Bis[2,4-di-bromo-6-(N-{4-[(E)-1-(benzyl-oxy-imino)-eth-yl]phen-yl}carboximido-yl)phenolato]copper(II).
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 5): m267, 2013 May 01.
Article
em En
| MEDLINE
| ID: mdl-23723774
ABSTRACT
In the title complex, [Cu(C22H17Br2N2O2)2], the Cu(II) ion is four-coordinated in a trans-CuN2O2 square-planar geometry by two phenolate O and two imino N atoms from two deprotonated N,O-bidentate ligands. In the crystal, the packing of the mol-ecules is controlled by C-Hâ¯π and π-π inter-actions [centroid-centroid distances = 3.568â
(3), 3.678â
(2), 3.717â
(3) and 3.799â
(2)â
Å] and weak Brâ¯Br halogen bonds [3.508â
(4)â
Å], linking the mol-ecules into an infinite three-dimensional supra-molecular network.
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MEDLINE
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article