Crystal structures of poly(aryl ether) dendrons with palladium scorpionate complexes at their focal point.
Inorg Chem
; 46(12): 4793-5, 2007 Jun 11.
Article
em En
| MEDLINE
| ID: mdl-17489590
ABSTRACT
Novel palladium(II) complexes with bis(pyrazol-1-yl)methane ligands at the focal point of G0-G3 poly(aryl ether) Fréchet-type dendrons are reported. The molecular structures of the metallodendrimer series G0, G1, and G2 [(dend)CH(3,5-Me2pz)2(PdCl2)] have been determined by X-ray diffraction methods. The three structures show a similar three-dimensional organization of the metal complex, which is progressively engulfed by the branches with increasing dendrimer generation.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2007
Tipo de documento:
Article