Asymmetric methallylation of ketones catalyzed by a highly active organocatalyst 3,3'-F2-BINOL.
Org Lett
; 15(7): 1710-3, 2013 Apr 05.
Article
em En
| MEDLINE
| ID: mdl-23527954
ABSTRACT
(S)-3,3'-F2-BINOL has been synthesized for the first time and demonstrated as a highly active organocatalyst for asymmetric methallylation of ketones. Up to 982 enantioselectivity and 99% yield were obtained with 5 mol % catalyst loading. The catalyst (S)-3,3'-F2-BINOL could be easily recovered and reused.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Cetonas
/
Naftóis
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article