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Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides.
Zhang, Chen; Zhang, Shao-Qiao; Cai, Hua-Jun; Cui, Dong-Mei.
Afiliação
  • Zhang C; School of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, PR China.
Beilstein J Org Chem ; 9: 1045-50, 2013.
Article em En | MEDLINE | ID: mdl-23766819
ABSTRACT
A co-catalyst of (PPh3)AuCl/AgOTf for the intermolecular hydroamination of allenes with sulfonamides is shown. The reaction proceeded smoothly under mild conditions for differently substituted allenes giving N-allylic sulfonamides in good yields with high regioselectivity and E-selectivity.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article