Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
Chem Commun (Camb)
; (4): 434-5, 2004 Feb 21.
Article
em En
| MEDLINE
| ID: mdl-14765245
ABSTRACT
A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me(3)[9]aneN(3))Cl(2)](R = alkyl or aryl; Me(3)[9]aneN(3)= 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation precatalysts with activities in the range ca. 3 400 to 10 000 kg(PE) mol(-1) h(-1) bar(-1).
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MEDLINE
Tipo de estudo:
Diagnostic_studies
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Screening_studies
Idioma:
En
Ano de publicação:
2004
Tipo de documento:
Article