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Inducing hysteretic spin crossover in solution.
Martinho, Paulo N; Ortin, Yannick; Gildea, Brendan; Gandolfi, Claudio; McKerr, George; O'Hagan, Barry; Albrecht, Martin; Morgan, Grace G.
Afiliação
  • Martinho PN; Centre for Synthesis and Chemical Biology and School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland.
Dalton Trans ; 41(25): 7461-3, 2012 Jul 07.
Article em En | MEDLINE | ID: mdl-22499230
A hysteretic spin transition is induced in a solution assembly of a mononuclear Fe(III) amphiphilic complex which exhibits only gradual spin crossover in the solid state. The hysteretic behavior is dependent on dynamic solution assembly and removal of solvent causes reversion to the original bulk solid magnetic response.
Assuntos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Ferro Idioma: En Ano de publicação: 2012 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Compostos Organometálicos / Ferro Idioma: En Ano de publicação: 2012 Tipo de documento: Article