Reductive olefination of aldehydes via chromium Brook rearrangement.
Org Lett
; 8(14): 2949-51, 2006 Jul 06.
Article
em En
| MEDLINE
| ID: mdl-16805524
ABSTRACT
[reaction see text] The combination of CrCl(2) and silyl chlorides converts aryl and conjugated aldehydes into olefinic adducts in good to excellent yields. When constrained by structural features, the intermediate vic-diol can be isolated. Available data are consistent with a novel chromium Brook rearrangement.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Silanos
/
Cromo
/
Aldeídos
/
Alcenos
Idioma:
En
Ano de publicação:
2006
Tipo de documento:
Article