Microporous lanthanide-organic frameworks with open metal sites: unexpected sorption propensity and multifunctional properties.
Inorg Chem
; 49(11): 4723-5, 2010 Jun 07.
Article
em En
| MEDLINE
| ID: mdl-20450205
ABSTRACT
Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd(3+) to Gd(3+), which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Elementos da Série dos Lantanídeos
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article