Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol.
Org Lett
; 3(1): 135-7, 2001 Jan 11.
Article
em En
| MEDLINE
| ID: mdl-11429857
ABSTRACT
[figure see text] Two distinctively different total syntheses of natural sclerophytin A in its revised structural formulation are reported. The first proceeds from (S)-carvone via a cladiellene triol and involves photoisomerization of the double bond. The second route makes use of (5S)-5-(d-menthyloxy)-2(5H)-furanone, which is subjected to cycloaddition, Claisen ring expansion, and regiocontrolled dihydroxylation tactics.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Hidrocarbonetos Aromáticos com Pontes
/
Fatores Biológicos
/
Furanos
Idioma:
En
Ano de publicação:
2001
Tipo de documento:
Article