levels into the analyzed vortex beam simultaneously, and to form a set of aberration-transformed beam patterns in different diffraction orders in one detection plane. The proposed approach greatly simplifies the analysis of the characteristics of a vortex beam based on measurements in the single plane without additional adjustments. In this article, a detailed study of the effect of various types of astigmatic aberrations based on a numerical simulation and experiments was carried out, which confirmed the effectiveness of the proposed approach.

Computational Imaging in Dual-Band Infrared Hybrid Optical System with Wide Temperature Range.

The special dispersion and temperature characteristics of diffractive optical element (DOE) make them widely used in optical systems that require both athermalization and achromatic aberrations designs. The multi-layer DOE (MLDOE) can improve the diffraction efficiency of the overall broad waveband, but its diffraction efficiency decreases with changes in ambient temperature. When the ambient temperature changes, the micro-structure heights of MLDOE and the refractive index of the substrate materials change, ultimately affecting its diffraction efficiency, and, further, the optical transform function (OTF). In this paper, the influence of ambient temperature on the diffraction efficiency of MLDOE in a dual-infrared waveband is proposed and discussed, the diffraction efficiency of MLDOE caused by ambient temperature is derived, and a computational imaging method that combines optical design and image restoration is proposed. Finally, a dual-infrared waveband infrared optical system with athermalization and achromatic aberrations corrected based on computational imaging method is designed. Results show that this method can effectively reduce the diffraction efficiency of MLDOE by ambient temperature and improve the imaging quality of hybrid optical systems.

Phase Compensation of the Non-Uniformity of the Liquid Crystal on Silicon Spatial Light Modulator at Pixel Level.

Phase compensation is a critical step for the optical measuring system using spatial light modulator (SLM). The wavefront distortion from SLM is mainly caused by the phase modulation non-linearity and non-uniformity of SLM's physical structure and environmental conditions. A phase modulation characteristic calibration and compensation method for liquid crystal on silicon spatial light modulator (LCoS-SLM) with a Twyman-Green interferometer is illustrated in this study. A method using two sequences of phase maps is proposed to calibrate the non-uniformity character over the whole aperture of LCoS-SLM at pixel level. A phase compensation matrix is calculated to correct the actual phase modulation of the LCoS-SLM and ensure that the designed wavefront could be achieved. Compared with previously known compensation methods, the proposed method could obtain the phase modulation characteristic curve of each pixel on the LCoS-SLM, rather than a mono look-up table (LUT) curve or multi-LUT curves corresponding to an array of blocks over the whole aperture of the LCoS-SLM. The experiment results show that the phase compensation precision could reach a peak-valley value of 0.061λ in wavefront and this method can be applied in generating freeform wave front for precise optical performance.

Spatial-Light-Modulator-Based Multichannel Data Transmission by Vortex Beams of Various Orders.

We report an atmospheric multichannel data transmission system with channel separation by vortex beams of various orders, including half-integer values. For the demultiplexing of the communication channels, a multichannel diffractive optical element (DOE) is proposed, being matched with the used vortex beams. The considered approach may be realized without digital processing of the output images, but only based on the numbers of informative diffraction orders, similar to sorting. The system is implemented based on two spatial light modulators (SLMs), one of which forms a multiplexed signal on the transmitting side, and the other implements a multichannel DOE for separating the vortex beams on the receiving side. The stability of the communication channel to atmospheric interference and the crosstalk between the channels are investigated.

Fast convolution-based performance estimation method for diffraction-limited source with imperfect X-ray optics.

Although optical element error analysis is always an important part of beamline design for highly coherent synchrotron radiation or free-electron laser sources, the usual wave optics simulation can be very time-consuming, which limits its application at the early stage of the beamline design. In this work, a new theoretical approach has been proposed for quick evaluations of the optical performance degradation due to optical element error. In this way, time-consuming detailed simulations can be applied only when truly necessary. This approach treats the imperfections as perturbations that convolve with the ideal performance. For simplicity, but not by necessity, the Gaussian Schell-model has been used to show the application of this theoretical approach. The influences of the finite aperture size and height error of a focusing mirror are analysed using the proposed theory. The physical explanation of the performance degradation acquired from the presented approach helps to give a better definition of the critical range of error spatial frequencies that most affect the performance of a mirror. An example comparing two mirror surface errors with identical power spectral density functions is given. These two types of mirror surface errors result in very different intensity profiles. The approach presented in this work could help beamline designers specify the error tolerances on general optical elements more accurately.

Hydrogen Sulfide Gas Detection via Multivariate Optical Computing.

Hydrogen-sulfide gas is a toxic, colorless gas with a pungent odor that occurs naturally as a decomposition by-product. It is critical to monitor the concentration of hydrogen sulfide. Multivariate optical computing (MOC) is a method that can monitor analytes while minimizing responses to interferences. MOC is a technique by which an analogue calculation is performed entirely in the optical domain, which simplifies instrument design, prevents the drift of a calibration, and increases the strength and durability of spectroscopic instrumentation against physical perturbation when used for chemical detection and identification. This paper discusses the detection of hydrogen-sulfide gas in the ultraviolet (UV) spectral region in the presence of interfering gaseous species. A laboratory spectroscopic measurement system was set up to acquire the UV spectra of H2S and interference gas mixtures in high-pressure/high-temperature (HPHT) conditions. These spectra were used to guide the design and fabrication of a multivariate optical element (MOE), which has an expected measurement relative accuracy of 3.3% for H2S, with a concentration in the range of 0⁻150 nmol/mL. An MOC validation system with the MOE was used to test three samples of H2S and mercaptans mixtures under various pressures, and the relative accuracy of H2S measurement was determined to be 8.05%.

A Microflow Cytometer with a Rectangular Quasi-Flat-Top Laser Spot.

This work develops a microflow cytometer, based on a microfluidic chip for three-dimensional (3D) hydrodynamic focusing and a binary optical element (BOE) for shaping and homogenizing a laser beam. The microfluidic chip utilizes sheath flows to confine the sample flow along the channel centerline with a narrow cross section. In addition to hydrodynamic focusing, secondary flows are generated to strengthen the focusing in the vertical direction. In experiments, the chip was able to focus the sample flow with cross sections of 15 µm high and 8-30 µm wide at 5 m/s, under the condition of the sample flow rates between 10 and 120 µL/min. Instead of using the conventional elliptical Gaussian spot for optical detection, we used a specially designed BOE and obtained a 50 µm × 10 µm rectangular quasi-flat-top spot. The microflow cytometer combining the chip and the BOE was tested to count 3, 5, and 7 µm fluorescence microbeads, and the experimental results were comparable to or better than those derived from two commercial instruments.

High Resolution Multiview Holographic Display Based on the Holographic Optical Element.

Limited by the low space-bandwidth product of the spatial light modulator (SLM), it is difficult to realize multiview holographic three-dimensional (3D) display. To conquer the problem, a method based on the holographic optical element (HOE), which is regarded as a controlled light element, is proposed in the study. The SLM is employed to upload the synthetic phase-only hologram generated by the angular spectrum diffraction theory. Digital grating is introduced in the generation process of the hologram to achieve the splicing of the reconstructions and adjust the position of the reconstructions. The HOE fabricated by the computer-generated hologram printing can redirect the reconstructed images of multiview into multiple viewing zones. Thus, the modulation function of the HOE should be well-designed to avoid crosstalk between perspectives. The experimental results show that the proposed system can achieve multiview holographic augmented reality (AR) 3D display without crosstalk. The resolution of each perspective is 4K, which is higher than that of the existing multiview 3D display system.

Transforming a Mid-infrared Laser Profile from Gaussian to a Top-Hat with a Diffractive Optical Element for Mass Spectrometry Imaging.

Many mass spectrometry imaging (MSI) applications such as infrared matrix-assisted electrospray ionization (IR-MALDESI) employ an infrared (IR) laser with a Gaussian profile where laser irradiance is highest in the center and decreases exponentially. To enable full ablation of a square region of interest, oversampling is often needed, which results in nonuniform ablation and leads to decreased image quality. A diffractive optical element (DOE) was integrated into the optical path to generate homogeneous intensity distributions while maintaining laser energy above the ablation threshold, to enable complete sample removal from laser pulses without oversampling. 2D and 3D imaging with the DOE inserted show clear and sharp ablation patterns with satisfactory biological signals gained. Further improvements will optimize the beam profile and generate a square top-hat laser beam for MSI application at higher spatial resolution.

What Binarization Method Is the Best for Amplitude Inline Fresnel Holograms Synthesized for Divergent Beams Using the Direct Search with Random Trajectory Technique?

Fast reconstruction of holographic and diffractive optical elements (DOE) can be implemented by binary digital micromirror devices (DMD). Since micromirrors of the DMD have two positions, the synthesized DOEs must be binary. This work studies the possibility of improving the method of synthesis of amplitude binary inline Fresnel holograms in divergent beams. The method consists of the modified Gerchberg-Saxton algorithm, Otsu binarization and direct search with random trajectory technique. To achieve a better quality of reconstruction, various binarization methods were compared. We performed numerical and optical experiments using the DMD. Holograms of halftone image with size up to 1024 × 1024 pixels were synthesized. It was determined that local and several global threshold methods provide the best quality. Compared to the Otsu binarization used in the original method of the synthesis, the reconstruction quality (MSE and SSIM values) is improved by 46% and the diffraction efficiency is increased by 27%.

Metasurface Micro/Nano-Optical Sensors: Principles and Applications.

Metasurfaces are 2D artificial materials consisting of arrays of metamolecules, which are exquisitely designed to manipulate light in terms of amplitude, phase, and polarization state with spatial resolutions at the subwavelength scale. Traditional micro/nano-optical sensors (MNOSs) pursue high sensitivity through strongly localized optical fields based on diffractive and refractive optics, microcavities, and interferometers. Although detections of ultra-low concentrations of analytes have already been demonstrated, the label-free sensing and recognition of complex and unknown samples remain challenging, requiring multiple readouts from sensors, e.g., refractive index, absorption/emission spectrum, chirality, etc. Additionally, the reliability of detecting large, inhomogeneous biosamples may be compromised by the limited near-field sensing area from the localization of light. Here, we review recent advances in metasurface-based MNOSs and compare them with counterparts using micro-optics from aspects of physics, working principles, and applications. By virtue of underlying the physics and design flexibilities of metasurfaces, MNOSs have now been endowed with superb performances and advanced functionalities, leading toward highly integrated smart sensing platforms.

Diffractive and Interferometric Characterization of Nanostructured Photopolymer for Sharp Diffractive Optical Elements Recording.

We study the behavior of a nanoparticle-polymer composite (NPC) material, based on a thiol-ene monomer system, working with long grating spacing. Thus, we evaluate the suitability of the NPC for storing complex diffractive optical elements with sharp profiles, such as blazed gratings. Using holographic methods, we measure the "apparent" diffusion of the material and the influence of the spatial period on this diffusion. The applicability of this material in complex diffractive optical elements (DOEs) recording is analyzed using an interferometric method. Supported by the results of this analysis, we record blazed gratings with different grating spacing and measure the maximum diffraction efficiency (DE) achieved. The results show that NPC has a good behavior in this range of spatial frequencies.

The Use of Functionalized Silk Fibroin Films as a Platform for Optical Diffraction-Based Sensing Applications.

A set of biocompatible, biodegradable, and biofunctionalizable diffractive optical elements (DOEs) using silk proteins as the building materials is reported. The diffraction pattern of a DOE is highly sensitive to the surrounding environment and the structural integrity, offering numerous opportunities for biosensing applications.