[1,2-Bis(diphenyl-phosphino)ethane]-chlorido(η-penta-methyl-cyclo-penta-dien-yl)iron(II) dichloro-methane solvate.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 8): m921, 2010 Jul 10.
Article
em En
| MEDLINE
| ID: mdl-21588156
ABSTRACT
In the title compound, [Fe(C(10)H(15))Cl(C(26)H(24)P(2))]·CH(2)Cl(2), the Fe(II) atom is coordinated by two P atoms from a 1,2-bis-(diphenyl-phosphino)ethane ligand [Fe-P = 2.2130â
(7) and 2.2231â
(7)â
Å], a chloride anion [Fe-Cl = 2.3329â
(7)â
Å] and a penta-methyl-cyclo-penta-dienyl (Cp*) ligand [Fe-centroid(Cp*) = 1.732â
(3)â
Å] in a typical piano-stool geometry. In the crystal structure, the complex and solvent mol-ecules are paired via weak C-Hâ¯Cl inter-actions.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article