New polyfunctional magnesium reagents for organic synthesis
Chemistry
; 6(5): 767-70, 2000 Mar 03.
Article
em En
| MEDLINE
| ID: mdl-10826597
ABSTRACT
The iodine-magnesium exchange reaction allows the preparation of polyfunctional aryl, heteroaryl, or alkenyl magnesium reagents at low temperature. These reagents display the typical reactivity of Grignard compounds and undergo various copper-catalyzed reactions such as allylation or 1,4-addition. Using this halogen-metal exchange reaction, it was possible to generate polyfunctional magnesium reagents on the solid phase.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2000
Tipo de documento:
Article