Bis{2-[2-(isopropyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}nickel(II) dithio-cyanate.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 4): m597-8, 2008 Mar 29.
Article
em En
| MEDLINE
| ID: mdl-21202042
ABSTRACT
The title complex, [Ni(C(13)H(20)N(2)O(2))(2)](NCS)(2), consists of a centrosymmetric mononuclear four-coordinate nickel(II) complex cation and two thio-cyanate anions. The Ni atom is located on an inversion center and is coordinated by two phenol O atoms and two imine N atoms from two equivalent Schiff base ligands, in a square-planar geometry. In the crystal structure, the amino H atoms are involved in N-Hâ¯O hydrogen bonds with the phenol and meth-oxy O atoms of the ligand, and in N-Hâ¯N hydrogen bonds with the N atoms of the thio-cyanate anions, which sit above and below the Ni atom.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2008
Tipo de documento:
Article