One-step synthesis of SnO2 and TiO2 hollow nanostructures with various shapes and their enhanced lithium storage properties.

ABSTRACT

A versatile one-step method for the general synthesis of metal oxide hollow nanostructures is demonstrated. This method involves the controlled deposition of metal oxides on shaped α-Fe(2)O(3) crystals which are simultaneously dissolved. A variety of uniform SnO(2) hollow nanostructures, such as nanococoons, nanoboxes, hollow nanorings, and nanospheres, can be readily generated. The method is also applicable to the synthesis of shaped TiO(2) hollow nanostructures. As a demonstration of the potential applications of these hollow nanostructures, the lithium storage capability of SnO(2) hollow structures is investigated. The results show that such derived SnO(2) hollow structures exhibit stable capacity retention of 600-700 mA h g(-1) for 50 cycles at a 0.2 C rate and good rate capability at 0.5-1 C, perhaps benefiting from the unique structural characteristics.