A mild method for the efficient [3,3]-sigmatropic rearrangement of N,O-diacylhydroxylamines.
J Org Chem
; 74(20): 8001-3, 2009 Oct 16.
Article
em En
| MEDLINE
| ID: mdl-19754109
ABSTRACT
A mild, general method for the [3,3]-sigmatropic rearrangement of N,O-diacylhydroxylamines, employing a combination of mild base and Lewis acid, is described. Employing stoichiometric amounts of reagents with respect to substrate provides alpha-acyloxyamides, whereas an excess of reagents favors formation of cyclic orthoamides.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Hidroxilaminas
Idioma:
En
Ano de publicação:
2009
Tipo de documento:
Article