Pyro without fire: synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex.
Inorg Chem
; 51(19): 10077-9, 2012 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-22974202
ABSTRACT
The complex {[(V(IV)O)bipy(H(2)O)](2)(µ-P(2)O(7))}·3H(2)O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article