Ligand-centered redox activity in cobalt(II) and nickel(II) bis(phenolate)-dipyrrin complexes.
Chemistry
; 18(46): 14590-3, 2012 Nov 12.
Article
em En
| MEDLINE
| ID: mdl-23042520
ABSTRACT
One for all a trianionic ligand containing the biologically relevant moieties phenolate and porphyrin was designed and synthesized. One-electron oxidation of the nickel and cobalt complexes of these ligands affords an unprecedented and highly stable hybrid porphyrinyl-phenoxyl radical bound to the metal center. Two-electron oxidation of these complexes leads to the M(2+) -(close-shell two-electron oxidized ligand) species.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Porfirinas
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Cobalto
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Níquel
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article