A gas-phase study of the preferential solvation of Mn(2+) in mixed water/methanol clusters.
J Am Soc Mass Spectrom
; 19(4): 520-30, 2008 Apr.
Article
em En
| MEDLINE
| ID: mdl-18258449
ABSTRACT
The kinetic shift that exists between two competing unimolecular fragmentation processes has been used to establish whether or not gas-phase Mn(2+) exhibits preferential solvation when forming mixed clusters with water and methanol. Supported by molecular orbital calculations, these first results for a metal dication demonstrate that Mn(2+) prefers to be solvated by methanol in the primary solvation shell.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2008
Tipo de documento:
Article