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Poly[µ3-hydroxido-µ6-sulfato-µ3-(1,2,4-triazolato-κ3N1:N2:N4)-dicadmium(II)]: a cadmium-triazolate coordination polymer with a pseudo-cubane-like tetranuclear cluster.
Liang, Qian; Pan, Tong-Hen; Huang, Chang-Cang.
Afiliação
  • Liang Q; State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fujian, People's Republic of China.
Acta Crystallogr C ; 67(Pt 2): m56-8, 2011 Feb.
Article em En | MEDLINE | ID: mdl-21285497
The title complex, [Cd(2)(C(2)H(2)N(3))(OH)(SO(4))](n), is a three-dimensional metal-organic framework consisting of pseudo-cubane-like tetranuclear cadmium clusters, which are formed by four Cd(II) atoms, two sulfate groups and two hydroxide groups. The tetranuclear cadmium clusters are connected into a layered substructure by Cd-O bonds and adjacent layers are linked by triazolate ligands into a three-dimensional network. A photoluminescent study revealed that the complex exhibits a strong emission in the visible region which probably originates from a π-π* transition.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE País/Região como assunto: Cuba Idioma: En Ano de publicação: 2011 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE País/Região como assunto: Cuba Idioma: En Ano de publicação: 2011 Tipo de documento: Article