Spiro oligothiophenes.
Org Lett
; 12(14): 3230-3, 2010 Jul 16.
Article
em En
| MEDLINE
| ID: mdl-20550149
ABSTRACT
Linear oligothiophenes, containing annelated dithieno[2,3-b3',2'-d]thiophene units, undergo unexpected spirocyclizations upon treatment with trifluoroacetic acid. The resultant spiro oligothiophenes possess novel structures in which the spiro or dispiro skeleton is within an all-thiophene/dihydrothiophene framework. Racemic dispiro octathiophene is obtained with high diastereoselectivity and in high yield.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article