Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology.
Chem Commun (Camb)
; 48(67): 8407-9, 2012 Aug 28.
Article
em En
| MEDLINE
| ID: mdl-22801712
ABSTRACT
Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr(4+) or Hf(4+) source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article