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Ni-catalyzed ketene cycloaddition: a system that resists the formation of decarbonylation side products.
Kumar, Puneet; Troast, Dawn M; Cella, Rodrigo; Louie, Janis.
Afiliação
  • Kumar P; Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-8450, USA.
J Am Chem Soc ; 133(20): 7719-21, 2011 May 25.
Article em En | MEDLINE | ID: mdl-21528904
ABSTRACT
Ni-phosphine complexes were used as catalysts for the cycloaddition of various ketenes and diynes. In general, 2,4-cyclohexadienones were formed instead of products arising from decarbonylation of the ketenes.
Assuntos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Etilenos / Cetonas / Níquel Idioma: En Ano de publicação: 2011 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Etilenos / Cetonas / Níquel Idioma: En Ano de publicação: 2011 Tipo de documento: Article