Aqua-dipyridine-bis-(N-p-tolysulfonyl-l-leucinato)nickel(II).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 11): m1346, 2010 Oct 02.
Article
em En
| MEDLINE
| ID: mdl-21588793
ABSTRACT
In each of the two mol-ecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octa-hedron, arising from its coordination by one water mol-ecule, two pyridine mol-ecules, and one O-monodentate and one O,O'-bidentate deprotonated N-p-tolysulfonyl-l-leucine ligand. In the crystal, mol-ecules are linked by N-Hâ¯O and O-Hâ¯O hydrogen bonds, forming chains along the c axis. An intra-molecular O-Hâ¯O hydrogen bond occurs in one of the mol-ecules.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2010
Tipo de documento:
Article