Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site.
Dalton Trans
; (34): 3754-6, 2007 Sep 14.
Article
em En
| MEDLINE
| ID: mdl-17712440
Treatment of [Fe(2)(micro-pdt)(CO)(6)] (pdt = S(CH(2))(3)S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe(2)(micro-pdt)(CO)(4)(phen)] (1); the protonation of with HBF(4).OEt(2) in CD(2)Cl(2) at 203 K has been monitored by (1)H NMR.
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01-internacional
Base de dados:
MEDLINE
Assunto principal:
Fenantrolinas
/
Compostos de Sulfidrila
/
Compostos Férricos
/
Hidrogenase
/
Ferro
/
Proteínas Ferro-Enxofre
Idioma:
En
Ano de publicação:
2007
Tipo de documento:
Article