Single-molecule chemistry and analysis: mode-specific dehydrogenation of adsorbed propene by inelastic electron tunneling.
J Am Chem Soc
; 133(15): 5689-91, 2011 Apr 20.
Article
em En
| MEDLINE
| ID: mdl-21443208
ABSTRACT
A single propene molecule, located in the junction between the tip of a scanning tunneling microscope (STM) and a Cu(211) surface can be dehydrogenated by inelastic electron tunneling. This reaction requires excitation of the asymmetric C-H stretching vibration of the âCH(2) group. The product is then identified by inelastic electron tunneling action spectroscopy (IETAS).
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2011
Tipo de documento:
Article