Reversible structural modulation of Fe-Pt bimetallic surfaces and its effect on reactivity.

ABSTRACT

Tunable surface The surface structure of the Fe-Pt bimetallic catalyst can be reversibly modulated between the iron-oxide-rich Pt surface and the Pt-skin structure with subsurface Fe via alternating reduction and oxidation treatments (see figure). The regenerated active Pt-skin structure is active in reactions involving CO and/or O.