2,6-Diisopropyl-anilinium chloride.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 8): o1480, 2008 Jul 12.
Article
em En
| MEDLINE
| ID: mdl-21203192
ABSTRACT
The title compound, C(12)H(20)N(+)·Cl(-), crystallizes with the chloride anions situated on twofold axes, while the cation is on a general position. All conventional hydrogen-bond donors and acceptors are utilized, forming a hydrogen-bonded ladder motif along the c axis. Investigation of the torsion angles between aromatic systems and isopropyl groups reveals unusual geometrical features. One isopropyl groups exhibits an expected eclipsed conformation with respect to the aromatic ring. The other isopropyl group shows a slight twist with respect to the aromatic ring. The short Clâ¯HC(methine) contact (2.88â
Å) observed in the asymmetric unit is the probable reason for the twist feature around the isopropyl area.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2008
Tipo de documento:
Article