Ion-neutral complexes formation and 1,3-proton transfer in the chemical ionization of alkylcyclohexyl benzoates.

Denekamp, Chagit; Stanger, Amnon

Denekamp, Chagit; Stanger, Amnon.

Afiliação

Denekamp C; Department of Chemistry, Institute of Catalysis Science and Technology, Lise-Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel. chchagit@tx.technion.ac.il

Chem Commun (Camb) ; (3): 236-7, 2002 Feb 07.

Article em En | MEDLINE | ID: mdl-12120382

ABSTRACT

ABSTRACT

CI, CID, labelling experiments and DFT calculations are used for the elucidation of the mechanism for the decomposition of cyclohexyl benzoates, which proceeds through 1,3-H shift and two equilibrating ion-neutral complexes.

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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2002 Tipo de documento: Article

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PubMed Links

Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2002 Tipo de documento: Article