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Bis[2,4-di-bromo-6-(N-{4-[(E)-1-(benzyl-oxy-imino)-eth-yl]phen-yl}carboximido-yl)phenolato]copper(II).
Li, Xiao-Bing; Li, Xiao-Jun; Meng, Wei-Sheng; Zhang, Yu-Jie; Li, Gang.
Afiliação
  • Li XB; Information Centre, Gansu Institute of Forestry Survey and Planning, Lanzhou 730020, People's Republic of China ; College of Earth and Environmental Scieces, Lanzhou University, Lanzhou 730000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online ; 69(Pt 5): m267, 2013 May 01.
Article em En | MEDLINE | ID: mdl-23723774
ABSTRACT
In the title complex, [Cu(C22H17Br2N2O2)2], the Cu(II) ion is four-coordinated in a trans-CuN2O2 square-planar geometry by two phenolate O and two imino N atoms from two deprotonated N,O-bidentate ligands. In the crystal, the packing of the mol-ecules is controlled by C-H⋯π and π-π inter-actions [centroid-centroid distances = 3.568 (3), 3.678 (2), 3.717 (3) and 3.799 (2) Å] and weak Br⋯Br halogen bonds [3.508 (4) Å], linking the mol-ecules into an infinite three-dimensional supra-molecular network.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article