A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO4/SiO2.

Aoyama, Tadashi; Koda, Shuichi; Takeyoshi, Yuka; Ito, Tetsuhiro; Takido, Toshio; Kodomari, Mitsuo

Aoyama, Tadashi; Koda, Shuichi; Takeyoshi, Yuka; Ito, Tetsuhiro; Takido, Toshio; Kodomari, Mitsuo.

Afiliação

Aoyama T; Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, Kanda Surugadai, Tokyo, Japan. aoyama.tadashi@nihon-u.ac.jp

Chem Commun (Camb) ; 49(59): 6605-7, 2013 Jul 28.

Article em En | MEDLINE | ID: mdl-23770760

ABSTRACT

ABSTRACT

Simple and efficient cross coupling of alcohols was developed in the presence of NaHSO4/SiO2 to give the corresponding substituted olefins. Direct coupling of alcohols and alkenes was also achieved to give substituted olefins. NaHSO4/SiO2 could be recycled 7 times without loss of catalytic activity.

Assuntos

Álcoois/química; Alcenos/síntese química; Dióxido de Silício/química; Sulfatos/química; Alcenos/química; Estrutura Molecular

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Sulfatos / Dióxido de Silício / Álcoois / Alcenos Idioma: En Ano de publicação: 2013 Tipo de documento: Article

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