Photodesorption of excited iodine atoms from KI (100).
J Chem Phys
; 131(14): 144509, 2009 Oct 14.
Article
em En
| MEDLINE
| ID: mdl-19831454
ABSTRACT
Band-to-band photoexcitation of potassium iodide single crystals with UV photons produces thermal and hyperthermal I-atom emission in both the ground I((2)P(3/2)) and spin-orbit excited I( *)((2)P(1/2)) states. Thermal halogen atom emission is preceded by H-center diffusion from bulk to surface and excited atom emission indicates that the excited hole spin state relaxation is incomplete before H-center diffusion to the surface. The hyperthermal I-atom kinetic energy distribution is inverted in the sense that the electronically excited I( *)((2)P(1/2)) atoms are more energetic than the ground state I((2)P(3/2)) atoms. The mechanism for hyperthermal emission of halogen atoms and their kinetic energy distributions are discussed in terms of recent calculations and a simple curve crossing model for the dynamical desorption process.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2009
Tipo de documento:
Article