Enantioselective synthesis of optically active 3,3-diarylpropanoates by conjugate hydrosilylation with chiral Rh-bis(oxazolinyl)phenyl catalysts.
J Org Chem
; 77(23): 10914-9, 2012 Dec 07.
Article
em En
| MEDLINE
| ID: mdl-23140754
ABSTRACT
Conjugate hydrosilylation of 3,3-diarylacrylate derivatives catalyzed by chiral rhodium-bis(oxazolinyl)phenyl complexes (1 mol %) at 60 °C for 2 h was investigated to prepare optically active 3,3-diarylpropanoate derivatives in high yields up to 99% yield and high enantioselectivities up to 99%.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2012
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Article