Making mixtures to solve structures: structural elucidation via combinatorial synthesis.
J Comb Chem
; 12(1): 141-50, 2010.
Article
em En
| MEDLINE
| ID: mdl-20000720
ABSTRACT
A domino Horner-Wadsworth-Emmons olefination strategy has been used to prepare homologous series of (polyen)ones, and through combinatorial elaboration, corresponding families of highly branched hydrocarbons. Gas chromatography-mass spectrometry of the mixtures has enabled the rapid and unambiguous identification of several highly branched alkanes of geochemical importance. This is the first example of the use of combinatorial synthesis for the elucidation of structural connectivity.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Polipropilenos
/
Técnicas de Química Combinatória
/
Alcanos
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article