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Should the Gibbs analysis be revised?
Laven, Jozua; de With, Gijsbertus.
Afiliação
  • Laven J; Laboratory for Materials and Interface Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. J.Laven@tue.nl
Langmuir ; 27(12): 7958-62; discussion 7963-5, 2011 Jun 21.
Article em En | MEDLINE | ID: mdl-21604731
Recently, some arguments were published that cast doubt on the validity of the Gibbs adsorption isotherm. The doubt was on whether the often visible linearly declining part in the surface tension versus logarithm of concentration plot of a surfactant solution, just before the critical micelle concentration, really represents a situation of constant adsorption. Those published arguments are partly of a conceptual nature and partly based on experimental evidence. The conceptual arguments appear to be based on a misunderstanding of the theory, while the arguments based on experimental evidence stem from an inaccurate treatment of these data. Our conclusion is that none of the relevant arguments put forward are valid. The experimental evidence, if properly treated, is in line with the Gibbs theory.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2011 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2011 Tipo de documento: Article