Strong and dynamic CO2 sorption in a flexible porous framework possessing guest chelating claws.
J Am Chem Soc
; 134(42): 17380-3, 2012 Oct 24.
Article
em En
| MEDLINE
| ID: mdl-23039713
ABSTRACT
Using a bis-triazolate ligand and tetrahedral Zn(II) ion, we synthesized a flexible porous coordination polymer functionalized with pairs of uncoordinated triazolate N-donors that can be used as guest chelating sites to give very high CO(2) adsorption enthalpy and CO(2)/N(2) selectivity. The dynamic CO(2) sorption behavior could be monitored well by single-crystal X-ray diffraction.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Dióxido de Carbono
/
Quelantes
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article