Nonvolatile Me(3)P-like P-donor ligand: synthesis and properties of 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane.
Org Lett
; 5(15): 2671-4, 2003 Jul 24.
Article
em En
| MEDLINE
| ID: mdl-12868886
ABSTRACT
[reaction see text] A new trialkylphosphine ligand with Me(3)P-like steric and electronic properties, 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane (Ph-SMAP), was synthesized. Given a phenyl group at the silicon atom, the Ph-SMAP ligand displayed nonvolatility with retention of Me(3)P-like properties. The new ligand was air-stable, crystalline, and easy to handle.
Buscar no Google
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2003
Tipo de documento:
Article