Differences between the macroscopic and tracer level chemistry of rhenium and technetium: contrasting cage isomerisation behaviour of Re(I) and Tc(I) carborane complexes.
Dalton Trans
; 39(35): 8128-31, 2010 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-20694253
ABSTRACT
Carboranes form stable complexes with the [M(CO)(3)](+) (M = (99m)Tc, Re) core and are viable ligands for the development of targeted radiopharmaceuticals. (99m)Tc-carborane complexes were found to exhibit substantially different 1,2-->1,7 cage isomerisation behaviour than their Re counterparts, challenging the validity of the routine use of rhenium as a surrogate for the development of technetium-99m based molecular imaging agents.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Rênio
/
Boranos
/
Tecnécio
/
Compostos Radiofarmacêuticos
/
Complexos de Coordenação
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article